特殊地质样品中钼同位素分析的化学前处理方法研究

Mo同位素的研究在地学领域应用广泛,它可以示踪Mo的全球循环、古海洋氧化还原条件、成矿过程、天体演化过程等。应用多接收电感耦合等离子体质谱法(MC-ICP-MS)分析Mo同位素比值前需对样品进行分离纯化,以富集Mo和去除Zr、Ru、Fe、Mn等干扰元素。处理某些Fe含量特别高且Ca含量也高的特殊地质样品(如含大量黄铁矿的钙质泥岩、钙质页岩等),若根据传统的阴阳离子交换树脂双柱法,需多次使用阳离子交换树脂分离Fe,步骤较繁琐且Mo回收率也会降低,而根据传统的阴离子交换树脂单柱法,使用1mol/L氢氟酸-0.5mol/L盐酸介质会产生较多CaF_2沉淀影响分离纯化效果。针对此类特殊地质样品,本实验使用同一阴离子树脂柱(AG1-X8,100～200目)对样品进行两次淋洗,第一次使用6mol/L盐酸,第二次使用1mol/L氢氟酸-0.1mol/L盐酸和6mol/L盐酸。结果表明Mo的回收率96%,干扰元素的去除效果好,尤其是Ru的去除率接近100%,比原方法提高了约12%。对实际样品进行实验的结果也显示,Mo的回收率和干扰元素的去除都符合要求,δ~(98/95)Mo测定值与文献报道值一致。改进后的阴离子交换树脂单柱-二次淋洗法适用于Fe、Ca含量较高的特殊样品,降低了分析成本,也适用于绝大多数地质样品。     

Statistical study of spatial variation of response spectrum using free field records of dense strong motion arrays

Spatial variation of acceleration response spectra is examined using strong motion records for a large number of events from dense accelerometer arrays at Chiba in Japan and SMART-1 in Lotung, Taiwan. The effects of earthquake component, structural damping, earthquake magnitude, focal depth, epicentral distance, structural time period, and station separation on the intra-event variation of response spectra are examined first through an empirical analysis and then through a least-square regression fit for parametric study. A very large scatter of the response spectra ratio is observed for both arrays, especially for SMART-1 array. The mean values of the ratio vary from 10 to 20 per cent for Chiba array while they vary from 25 to 50 per cent for SMART-1 array. The coefficients of variation of the ratio range from 5 to 25 per cent for Chiba array and 30 to 50 per cent for SMART-1 array. The correlation among response spectra is found to be inversely proportional to station separation and shows frequency dependence. For larger time periods, the correlation is lower and not higher. The correlation is also lower for UD earthquake component as compared to the two horizontal components. For higher damping ratio, the correlation among spectra is higher. The effect of the earthquake magnitude, focal depth and epicentral distance on the spatial variation is complex. The three parameters having implicit interdependence, considering their combined effect, a positive contribution to the value of ratio of response spectra is observed in the case of larger earthquake events. Furthermore, as mentioned above, the spatial variation for SMART-1 array is much larger than that for Chiba array. This difference can be attributed mainly to the difference in distance between the instruments in the two arrays. However, some of the difference is considered to be due to site specific characteristics. Copyright © 1999 John Wiley & Sons, Ltd.     

"3S"技术在城市规划专业的应用与教学改革

信息技术的发展,城市规划专业教育逐步将定量和数字技术方法引入教育体系,文章对“3S”技术特别是“GIS”、“RS”和数字城市技术在城市规划领域的广泛应用和课程体系的教学改革进行探讨和建议。     

中国沿岸海洋站自动测波仪器测波特征分析

选取我国沿岸18个海洋观测站,对SBF3-1、SBF3-2、LPB1-2、SZF型自动测波仪器与目测、岸用测波仪两种非自动测波方式的海浪观测参数进行了比较分析。研究发现,与非自动测波方式相比,SBF3-1型浮标观测波高无明显变化,观测周期具有显著变大的特点;SBF3-2型浮标观测波高多数情况下具有变小的特点,观测周期保持不变或趋于变大;LPB1-2型声学测波仪观测波高有微弱变大的特点,观测周期无明显变化或微弱变大;SZF型浮标观测波高和观测周期既存在明显变大的情况,也存在明显变小或变化不明显的情况,无明显共性观测特点。     

P2000型测氡仪在气氡连续观测中记录的潮汐现象

利用宁波地震台ZK03井的原气氡观测系统,将P2000型测氡仪应用于气氡连续观测试验,记录到较明显的潮汐现象且其波动幅度较大。功率谱估计结果显示,观测数据存在显著的固体潮效应。同时,与同井观测的动水位、同台观测的VS垂直摆NS向记录的潮汐波形进行对比,发现曲线变化趋势基本一致,每天都有两峰两谷,但存在约2h的时间差。P2000型测氡仪具有自动扣除本底污染的功能,其记录到的波形能更真实地反应地下流体中气氡浓度的动态变化过程,可应用于地震流体气氡的连续观测。     

地震仪器设备管理系统的设计与实现

利用Java语言,使用Microsoft SQL Server 2005数据库,利用MyEclipse工具研发地震仪器设备管理系统.使用该系统进行台站仪器设备信息管理,便于保存、查询、更新信息,实现数据资料的完整、准确、长期保存,工作效率增加.     

Seismic performance and comparison of three different I beam to box column joints

Despite the inherently advantages of the box column, finding the best option for the I beam to the box column connection is the main challenge in using the box column as a structural member for special moment frames. In this paper, the seismic performance of unreinforced connection, weakened connection and strengthened connection was evaluated through a comprehensive experimental program. The seismic comparisons were fabricated by assessing the strength, ductility and energy dissipation in each configuration. Three full scale tests with several connections were carried out. All the specimens were subjected to cyclic loading and prior to failure by forming a plastic hinge in the beam, all the connections managed to reach an inelastic rotation of more than 6.0% rad. The experimental and analytical results showed that the seismic performance of the strengthened connection with flange and shear plates turned out to be the most effective in the beam to the box column connection. Moreover, the normalized stress distribution of the continuity plates revealed that the possibility of the weld fracture in unreinforced connection is more than other specimens.     

基于eZ80F91 Flash微控制器前兆仪器的嵌入式以太网接口的设计与应用

介绍了利用eZ80F91 Flash微控制器实现地震前兆仪器的网络化功能的方法,提出了一种微控制器与前兆仪器的嵌入式连结方案,满足了前兆仪器网络化的要求。     

DLS型高精度多功能拾振器的设计与应用

文中介绍了新研制的便携式高精度多功能拾振器的技术性能、工作原理和理论计算,分析讨论了仪器的特点,给出了技术指标实测结果并进行了结构微振动记录幅值谱分析。     

地震地下流体观测现状

系统介绍我国地震地下流体井（泉）的分布现状、观测井含水层特征及自流热水井的观测现状,并介绍观测项目及主要观测仪器等。上述调查与分析结果,可为我国地震地下流体台网的进一步调整与优化,及今后地震地下流体学科的发展提供科学依据。