发挥行业和地域优势开辟经济发展新领域——矿业网站的建设设想

网络经济已成为新的社会生产力的代表。广西地质矿产勘查开发局应该利用其行业和地域方面的固有优势，积极参与网络经济，以期打开矿业市场。文章提出了建立矿业网站的设想和框架。     

多接收器电感耦合等离子体质谱法测定镉标准溶液中镉的同位素组成

建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。     

Mineralogy and geochemistry of the Texeo Cu–Co mine site (NW Spain): screening tools for environmental assessment

The Cu–Co–Ni Texeo mine has been the most important source of Cu in NW Spain since Roman times and now, approximately 40,000 m³ of wastes from mine and metallurgical operations, containing average concentrations of 9,263 mg kg⁻¹ Cu, 1,100 mg kg⁻¹ As, 549 mg kg⁻¹ Co, and 840 mg kg⁻¹ Ni, remain on-site. Since the cessation of the activity, the abandoned works, facilities and waste piles have been posing a threat to the environment, derived from the release of toxic elements. In order to assess the potential environmental pollution caused by the mining operations, a sequential sampling strategy was undertaken in wastes, soil, surface and groundwater, and sediments. First, screening field tools were used to identify hotspots, before defining formal sampling strategies; so, in the areas where anomalies were detected in a first sampling stage, a second detailed sampling campaign was undertaken. Metal concentrations in the soils are highly above the local background, reaching up to 9,921 mg kg⁻¹ Cu, 1,373 mg kg⁻¹ As, 685 mg kg⁻¹ Co, and 1,040 mg kg⁻¹ Ni, among others. Copper concentrations downstream of the mine works reach values up to 1,869 μg l⁻¹ and 240 mg kg⁻¹ in surface water and stream sediments, respectively. Computer-based risk assessment for the site gives a carcinogenic risk associated with the presence of As in surface waters and soils, and a health risk for long exposures; so, trigger levels of these elements are high enough to warrant further investigation.     

Mineralogical and geochemical alteration of Hitura sulphide mine tailings with emphasis on nickel mobility and retention

Weathering of Hitura (W Finland) nickel sulphide mine tailings and release of heavy metals into pore water was studied with mineralogical (optical and electron microscopy, X-ray diffraction) and geochemical methods (selective extractions). Tailings were composed largely of serpentine, micas and amphiboles with only minor carbonates and sulphides. Sulphides, especially pyrrhotite, have oxidized intensively in the shallow tailings in 10–15 years, but a majority of the tailings have remained unchanged. Oxidation has resulted in depletion of carbonates, slightly decreased pH, and heavy metal (Ni, Zn) release in pore water as well as in the precipitation of secondary Fe precipitates. Nevertheless, in the middle of the tailings area, where the oxidation front moves primarily downward, released heavy metals have been adsorbed and immobilized with these precipitates deeper in the oxidation zone. In contrast to what was seen in pore water pH, but in accordance with static tests of the previous studies, the neutralisation potential ratio (NPR) calculated based on the mineralogical composition and the total sulphur content suggested that tailings are ‘not potentially acid mine drainage (AMD) generating’. However, the calculated buffering capacity of the tailings resulted largely from the abundant serpentine because of the low carbonate content. Despite its slow weathering rate, serpentine may buffer the acidity to some extent through ion exchange processes in fine ground tailings. Nevertheless, in practice, acid production capacity of the tailings depends primarily on the balance between Ca–Mg carbonates and iron sulphides. NPR calculation based on carbonate and sulphur contents suggested, that the Hitura tailings are ‘likely AMD generating’. The study shows that sulphide oxidation can be significant in mobilisation of heavy metals even in apparently non-acid producing, low sulphide tailings. Therefore, prevention of oxygen diffusion into tailings is also essential in this type of sulphide tailings.     

基于Poulos弹性理论的被动桩改进算法

传统的Poulos弹性理论仅适合于均质土中土体侧向位移时桩的性状分析,无法考虑土的层状特性。通过引入层状地基中作用一水平集中力的广义Mindlin解和地面作用有竖向荷载时的应力和位移通解,对Poulos方法进行了改进,使之扩展到多层土中,还用于研究堆载条件下的被动桩变形和受力响应。算例分析表明,改进弹性理论要比Poulos方法更为严密、合理,提高了计算精度,应用范围也更广。     

气举反循环采矿方法单井试验及应用探讨

湖南道县一个矿区,铁锰矿体储量约2200万t。由于复杂的水文地质和工程地质条件,从20世纪70年代发现后,一直没有开采。笔者通过多年大直径工程井的实践经验,查阅国内外资料后,提出了钻井-气举反循环法试开采的方法,并在现场进行了单孔开采试验,获得了比较满意的效果。以该矿体Ⅱ号矿为例,介绍了钻井-气举反循环法采矿的适用条件、工艺过程以及试采情况,并就以后大面积开采提出了若干技术措施。     

中国开辟区不利开采地形类型及其分布

利用1998年"大洋一号"调查船近海底作业所获的深拖海底电视和照相系统资料,对中国开辟区不利开采地形类型及其分布特征进行了研究,并对海底地形的坡度进行了计算,结果表明:(1)中国开辟区东、西两区海底的东向坡和西向坡是均衡分布的。东、西两区海底地形坡度的分布特征明显不同,东区海底地形坡度以0～15°为主,而西区坡度大于3°的地形则很少。坡度大于5°的地形主要分布于坡脚处,特别是坡度超过15°的地形总是出现在水深变化的转折点处。(2)研究区不利开采地形可分为坡度为5～15°和大于15°两种类型,东区地形坡度大于5°的不利开采地形比西区多14%,东区坡度大于15°的地形为3.6%,比西区(仅为1.4%)多,东、西两区都有少量坡度近90°的地形出现,并且这种地形在东区所占比率比西区大,说明东区断崖、陡坎和断裂沟槽比西区多,地形也更为复杂多变。     

Modelling of periodic wave transformation in the inner surf zone

In this paper, we analyse the ability of the nonlinear shallow-water (NSW) equations to predict wave distortion and energy dissipation of periodic broken waves in the inner surf zone. This analysis is based on the weak-solution theory for conservative equations. We derive a new one-way model, which applies to the transformation of non-reflective periodic broken waves on gently sloping beaches. This model can be useful to develop breaking-wave parameterizations (in particular broken-wave celerity expression) in both time-averaged wave models and time-dependent Boussinesq-type models. We also derive a new wave set-up equation which provides a simple and explicit relation between wave set-up and energy dissipation. Finally, we compare numerical simulations of both, the NSW model and the simplified one-way model, with spilling wave breaking experiments and we find a good agreement.     

Design and Strength Analysis of A Spherical Connector for Lifting Subsystem in Deep Sea Mining System

1 .IntroductionThe lifting systemis composed of pipes andtheir connectors .It is not onlythe lifting channel formanganese nodule betweenthe miningship andintermediate bin,but alsothe supporting massfor deepsea miningequipment and cables .Sothe reliability…     

水溶液中聚合物在粘土上的吸附

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。