Ordovician sedimentation and bimodal volcanism in the Southern Qiangtang terrane of northern Tibet: Implications for the evolution of the northern Gondwana margin

This article reports our new interpretations of the depositional environment and provenance of the Dawashan Formation in the Longmuco–Shuanghu–Lancangjiang suture zone (LSLSZ), in the Southern Qiangtang terrane of northern Tibet, in order to gain a better understanding of the Ordovician tectonic evolution of the northern margin of Gondwana. The Dawashan Formation is dominated by greywacke and shale, with interlayered bimodal volcanic rocks that were deposited in a bathyal to abyssal marine basin. The detrital zircons in the greywacke of the Dawashan Formation have peak ages of 550, 988, 1640, and 2500 Ma, indicating a northern Gondwana margin provenance. The bimodal metavolcanic rocks from the Dawashan Formation are dominated by metarhyolite with subordinate metabasalt. The results of zircon LA-ICP-MS U–Pb dating indicate that the metarhyolite formed between 470 and 455 Ma. The metavolcanic samples are bimodal (SiO₂ = 45.27–55.05 and 66.09–74.59 wt.%). In comparison, the metabasalt has a wide range of MgO concentrations and Mg^# values, contains variable Cr and low Ni concentrations, is depleted in Rb, Ba, and Sr, and is enriched in TiO₂, Th, U, Nb, and Ta. Geochemical diagrams show that the metabasalt erupted in an intra-plate environment. The metarhyolites have high SiO₂, Th, and U concentrations, low concentrations of MgO, P₂O₅, Nb, Sr, and Ti, and negative Eu anomalies. The metarhyolites yield negative zircon ε_Hf(t) values (–2.08 to – 4.50) and T^C_DM model ages of 1436–1567 Ma. The metarhyolites formed from magma derived from the partial melting of old continental crust. These data indicate that the Dawashan Formation records Middle–Upper Ordovician bathyal to abyssal turbidite deposition in a deep-water rift basin at the northern margin of Gondwana.     

Permian ultrahigh–temperature reworking in the southern Chinese Altai: Evidence from petrology,P–T estimates,zircon and monazite U–Th–Pb geochronology

The Chinese Altai orogen formed in the Paleozoic is an important part of the Central Asian Orogenic Belt (CAOB), and the study on the metamorphism will provide novel and robust constraints on its tectonic evolution. In this study, we investigate our newly recognized garnet–orthopyroxene–cordierite granulites at Wuqiagou area in the southern Chinese Altai. Detailed petrographic study and P–T estimates suggest four distinct metamorphic stages of mineral assemblages: (1) pre–peak (M1) stage containing the spinel–cordierite–bearing association or biotite–plagioclase–quartz–bearing inclusion–phase assemblage, with P–T conditions of 3.0–4.0 kbar/700–750 °C; (2) peak ultrahigh–temperature (UHT) (M2) stage represented by relatively coarse–grained garnet–orthopyroxene–cordierite–bearing porphyroblastic assemblage, with high–Al₂O₃ contents (up to ∼8.7 wt%) in orthopyroxene and P–T conditions of ∼8.0 kbar/∼980 °C; (3) post–peak high–temperature granulite facies (M3) stage consisted of orthopyroxene–cordierite and cordierite–quartz corona assemblages, formed during cooling and moderate decompression; and (4) post–peak upper amphibolite facies (M4) stage represented by retrograde biotite–plagioclase–quartz intergrowths. These four discrete metamorphic stages define an anticlockwise P–T path involving a post–peak moderate decompression followed by nearly isobaric cooling process. LA–ICP–MS U–Pb age dating results of metamorphic zircons for UHT samples show two weighted mean ages of ∼390 Ma and ∼280 Ma. We propose that the M1 stage might occur in the middle Devonian, whereas the near–peak UHT stage probably occurred in the early Permian. The Permian UHT metamorphism was further supported by the monazite U–Th–Pb dating results (287.9 ± 2.1 Ma), reflecting a prominent HT–UHT reworking event in the late Paleozoic. We proposed that the Permian UHT reworking event in the southern Chinese Altai probably occurred in a post–orogenic or intraplate extensional tectonic setting associated with the input of external heat, related to the underplating of deep–derived magma as a result of the Tarim mantle plume activity.     

A thermo-chemo-electro-mechanical framework of unsaturated expansive clays

Prediction of the coupled chemo-mechanical behaviours of porous media is an important problem in many areas, i.e., expansive clays in geotechnical and petroleum engineering, engineered barriers in the underground storage of nuclear wastes, and biological tissues in biological engineering. A further complex condition occurs when the voids are not fully saturated by liquid, such that capillary effects cannot be neglected a priori and might play an important role. Focusing on the modelling of expansive clays in the geotechnical field and based on the modified mixture theory, the work presented in this paper contributes to the construction of a theoretical framework used to model such complex coupling behaviours. The Clausius–Duhem inequality, which governs the dissipation associated with mechanical work, phase transformation, mass transport and thermal transport, is rigorously derived. Based on this theoretical framework, a chemo-poro-elastic unsaturated model is developed. The model is subsequently used to simulate the salt solution infiltration process through an unsaturated expansive clayey soil that induces changes in the mechanical and hydraulic field quantities. The logical tendencies are obtained and provide a preliminary demonstration of the capabilities of the newly developed theoretical framework.     

Magmatic evolution of pre-ore volcanics and porphyry intrusives associated with the Altar Cu-porphyry prospect,Argentina

Altar is a Cu-porphyry deposit related to several small plagioclase porphyry intrusions of the late Miocene formed on the margin of the Flat-Slab segment along the Andean Cordillera in north-west Argentina. New stratigraphic and structural mapping supported by geochemistry and geochronology of pre-ore volcanics at Altar has revealed that a period of ∼6–7 Ma of volcanism during the late Oligocene-early Miocene formed ∼4000 m of volcano-stratigraphic succession making up the Pachón Formation. It represents a period dominated by explosive to effusive eruption in a dynamic arc basin with local ash fall and flow deposition in lacustrine and fluvial sites. Volcanism is typified by medium- to high-K calc-alkaline arc magmatism with a shift from mafic compositions at the base to felsic rocks at the top of the formation containing zircons aged 21.9 ± 0.2 Ma (2 Std.Dev, U–Pb). A clear geochemical separation exists between early Miocene pre-ore volcanics that show signatures akin to non-adakitic, normal arc, extensional tectonic settings conducive of chemical differentiation at shallow crustal levels and correlate with intra-regional Abanico and Farellones Formations; and the middle to late-Miocene Cu-mineralised porphyry intrusions. After a break of ∼9 Ma in the geological record at Altar, these Cu-fertile bodies are emplaced entirely within the Pachón Rhyolite and represent adakite-like magmas with fractionation trends evolving from a lower crustal MASH zone. This distinction is controlled by a change from an extensional to compressive tectonic regime in the region during the middle Miocene in which magmas were stalled in the lower crust for an extended period, subsequently became enriched in metals and then formed several Cu-porphyry bodies which were emplaced during a relatively short period towards the late Miocene.     

Recession flow prediction in gauged and ungauged basins by just considering past discharge information

ABSTRACT

Two contrasting methods have been proposed recently to predict the recession flow coefficient using past discharge information only. This study proposes a new method that attempts to obtain past discharge information that is minimally influenced by non-subsurface storage-controlled flows. The existing and new methods were tested using data from 324 US Geological Survey basins, and the new method was found to be superior to both existing methods in 265 basins. Furthermore, this study for the first time used past discharge-derived coefficients to predict recession discharge. The model performance was found to be satisfactory (NSE > 0.5) in 244 basins. Our results also show that the new framework may be useful in certain regions for predicting recession discharge in totally ungauged basins using past discharge information from nearby gauged basins. Overall, this study advances the idea that recession discharge can be predicted by just using past discharge data.     

Comparison of design peak flow estimation methods for ungauged basins in Iran

ABSTRACT

Determining the catchment design peak flow is crucial in hydrological practice. In this paper, the conceptual rainfall–runoff model EBA4SUB (Event-Based Approach for Small and Ungauged Basins) was applied in six catchments in Iran. The aims were to test EBA4SUB in reconstructing runoff hydrographs for the investigated case studies and to provide a suitable alternative for the review and updating of design peak flow estimation in Iran. The EBA4SUB output was compared with previous studies on selected catchments. The results show, for all case studies, a large variability in the peak flow values; the EBA4SUB model gave flow values similar to the other methodologies. The EBA4SUB model can be recommended for the following reasons: (i) it minimizes the subjectivity of the modeller. (ii) its modules are based on state-of-the-art procedures, which have been appropriately optimized for ungauged basins; and (iii) it furnishes the whole design flood hydrograph.     

Early cretaceous ophiolites of the Yarlung Zangbo Suture Zone: insights from dolerites and peridotites from the Baer upper mantle suite,SW Tibet (China)

The Baer ophiolitic massif is located in the northern sub-belt of the western segment of the Yarlung Zangbo Suture Zone (YZSZ) and mainly consists of a lherzolite-dominant mantle suite, dolerite intrusions and limited crustal outcrops. The dolerites show sub-ophitic texture and light rare earth element-depleted chondrite-normalized rare earth element patterns similar to normal-mid-ocean ridge basalts (N-MORB); though, they display enrichments in fluid-mobile elements (Rb, Ba, and Sr) and marked depletions in Th and Nb. The U–Pb ages of several magmatic zircon grains recovered from two dolerite samples indicate that the intrusion of the dikes into the Baer lherzolitic mantle occurred at 125.6–126.3 Ma, consistent with the widespread mafic magmatism between 120 and 130 Ma in the Yarlung Zangbo ophiolites. The dolerites have slightly more radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7043–0.7054) in comparison to N-MORB, whereas they show ¹⁴³Nd/¹⁴⁴Nd values (0.513067–0.513114) similar to N-MORB and high zircon Hf-isotope compositions. They have a limited range of Nd-isotope (ε_Nd(t) values: +8.2 to +9.1) and juvenile Hf-isotope compositions (ε_Hf(t) values: +8.4 to +14.2 and +10.0 to +15.1) indicating derivation from mantle melts. The moderate spread in the ε_Hf (t) values of zircons indicates derivation of the dolerites parental magma from a weakly contaminated spinel-bearing mantle source. This is also corroborated by the geochemical signatures of the Baer dolerites (enrichment in LILE and depletion in HFSE) suggesting minor slab input to the mantle source of the dike-filling melt. We suggest that the genesis of the dolerite dike-forming melt happened at a stage of subduction initiation in a sub-oceanic mantle domain mildly affected by fluids emanating from the downgoing slab. Our data combined with literature data allow us to presume that the intrusion of the dolerites into the Baer mantle corresponds to an early phase of subduction initiation beneath a developing forearc basin.     

尖晶石—斜方辉石间Al—Cr交换平衡的实验研究

在温度为1030～1400℃，压力为0．4～2．0GPa条件下，在自然体系中进行了包含橄榄石-叙方辉石-尖晶石-（熔体）－（斜长石）矿物组合的平衡实验。探讨了斜方辉石-尖晶石间的Al-Cr交换平衡。通过对这平衡的研究，得到Al-Cr在尖晶石中的混合参数WAl-CrSp49541±5000J／mol；它较简单体系中所得WAl-CrSp要大许多，可能是由于自然体系中有Ti4+和Fe3+等混入尖晶石结构中，或是文献中对WAl-CrOpx-0和WMg-AlOpx=0的假设错误所致。实验结果还发现在一定温度下，斜方辉石中Cr的含量随平衡共存尖晶石中Cr的增大而成抛物线状增大。第一次实验验证了Nagata（1983）在自然岩石中的观察。     

Diachronisme des bassins turbiditiques d'avant-pays méso/néocrétacés du pays de Sault (Aude,Pyrénées françaises)

The cartographic, sedimentological and micropalaeontological analysis of remnants of Middle–Upper Cretaceous turbiditic basins from the ‘Pays de Sault’ (Aude, French Pyrenees) shows their diachronism (interpreted on a wider scale) and their sequence diversity. The ‘Gesse breccias’ are regarded as the proximal deposits of a Turonian narrow foreland basin, principally supplied by the erosion of the Jurassic–Lower Cretaceous cover of the High Primary Range to the south, induced by a strike-slip and overthrusting faulting within the en-échelon North-Pyrenean Fault Zone. More to the north, the North-Pyrenean ‘Axat Basin’ consists of two successive backstepping turbiditic wedges, respectively corresponding to an Upper Albian distal flysch and to a Middle–Upper Cenomanian more proximal flysch, all the series unconformably overlying structures that were folded then eroded before the Upper Albian. The previous concept of carbonate olistoliths included within the Axat Cenomanian flysch is also refuted: these large-size blocks are now interpreted as belonging to a tectonic slice destroyed and partly collapsed on the southern slope of the Rebenty Valley during the Quaternary. To cite this article: M.-J. Fondecave-Wallez, B. Peybernès, C. R. Geoscience 336 (2004).     

The Devonian history of northeastern Australia

Devonian rocks occur in northeastern Australia within the ‘Tasman Geosyncline’ in three major tectonic divisions—(a) a very broad mobile platform related to the last stages of stabilisation of the Lachlan Geosyncline, marginal to which is found, (b) the volcanic‐rich New England Geosyncline, and (c) a contrasting region in northern Queensland where complex marine to continental sedimentation occurred on cratonic blocks while non‐volcanic flysch‐like sedimentation occurred in the marginal Hodgkinson Basin.

The tectonic setting was governed by differences in the nature of the continental margin, so that the New England Geosyncline and Hodgkinson Basin, which developed along the eastern margin of the continent from the earliest Devonian to the late Palaeozoic, show correspondingly different sedimentation and deformation histories.

An integrated account of the Devonian geology of these regions is given, leading to.an interpretation of the environments of the Devonian in terms of plate‐tectonic movements, generally from the east.

Postulated tectonic zones within the New England Geosyncline region include pre‐Devonian deep ocean deposits with mild high‐pressure low‐temperature meta‐morphism, and Devonian volcanic arc and marginal sea volcanic‐derived deposits. Within the mobile platform to the west, variable marine and continental deposits are associated with volcanicity in the zone transitional to the New England Geosyncline. In the northern region, rifting of the craton and development of an Atlantic‐type margin was followed by subduction with folding and metamorphism at the end of the Devonian.

The Devonian rocks are strongly affected by intense late Palaeozoic tectonic and igneous activity in the eastern marginal regions, but only minor effects are seen to the west.