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原油在储层介质中的加水裂解生气模拟实验 总被引:5,自引:2,他引:5
采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450~500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450~600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。 相似文献
23.
Scott Lamoureux 《地球表面变化过程与地形》2002,27(10):1107-1124
A 487‐year annually laminated (varved) sediment record from Nicolay Lake, Cornwall Island, in the Canadian High Arctic was evaluated to determine the impact that years with high sediment yields had on sediment yields in subsequent years. All of the 40 largest years showed evidence for increased sediment yield in the subsequent 10–30 years. The positive anomalies in lagging years were approximately scaled according to the size of the initiating year, although many intermediate years (25‐ to 100‐year recurrence) showed weak or variable responses. The smallest events considered (10‐ to 25‐year recurrence) showed a consistent, but low‐amplitude response. Additionally the 10‐year events revealed frequent negative sediment yield anomalies in the preceding decade. This behaviour was interpreted as a frequent sediment activation cycle initiated by the modest year, and leading to sediment yield hysteresis lasting 15–25 years. The largest years (greater than 50‐year recurrence) showed consistently above‐average sediment yields in the preceding decade, in part due to the frequent occurrence of moderate (Q10) years. It is hypothesized that temporary storage of sediment and previous initiation of erosion sites resulted in extraordinary sediment yields during intense summer rainfall events. This study demonstrates the potential use of varved lake sediment records to improve our understanding of long‐term sediment dynamics. These records present an opportunity to further develop and test sediment dynamic and routing models to gain insight into the interaction of time and space in fluvial and sediment delivery processes. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
24.
Jean‐Jacques Macaire Saïda Bellemlih Christian Di‐Giovanni Patrick De Luca Lionel Visset Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009
In the Négron River catchment area (162 km2), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 106 t) and loess (21 × 106 t), and Holocene alluvium (12·6 × 106 t), peat (0·6 × 106 t) and colluvium (18·5 × 106 t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km?2 a?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km?2 a?1 from alluvium stores and 7·6 t km?2 a?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km?2 a?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km?2 a?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
25.
This study examines runoff generated under simulated rainfall on Summerford bajada in the Jornada Basin, New Mexico, USA. Forty‐five simulation experiments were conducted on 1 m2 and 2 m2 runoff plots on grassland, degraded grassland, shrub and intershrub environments located in grassland and shrubland communities. Average hydrographs generated for each environment show that runoff originates earlier on the vegetated plots than on the unvegetated plots. This early generation of runoff is attributed to soil infiltration rates being overwhelmed by the rapid concentration of water at the base of plants by stemflow. Hydrographs from the degraded grassland and intershrub plots rise continuously throughout the 30 min simulation events indicating that these plots do not achieve equilibrium runoff. This continuously rising form is attributed to the progressive development of raindrop‐induced surface seals. Most grassland and shrub plots level out after the initial early rise indicating equilibrium runoff is achieved. Some shrub plots, however, display a decline in discharge after the early rise. The delayed infiltration of water into macropores beneath shrubs with vegetation in their understories is proposed to explain this declining form. Water yields predicted at the community level indicate that the shrubland sheds 150 per cent more water for a given storm event than the grassland. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
26.
古代生物分子在第四纪研究中的应用 总被引:4,自引:1,他引:4
从第四纪化石和沉积物中获得的古代生物分子为第四纪研究者提供了丰富和独特的有关古代生物、遗传和古环境信息的定量和高分辨率的数据.过去10多年的研究证实来自第四纪材料中的各种古代生物分子的分离、鉴定和应用的能力在不断增加.文章总结了古代生物分子在第四纪研究中的最新进展,主要包括以下几个方面的内容:1)不同类型的古代生物分子在地质体中的保存和降解;2)古DNA和古蛋白序列中的生物遗传学信息;3)单体分子同位素与第四纪古环境和古气候研究;4)建于古代生物分子水平上的第四纪年代学.作者预见对第四纪地层中的原位和分散保存的古代生物分子的研究将在广度上以多分子综合研究而深度上与单体分子同位素技术相结合,为第四纪科学家们提供大量解决地质学和演化生物学问题的高精度数据.随着地球化学和分子生物学技术的不断改进以及人们对古代生物分子的降解过程和机制的进一步理解,对古代生物分子的研究无疑将进一步促进和推动第四纪科学研究的发展. 相似文献
27.
The objective of this experimental study was to account for the role of sediment availability and specific gravity on cluster formation and cluster geometric characteristics (spacing and size). To isolate the effects of sediment availability and specific gravity on cluster evolution, mono‐sized spheres were used to simulate the cluster evolutionary cycle. Overall, twelve experimental runs were carried out in the laboratory flume. Six of these tests were performed by using glass spheres (specific gravity, SG = 2·58) and the other six by employing an equal combination of glass and Teflon spheres (SG = 2·12) of the same diameter to evaluate the role of specific gravity on cluster evolution. The three sediment availability conditions that were investigated here simulated isolated gravel elements, pool–riffle sequences and densely packed gravel‐bed. An advanced image analysis technique was employed to track the evolution of cluster microforms and provide quantitative information about the size and shape of clusters and the number of clusters per unit area. The results of this study showed that: (1) sediment availability affects the architecture and size of cluster microforms; and (2) clusters consisting of mono‐sized sediments start disintegrating at twice the incipient conditions. By performing complementary tests for the isolated gravel elements case, it was found that the evolutionary cycle of individual clusters could be described as follows, in order of increasing stress: no cluster→two particle cluster→comet→triangle→rhomboid→break up. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
28.
XU Jiongxin Professor Institute of Geography Chinese Academy of Sciences Beijing China 《国际泥沙研究》1997,(3)
LINTRODUCTIONThetributariesofmiddleYellowRiverarefamousintheworldforthehighestsuspendedsedimentconcentrationandsedimentyield.Forexample,atWenjiachuanstationofKuyeheRiverthemeasuredhighestsuspendedconcentrationis1700kg/m',andthemeanannualsedimentyieldis25000t/(kln'.a).Theformationofhyperconcentratedflowsandtheirinfluenceonerosionprocessesareofgreatimportancenotonlyfromatheoreticalpointofviewbutalsoforpracticalpurposes.Therefore,scientistsfromChinaandallovertheworldhavedrawntheirintensio… 相似文献
29.
为更加系统有效地开展农作物产量预报工作,研制了《农作物产量预报模式管理咨询应用服务系统》,可将各种类型的已建产量预报模式归入档入库,为用户提供咨询服务并自动实现预报结果输出 相似文献
30.