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41.
The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface. 相似文献
42.
A Simple Parameterisation for Flux Footprint Predictions 总被引:9,自引:6,他引:9
Flux footprint functions estimate the location and relative importance of passive scalar sources influencing flux measurements
at a given receptor height. These footprint estimates strongly vary in size, depending on receptor height, atmospheric stability,
and surface roughness. Reliable footprint calculations from, e.g., Lagrangian stochastic models or large-eddy simulations
are computationally expensive and cannot readily be computed for long-term observational programs. To facilitate more accessible
footprint estimates, a scaling procedure is introduced for flux footprint functions over a range of stratifications from convective
to stable, and receptor heights ranging from near the surface to the middle of the boundary layer. It is shown that, when
applying this scaling procedure, footprint estimates collapse to an ensemble of similar curves. A simple parameterisation
for the scaled footprint estimates is presented. This parameterisation accounts for the influence of the roughness length
on the footprint and allows for a quick but precise algebraic footprint estimation. 相似文献
43.
44.
A processing strategy and the corresponding software architecture for the processing of GOCE (Gravity field and steady-state Ocean Circulation Explorer) observables is presented and described, with the major objective to compute a high-accuracy, high-resolution spherical harmonic model of the Earth's gravity field. The combination of two numerical solution strategies, i.e. the rigorous solution of the corresponding large normal equation systems applying parallel processing (on a PC cluster) as the core solver, and the fast semianalytic approach as a quick-look gravity field analysis (QL-GFA) tool, is proposed. Such a method fusion benefits from the advantages of the individual components: the rigorous inversion of the system providing also the full variance-covariance information, and the quickness enabling the consecutive production of intermediate gravity field solutions, for the purpose to analyse partial and incomplete data sets and to derive a diagnosis of the performance of the GOCE measurement system. The functionality and operability of the individual components are demonstrated in the framework of a closed loop simulation, which is based on a realistic mission scenario both in terms of the orbit configuration and the coloured measuring noise. Special concern is given to the accuracy of the recovered coefficients, the numerical behaviour, the required computing time, and the particular role of the individual modules within the processing chain. In the case of the core solver, it is demonstrated that the assembling and rigorous solution of large normal equation systems can be handled by using Beowulf clusters within a reasonable computing time. The application of the quick-look tool to partial data sets with short-term data gaps is demonstrated on the basis of several case studies. Additionally, the spectral analysis of the residuals of the adjustment is presented as a valuable tool for the verification of the noise characteristics of the GOCE gradiometer. 相似文献
45.
Ali Kahriman 《Soil Dynamics and Earthquake Engineering》2004,24(11):887-892
The aim of this study is to predict peak particle velocity level at a limestone quarry located in Istanbul, Turkey. The ground vibration components were measured for 73 blast events during the bench blast optimization studies during a long period. In blasting operations; ANFO (blasting agent), gelatine dynamite (priming) and NONEL detonators (firing) were used as explosives at this site. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured by means of vibration monitors for every event. Then, the data pairs of scaled distance and particle velocity were analyzed. The equation of scaled distance extensively used in the literature was taken into consideration for the prediction of peak particle velocity. At the end of statistical evaluations, an empirical relationship with good correlation was established between peak particle velocity and scale distance for this site. The established relationship and the results of the study are presented. 相似文献
46.
IntroductionWhenpropagatingthroughananisotropicmedium,ashearwavesplitsintotwo(quasi)shearwaveswithdifferentpropagationspeedsandpolarizedorthogonally.Owingtotherecentdevel-opmentofseismicobservationsystem,detectionofshearwavessplittingwithverysmalldelaytimesbetweenfasterandslowershearwavesbecameavailableandprovidedpowerfulapproachfordetectionofcrustalanisotropy.Crampin(1978)emphasizedtheroleofalignedmicrocracksasacauseofcrustalanisotropyandpointedoutthatforverticallyalignedmicrocracksthedirecti… 相似文献
47.
北京市春夏季大气气溶胶的单颗粒分析表征 总被引:9,自引:0,他引:9
采集了北京市2000年春夏季大气气溶胶样品5个,采用扫描电镜X射线能谱技术分析大气气溶胶单颗粒约2500个。研究结果表明,沙尘期间,矿物尘是最主要的颗粒物种类,非沙尘期间,北京市大气气溶胶中主要检出矿物尘和含硫颗粒物。夏季随着颗粒物污染的加重,含硫颗粒物的数目百分数增加。是北京市大气颗粒物污染的重要特征。重点讨论了Ca-S颗粒、K-S颗粒和Ca-K-S颗粒三类典型含硫颗粒物的化学组成和粒径分布特征。数目可观的Ca-K-S颗粒以及其他硫酸盐颗粒的生成与相对湿度和云量等气象条件相关,这些颗粒物可能是云中过程的产物。减少SO2排放,减少含硫颗粒物,对于控制北京市的大气颗粒物浓度水平具有重要意义。 相似文献
48.
49.
Aeolian abrasion and modes of fine particle production from natural red dune sands: an experimental study 总被引:3,自引:0,他引:3
A series of experiments was conducted to determine the potential for aeolian abrasion of natural dune sands to produce fine particles (< 125 µm) by (1) the release of resident fines; (2) spalling, chipping and breakage of particles; and (3) the removal of grain surface coatings. Parent samples were obtained from the surfaces of four active continental dunes and abraded using a glass ‘test tube’ chamber for up to 120 h. The fine particles produced by this abrasion process were trapped at varying time intervals and subject to detailed particle‐size analyses using a Coulter Multisizer. The abrasion of untreated parent samples produced fine particles in one of two main size classes, < 10 µm and > 50 µm, but when the parent sample was sieved to exclude particles < 250 µm, relatively more material in the range 10–50 µm was produced. For unsieved parent samples, the size range associated with the dominant mode varied according to the length of the abrasion time. The coarsest mode (> 63 µm) was dominant during the first 16 h of abrasion, then became less significant and is thought to be associated with the release of resident fines into suspension. The finest mode (< 10 µm) was absent or very weak during the first 16 h of abrasion, then became more significant and, in some instances, dominated the distribution as abrasion continued. Removal of grain surface coatings is the main source of fine material < 10 µm, and this may be a significant source of fine material in areas where sands are dominated by subrounded and rounded particles. By comparison with previous studies of aeolian particle abrasion, these natural dune sands produced very low quantities of fine material (by weight), but their spatial extent makes them potentially a significant source of dust‐sized particles at the global scale. 相似文献
50.
E. Villaescusa I. Onederra C. Scott 《Fragblast: International Journal for Blasting and Fragmentation》2004,8(1):23-40
This paper presents the results of a comprehensive monitoring program designed to investigate the extent of blast induced damage experienced by rock masses extracted by bench stoping methods. An array of triaxial geophones and extensometers were used to monitor blast vibration attenuation and measure hangingwall deformations during stope extraction. In addition, pre and post surveys of the hangingwall rock mass were conducted using a TV borehole camera and cavity survey instrumentation. These surveys were later used to calibrate damage profiles into the stope hangingwalls.
Peak particle velocity, hangingwall deformation measurements and stope surveys were used to develop a site specific damage model that allowed engineers to asses drilling and blasting configurations to minimise the extent of pre-conditioning and damage. In addition the study included the analysis of the frequency response, displacements and accelerations experienced by the excavation as extraction and mine filling progressed. This work aimed at improving our understanding of the influence of blasting on the dynamic behaviour of stope hangingwalls.
The study demonstrated that estimates of the maximum extent of rock mass pre-conditioning and/or damage made through the application of the Holmberg-Persson approach compared well with measured results. In addition, the study found that dynamic loading imparted on an exposed hangingwall from subsequent stope blasting was also expected to contribute to rock mass weakening and that mine filling was crucial to arrest further deterioration. Hangingwall accelerations were used to demonstrate that larger openings may be more susceptible to dynamic loading. 相似文献
Peak particle velocity, hangingwall deformation measurements and stope surveys were used to develop a site specific damage model that allowed engineers to asses drilling and blasting configurations to minimise the extent of pre-conditioning and damage. In addition the study included the analysis of the frequency response, displacements and accelerations experienced by the excavation as extraction and mine filling progressed. This work aimed at improving our understanding of the influence of blasting on the dynamic behaviour of stope hangingwalls.
The study demonstrated that estimates of the maximum extent of rock mass pre-conditioning and/or damage made through the application of the Holmberg-Persson approach compared well with measured results. In addition, the study found that dynamic loading imparted on an exposed hangingwall from subsequent stope blasting was also expected to contribute to rock mass weakening and that mine filling was crucial to arrest further deterioration. Hangingwall accelerations were used to demonstrate that larger openings may be more susceptible to dynamic loading. 相似文献