福建地壳运动观测网络观测成果初步分析

利用最新GAMIT软件,对福建省地壳运动观测网络的厦门、福州、泉州、龙岩、南平5个GPS基准站2004年3月1日至2005年3月6日的观测资料在ITRF2000全球坐标系统框架下,使用IGS精密星历数据及其核心观测站的坐标和运动速率为控制参数进行了统一解算,并利用GLOBK软件进行联合平差,得到了5个测站的观测精度。结果表明,福建地区形变南强北弱、东强西弱,且该地区随中国大陆较均匀地向SE（SEE）方向运动。     

M5 model tree based modelling of reference evapotranspiration

This paper investigates the potential of M5 model tree based regression approach to model daily reference evapotranspiration using climatic data of Davis station maintained by California irrigation Management Information System (CIMIS). Four inputs including solar radiation, average air temperature, average relative humidity, and average wind speed whereas reference evapotranspiration calculated using a relation provided by the CIMIS was used as output. To compare the performance of M5 model tree in predicting the reference evapotranspiration, FAO–56 Penman–Monteith equation and calibrated Hargreaves–Samani relation was used. A comparison of results suggests that M5 model tree approach works well in comparison to both FAO–56 and calibrated Hargreaves–Samani relations. To judge the generalization capability of M5 model tree approach, model created by using the Davis data set was tested with the datasets of four different sites. Results from this part of the study suggest that M5 model tree could successfully be employed in modeling the reference evapotranspiration. Further, sensitivity analysis with M5 model tree approach suggests the suitability of solar radiation, average air temperature, average relative humidity, and average wind speed as input parameters to model the reference evapotranspiration Copyright © 2009 John Wiley & Sons, Ltd.     

The GGOS as the backbone for global observing and local monitoring: A user driven perspective

A key geodetic contribution to both the three Global Observing Systems and initiatives like the European Global Monitoring for Environment and Security is an accurate, long-term stable, and easily accessible reference frame as the backbone. Many emerging scientific as well as non-scientific high-accuracy applications require access to an unique, technique-independent reference frame decontaminated for short-term fluctuations due to global Earth system processes. Such a reference frame can only be maintained and made available through an observing system such as the Global Geodetic Observing System (GGOS), which is currently implemented and expected to provide sufficient information on changes in the Earth figure, its rotation and its gravity field. Based on a number of examples from monitoring of infrastructure, point positioning, maintenance of national references frames to global changes studies, likely future accuracy requirements for a global terrestrial reference frame are set up as function of time scales. Expected accuracy requirements for a large range of high-accuracy applications are less than 5 mm for diurnal and sub-diurnal time scales, 2–3 mm on monthly to seasonal time scales, better than 1 mm/year on decadal to 50 years time scales. Based on these requirements, specifications for a geodetic observing system meeting the accuracy requirements can be derived.     

Assessing the applicability of OpenStreetMap data to assist the validation of land use/land cover maps

The validation of land use/land cover (LULC) maps is usually performed using a reference database consisting of a sample of points or regions to which the ‘real’ class is assigned. This assignment is usually performed by specialists using photointerpretation (PI) of high-resolution imagery and/or field visits, which are time consuming and expensive processes. The aim of this article is to assess if the data available in the collaborative project OpenStreetMap (OSM) may be used as a source of data to assist the creation of these reference databases, reducing the time spent and costs associated with their generation. For this aim, two case studies were used, where the validation of the Global Monitoring for Environment and Security Urban Atlas (UA) was performed. The used methodology requires the harmonization of the data available in OSM with the UA nomenclature, and the subsequent creation of a LULC map from the OSM data. This map was then compared to UA to assess the similarity of the regions mapped in both. To test the usefulness of OSM data to assess the accuracy of UA, a sample of points was created and two reference databases generated, one assigning the data extracted automatically from OSM to the points where these data were available, and PI for the remaining points, and the other using only PI. The accuracy assessment of UA for the two case studies was then made building confusion matrixes and computing accuracy indicators. The results showed that for the two study areas, only low percentages of points had to be photo interpreted in the first reference database (respectively, 12% and 2% for the two study areas), decreasing the work load considerably. The results obtained with both reference databases are comparable for level 1 classes. For level 2 classes, worse results were obtained for some classes, showing that the OSM data used are not enough to create reliable reference data.     

A New Reference Material for Tritium Organic Molecules in Sediment: Results of an International Intercomparison Exercise

Solid matrix ³H reference materials are challenging to prepare given the volatile nature of ³H and are often unrepresentative of the range of ³H forms that may be encountered during routine analysis. As a result, few ³H reference materials are currently available, undermining verification of analytical techniques for environmental ³H measurement. To address this, an International Working Group on Organically‐Bound Tritium Analysis determined to produce a tritium natural matrix reference material (NMRM). The reference material comprises marine sediment blended with sewage sludge contaminated with ³H‐organic species arising from authorised discharges from a radiopharmaceutical manufacturing site. Previous studies have demonstrated that the ³H species have persisted in the environment over three decades providing valuable supporting data to underpin the characterisation of the NMRM. The preparation and characterisation of the NMRM are described along with the subsequent application of the reference material in an international intercomparison exercise involving nineteen laboratories from nine countries. A reference value of 168 ± 22 Bq kg^?1 was derived from the data arising from the proficiency test.     

Comment on: Mass Fractions of Forty‐Six Major and Trace Elements,Including Rare Earth Elements,in Sediment and Soil Reference Materials Used in Environmental Studies. Fiket et al. (2017), Geostandards and Geoanalytical Research, 41, 123–135

This paper is intended to be a constructive discussion of Fiket et al. (2017, Geostandards and Geoanalytical Research , 41 , 123–135), who dealt with the determination of major, trace and rare earth elements in several sediment and soil certified reference materials. In the present author's view, the paper by Fiket et al. (2017) suffers from a lack of reference to several publications in which somewhat similar results had already been reported. The present contribution therefore provides a comparison of previously published results with those of Fiket et al. for the CRMs soil NCS DC 77302 (GBW 07410), stream sediment NCS DC 73309 (GBW 07311), marine sediments MESS‐3 and NCS DC 75301 (GBW 07314) and estuarine sediment IAEA‐405. It is argued that this fuller consideration (a) allows critical evaluation of the quality of the results presented by Fiket et al. and (b) highlights the advantages of their work. Finally, attention is drawn to the (possible or real) problems that can arise during simultaneous determination of multiple trace elements.     

High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

空间分析中几种插值方法的比较研究

针对常用的空间插值方法在精度分析方面比较的不足,从地质统计学、数学函数和几何方法方面分别选取普通克里金插值法、三次样条函数法和距离权重倒数法进行插值精度的比较与分析。文章分析了各个方法的优缺点和局限性,选取疏密差异较大的均匀和不均匀离散点数据进行实验,利用三次趋势面模型和MATLAB,ArcGIS,GS+Version...