吉林红旗岭铜镍矿床地电化学异常特征、成晕机制及找矿预测

通过在吉林红旗岭铜、镍矿区开展研究,在铜、镍矿体上同步垂直出现了Cu、Ni、Co、Pt、Cr、Sr异常.异常值的高低排列顺序是Cu＞Ni＞Co＞＞Pt＞Cr＞Sr,呈明显的电化学异常标志.对铜、镍矿的电化学溶解试验研究的结果表明,当铜、镍矿标本电解到24 h,其溶液中的Cu2 、Ni2 、Co2 离子质量分数分别达到2.2×10-6、1.8×10-6、1.5×10-6,充分证明铜镍矿床不但能产生电化学溶解,而且电化学溶解能力较强.经过在吉林红旗岭矿区深部找矿预测,发现3处具有成矿远景的地电化学异常,表明该方法具有良好的找矿效果.     

锆石铀含量与岩体成矿能力相关性研究——以诸广南部花岗岩为例

为初步探讨锆石铀含量在花岗岩型铀矿远景区预测方面的应用前景,以勘探研究程度较高的诸广南部花岗岩为样本,经花岗岩类样品概率统计显示产铀岩体锆石平均铀含量略大于贫铀岩体,总体差别不明显;样品分期次、岩性对比分析表明产铀岩体锆石平均铀含量也并非普遍高于贫铀岩体,印支期产铀岩体二云母花岗岩锆石平均铀含量甚至低于贫铀岩体;统计发现产铀岩体花岗岩岩脉中具有超高的锆石铀含量(平均铀含量3000×10-6以上)。初步分析认为依据花岗岩类锆石铀含量暂不能有效判别诸广山复式岩体成矿能力;岩脉锆石铀含量超高可能是铀矿找矿的重要标志,因而具超高锆石铀含量的花岗岩岩脉是否发育可能是该区域寻找工业铀矿床的关键。     

浙南龙泉地区晚侏罗世火山岩的厘定及成因探讨

浙江晚中生代大规模火山活动始于晚侏罗世还是早白垩世,长期以来存在争议。本文对浙南龙泉地区火山岩进行了锆石U-Pb定年,获得一批高精度的年代学数据,其SHRIMP锆石U-Pb和LA-ICP-MS锆石U-Pb年龄集中于163～145 Ma,确认浙江晚中生代火山活动始于晚侏罗世。地球化学特征和Sr-Nd同位素特征表明这套晚侏罗世火山岩具有高硅、高钾、低磷、贫铁镁的特征,属于过铝质高钾钙碱性岩石系列。由于晚中生代太平洋板块的俯冲作用,导致了下部地壳物质(基底变质岩)广泛熔融,形成了本区晚侏罗世火山岩浆活动。为了便于表达、对比,笔者建议新建"晚侏罗世黄茅尖群"地层单位。     

东营凹陷南坡东段潜山地层划分与残留地层展布

东营凹陷南坡东段的潜山勘探程度很低,复杂的残留地层结构及其发育模式认识不清严重制约着潜山的精细勘探。综合应用野外标准岩石地层对比、古生物群落时代划分及不整合测井综合分层等技术,重新厘定研究区的深部层系地层归属与划分方案。在此基础上,应用构造演化恢复技术搞清多期构造运动对地层剥蚀、残留的控制作用,最终明确残留地层平面的展布特征。研究表明,研究区中生界残留地层仅分布在王古2井区以北地区,南部草桥-王家岗南部广大地区则为上古生界地层;由于研究区遭受印支运动挤压成山、燕山运动拉张裂陷等多幕构造运动影响,残留地层表现为近北西向“跷跷板”状的地层产状模式。该成果可为东营凹陷的复杂潜山油气藏勘探提供理论指导。     

西藏羌塘南缘青草山北花岗闪长岩锆石U-Pb年代学、地球化学特征及其成矿意义

青草山北花岗闪长岩体位于班公湖-怒江缝合带北侧、羌塘陆块南缘,呈岩脉、岩株状与晚二叠世龙格组碳酸盐岩呈侵入接触。本文对该花岗闪长岩的锆石进行了LA-ICP-MS U-Pb年代学和岩石地球化学研究,其岩浆锆石U-Pb年龄为154.8±1.2Ma(MSWD=1.7),属晚侏罗世,与热那错埃达克质英安岩年龄高度一致,岩石地球化学特征显示,青草山北花岗闪长岩属于准铝质、高钾钙碱性系列,富集轻稀土元素、大离子亲石元素,亏损重稀土元素、高场强元素,具弱Eu负异常,显示出典型岛弧岩浆岩特征;锆石原位微量元素分析表明,锆石总体富集重稀土,相对亏损轻稀土,在锆石Nb/Ta-Y图解中样品点落入金伯利岩区域,而在岩石地球化学构造环境判别图解中,样品点同样指示其可能来源于幔源岩浆。青草山北花岗闪长岩班公湖-怒江洋壳晚侏罗世北向俯冲到一定深度后,俯冲洋壳发生部分熔融,形成的岩浆在上升的过程中与地幔楔发生混染,其中,部分岩浆在侵位的过程中形成中酸性的花岗闪长质岩浆房,部分岩浆则喷出地表,形成热那错组英安岩。     

Metallogenesis and hydrothermal evolution of Middle Jurassic porphyry Mo deposits in the southern Zhangguangcai Range,NE China: evidence from fluid inclusions,H–O–S isotopes,and Re–Os geochronology

A major metallogenic belt with substantial resources of gold, lead, zinc, copper, and molybdenum is present in the southern Zhangguangcai Range, NE China. Several large porphyry Mo deposits are located in this belt, as for example at Jidetun, Fu’anpu, and Daheishan. Five molybdenite samples from the Jidetun deposit yielded an Re–Os isochron age of 168.6 ± 2.1 Ma (mean standard weighted deviation = 0.20), and this is consistent with the Re–Os isochron ages of the other Mo deposits in the southern Zhangguangcai Range, giving a Middle Jurassic age for metallogenesis. The Jidetun, Fu’anpu, and Daheishan deposits all tend to have weakly enriched ³⁴S values of 0.80‰–3.20‰ and relatively low Re contents ranging from 3.073 to 43.567 ppm, which indicates the ore-forming materials were derived mainly from granitic magmas that had an origin in the mixture of crust and mantle. Three stages of mineralization can be identified in the deposits at Jidetun, Fu’anpu, and Daheishan. The original ore-forming fluids in stage I were characterized by high-temperature magmatic hydrothermal fluids that were most likely derived by exsolution from the Middle Jurassic ore-bearing magmas. However, two different fluid systems, NaCl–H₂O–CO₂ fluids and NaCl–H₂O fluids, were widespread in stage I of porphyry Mo deposits in the southern Zhangguangcai Range. Taking into account the regional geological characteristics and tectonic setting, we suggest that two different emplacement modes of the ore-bearing magmas explain the different fluid systems in stage I: the first magmas were emplaced along the contact zones between the strata and earlier granitoids, whereas the second magmas were emplaced entirely within the earlier granitoid intrusions. The stage II and III fluids were characterized by relatively lower temperatures and low H–O isotopic values, indicating a gradual evolution from magmatic to meteoric sources.     

Petrogenesis and tectonic implications of late Mesozoic granitoids in southern Anhui Province,southeastern China

Late Mesozoic granitoids are widely distributed in southern Anhui Province, southeastern China, which also contains significant W–Mo–Cu mineralization. This study presents new geochronological and geochemical data that reveal the petrogenesis and tectonic affinity of the granitoids in this region. These granitoids can be divided into a high-K calc-alkaline and peraluminous I-type granodiorites, and an alkaline and metaluminous A-type granites, with zircon U–Pb dating indicating that they formed at 150–138 and 133–124 Ma, respectively. The early stage I-type granodiorites are adakitic, enriched in the light rare earth elements, and depleted in Nb, Ta, P, and Ti. They have negative zircon ε_Hf(t) values (–19.8 to –2.5) that correspond to Hf crustal model ages of 2.4–1.4 Ga. These early stage granodiorites were derived from partial melting of thickened Palaeoproterozoic–Mesoproterozoic lower crust. The late-stage A-type granites with strong depletion in Sr, P, and Ti, contain higher Zr, Y, and Yb contents, higher zircon ε_Hf(t) values (–1.5 to +2.1), and younger zircon Hf model ages (1.1–1.3 Ga) than the early stage granodiorites. The geochemistry of these A-type granites indicates they were likely generated by the reworking of Mesoproterozoic to Neoproterozoic juvenile crustal material that experienced the fractional crystallization of plagioclase and accessory minerals. Combining these data with other geological data from the study area indicates that the early stage granodiorites formed in a continental arc setting, whereas the late-stage granites formed in an extensional setting associated with roll-back of the subducted Palaeo-Pacific slab. The results indicate that zircon Ce⁴⁺/Ce³⁺ value can provide useful insight into oxygen fugacity conditions during magmatism.     

The Manyas fault zone (southern Marmara region,NW Turkey): active tectonics and paleoseismology

The Manyas fault zone (MFZ) is a splay fault of the Yenice Gönen Fault, which is located on the southern branch of the North Anatolian Fault System. The MFZ is a 38 km long, WNW–ESE-trending and normal fault zone comprised of three en-echelon segments. On 6 October 1964, an earthquake (Ms = 6.9) occurred on the Salur segment. In this study, paleoseismic trench studies were performed along the Salur segment. Based on these paleoseismic trench studies, at least three earthquakes resulting in a surface rupture within the last 4000 years, including the 1964 earthquake have been identified and dated. The penultimate event can be correlated with the AD 1323 earthquake. There is no archaeological and/or historical record that can be associated with the oldest earthquake dated between BP 3800 ± 600 and BP 2300 ± 200 years. Additionally, the trench study performed to the north of the Salur segment demonstrates paleoliquefaction structures crossing each other. The surface deformation that occurred during the 1964 earthquake is determined primarily to be the consequence of liquefaction. According to the fault plane slip data, the MFZ is a purely normal fault demonstrating a listric geometry with a dip of 64°–74° to the NNE.     

南华北盆地偃龙地区二叠系泥页岩微观孔隙特征及其影响因素分析

运用氩离子抛光—场发射环境扫描电子显微成像测试技术,对南华北盆地偃龙地区ZK1614井二叠系海陆交互相—陆相的泥页岩样品进行观察并获取二次电子及背散射信息。结合X射线能谱信息和JMicro Vision软件灰度识别功能,对样品矿物组成及微观孔隙特征进行定性分析和定量表征,并探讨了孔隙发育分布的影响因素。研究发现:样品主要发育的孔隙以无机矿物孔为主,孔隙类型有粒内孔、粒间孔、少量有机质孔及微裂隙;样品面孔率介于0.92%~5.53%之间,整体来看,面孔率大小与孔隙数量正相关;孔径大小介于50~2000 nm间,不同区段的孔面积对数指标与单位面积孔数量对数指标呈两段式线性关系,孔径较小时两者负相关,孔径较大时两者正相关。不同矿物对孔隙的发育有不同的控制作用,脆性矿物主要影响裂隙的发育,对孔隙的发育有一定的抑制作用;粘土矿物因构造应力、矿物相变及脱水等作用形成大量孔隙,对孔隙的发育起一定的促进作用。研究区燕山期、喜山期因构造活动形成了大量尺度较大的裂隙,裂隙的发育使岩层的渗流性能增加,促进了有机酸和地层水对矿物的溶蚀作用,相应的促进了孔隙的发育。此外,随着埋藏深度的增加,孔隙体积随着压实作用的增大而逐渐减小。     

吉林省舒兰市长安堡钼(铜)矿床成矿岩体地球化学特征及其地质意义

为查明吉中地区典型斑岩型矿床矿化特征及成矿规律,对长安堡铜钼矿床地质特征和成矿岩体进行了研究.该矿床成矿岩体为黑云母二长花岗岩.岩石主量、微量及稀土元素组成特征为：高硅,全碱含量不高,富钾,Al₂O₃含量较高,TiO₂含量较低,贫Y和Yb,相对富集大离子亲石元素（LILE）和轻稀土元素（LREE）,而高场强元素（HFSE）、重稀土元素含量（RREE）相对较低,具负Eu异常,（La/Yb）_N值较高,2件未蚀变样品具有较低的（Rb/La）_N值,与我国东北部地区岛弧钙碱性火成岩地球化学特征基本一致.