基于多参数指标的长江口滨岸多环芳烃来源辨析

Samples of suspended particulate matters(SPMs),surface sediment and road dust were collected from the Yangtze estuarine and nearby coastal areas,coastal rivers,and central Shanghai.The samples were analyzed for the presence of 16 polycyclic aromatic hydrocarbons(PAHs)in the USEPA priority-controlled list by GC-MS.The compound-specific stable carbon isotopes of the individual PAHs were also analyzed by GC-C-IRMS.The sources of PAHs in the SPMs and surface sediments in the Yangtze estuarine and nearby coastal...     

激光辐照煤岩的热效应数值模拟分析

探究激光辐照煤岩的热效应,有助于理解激光作用于煤岩的成孔机制,从而为激光应用于煤层气水平钻进提供理论支持。基于传热学理论,建立了激光辐照煤岩的数学模型,通过多物理场仿真分析软件COMSOL Multiphysics对激光破岩过程中温度场分布情况进行数值计算,探讨了激光光束辐照在煤岩表面时激光功率、光斑半径及辐照时间等因素对激光作用于岩石的热效应影响。再考虑到煤岩在极高的升温速度下将发生相变,建立了其发生气体相变的数值仿真模型,对其气化后形成的烧灼孔进行模拟仿真。仿真结果分析表明,影响钻孔深度的主要因素是激光功率和辐照时间,影响孔口直径大小的主要因素是光斑直径,激光辐照煤岩的成孔机理主要是激光高温烧蚀成孔,如果用于实际钻进过程中将大幅减少固体岩屑,有助于降低排屑工艺的难度。     

火山岩盖层类型及封气能力——以松辽盆地徐家围子断陷为例

利用钻井、测井和分析测试资料,对徐家围子断陷火山岩盖层类型、识别标志、分布、封闭能力和对天然气成藏与分布的控制作用进行了研究,认为徐家围子断陷火山岩盖层分为火山碎屑岩和火山熔岩盖层2种。火山碎屑岩盖层主要是凝灰岩和火山角砾岩,具有井径扩容、电阻率小和高声波时差特征;火山熔岩盖层主要为流纹岩、凝灰岩和安山岩,具有井径不扩容、电阻率中等和低声波时差特征。利用高声波时差和声波时差值小于56 μs/ft可以分别识别火山碎屑岩盖层和火山熔岩盖层。火山碎屑岩盖层区域分布在断陷南部下白垩统营城组一段火山岩体的顶部,火山熔岩盖层局部分布在营一段和营三段火山岩体内部。火山碎屑岩盖层较火山熔岩盖层具有更强的封气能力,火山碎屑岩盖层控制着徐家围子断陷火山岩中天然气的区域聚集与分布,火山熔岩盖层仅控制着天然气在火山岩体中的局部聚集与分布。     

安徽省巢湖地区二叠纪栖霞组、孤峰组硅质岩地球化学特征对比及大地构造背景分析

为探讨下扬子地区二叠系硅质岩的硅质来源和形成背景,以巢湖地区二叠纪栖霞组和孤峰组硅质岩为研究对象,收集了前人大量有关栖霞组和孤峰组的研究成果和数据,并对采自栖霞组和孤峰组硅质岩样品进行了主量元素、微量元素、稀土元素测试。栖霞组、孤峰组硅质岩样品测试结果显示,硅质岩的稀土元素经北美页岩标准化后的配分曲线近似平坦型向左倾斜,有弱Ce负异常,且HREE弱富集,反映了热水沉积硅质岩的特征。研究区硅质岩样品的Al Fe Mn三角图中,样品投点分布较广,即Al比值变化范围较大,认为是岩浆在喷发过程中受硅-铝质陆壳混染作用的结果。结合沉积环境判别指标分析认为：栖霞组硅质岩沉积时期其沉积环境主要为大陆边缘环境;孤峰组硅质岩沉积时期其沉积环境为大陆边缘-海盆过渡环境。从栖霞组到孤峰组沉积时期,海侵规模不断变大,水体变深,海盆面积扩大,研究区在不同时期沉积环境存在差异。研究区栖霞组、孤峰组硅质岩的沉积与大陆边缘裂陷活动紧密相关。     

四川芦山 MS7．0地震震源机制解

使用中国数字地震台网记录的区域和远震宽频带波形,通过频率域和时间域多步反演,研究四川芦山 MS 7．0地震基于点源模型的震源机制解和有限断层模型。考虑到使用不同波形资料类型、盆地效应及简化的一维速度模型等给反演震源参数带来的影响,经测试比较,结果表明：使用区域波形和本区域简化一维速度模型,波形拟合误差最小。此次地震表现为高倾角纯逆冲型事件矩心在水平方向上位于震中偏南西向约4．5 km,最佳波形拟合矩心深度约17 km,矩震级 MW约6．6。推断此地震大多数能量主要在震源偏南西约4．5 km 处释放。     

Total gaseous mercury emissions from mercury-enriched soil in Guizhou, China

Guizhou is located in the Circum-Pacific Global Mercuriferous Belt, and mercury concentrations in soil in this area are enriched. In-situ total gaseous mercury （TGM） exchange fluxes between air and soil surface were intensively measured at four sampling sites in Guiyang from 21 May to 16 June, 2003, and five sites in the Lanmuchang mercury mining area in December 2002 and May 2003, respectively. The in-situ Hg flux measurement was conducted with a dynamic flux chamber （DFC） of quartz. Overall, net emissions were obtained from all sampling sites. Soil mercury concentration and solar radiation have been proved to be the two most important parameters to control mercury emissions from soil. Meanwhile, rain events can enhance mercury emission rate significantly.     

Hydrogeochemical characteristics of mine water in the Harz Mountains,Germany

Water samples (springs, creeks, mine adits) from different former mining districts of the Harz Mountains and the nearby Kupferschiefer (copper shale) basin of Sangerhausen were analysed for major ions and trace metals. Due to more intensive water rock interactions including the ore minerals, the mine water concentrations of main components and trace metals are generally higher compared to non mining affected surface waters of the mountain range. Furthermore, the content of major ions in mine water is enriched by mixing processes with saline waters from Permian layers in the Kupferschiefer district and at the deeper levels of the mines in the Upper Harz Mountains. The waters of the different mining districts can be distinguished by trace metal occurrences and concentrations derived from the different ore bodies. Water from the Kupferschiefer mines shows the highest Na, Cl, Cu, Mo and U concentrations, whereas a combination of elevated As and Se concentrations is typical for most of the samples from the mines around St. Andreasberg. However, there are exceptions, and some water samples of all the investigated mining districts do not follow these general trends. Despite the influence of mining activities and ore mineralisation, hydrochemical effects due to rain water dilution can be seen in most of the waters. According to the elevation of the mountain range, higher precipitation rates decrease the ion concentrations in the waters of springs, creeks and mine adits.     

Hydrothermal Mineralization on the Mesoproterozoic Passive Continental Margins of China： A Case Study of the Langshan-Zha＇ertaishan Belt, Inner Mongolia, China

Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt.     

1999年夏季江淮地区热源和水汽汇时空变化特征

利用1999年的NCAR再分析网格点风场、温度场、湿度场及含HUBEX试验加密观测的降水资料等,诊断分析了夏季长江流域梅雨暴雨集中期及其前后江淮地区的大气热源、水汽汇的时空分布及多时间尺度特征.