Chemical composition of wet deposition in a Mediterranean site Athens,Greece related to the origin of air masses

The goal of this study is to determine the chemical composition of rain, in the wider region of Athens, Greece for the time period 1st September 2001 to 31st August 2002. Two model automatic rain samplers were installed in the Meteorological Station of Laboratory of Climatology (latitude: 37° 58′ N, longitude: 23° 47′ E) inside the Athens University Campus and in a site at Heraklio Attica, a northern suburb of Athens (latitude: 38° 03′ N, longitude: 23° 45′ E). The concentrations (μeq l⁻¹) of the major cations (H⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺) and anions (Cl⁻, , και ), as well as pH and conductivity of rain in 39 total samples were determined. The figures of pH range from 6.4 to 8.4 and conductivity from 8 to 207 μS cm⁻¹. The analysis showed that Ca²⁺ ions are abundant within all examined samples, while and present the highest concentrations from the anions. In order to find out the origin of the air masses, the air mass back trajectories were calculated. Five sectors of the origin of air masses were revealed: the North, the South, the Local, the West and the East sector. Multivariate methods included Factor Analysis and Discriminant Analysis were applied to the examined ion concentrations and three main factors were extracted, which discriminated the ions according to their origin. The first group of ions is interpreted as the result of the anthropogenic activity, the second group represents the acidity–alkalinity independently of their source and the third one the marine influence.     

论苏轼诗歌景物描写的绘画美

苏轼诗歌中的景物描写渗透着诗人的情才和画家的技艺.诗歌在描写景物时浓墨淡写,构图简括,达到了虚与实精妙结合的境界;善于刻画自然事物的运动状态,写出景物运动的时间感、距离感、立体感,或变静为动,赋予景物运动情态;并且还描写景物的的新鲜色彩,使作者之情融于景物,唤起读者的色彩感觉,从而给人以美的感受.     

近地表土壤中可溶态阴离子的石油地质意义

沉积有机质在生成油气及运移的过程中,部分可溶微量元素会分离出来,溶解在伴生的水中.油田水及原油中的可溶微量元素部分溶解于水,并随水一起运移至近地表.通过一定技术手段分析近地表土壤中的可溶态阴离子的含量变化特征,就可以追踪下伏对应地层的含油气信息.通过对新场气田、昌德气田、平方王油田上方近地表土壤中的可溶态阴离子检测的实...     

Significance of processes in the near‐stream zone on stream water acidity in a small acidified forested catchment

The near‐stream zone has received increasing attention owing to its influence on stream water chemistry in general and acidity in particular. Possible processes in this zone include cation exchange, leaching of organic matter and redox reactions of sulphur compounds. In this study the influences of processes in the near‐stream zone on the acidity in runoff from a small, acidified catchment in central southern Sweden were investigated. The study included sampling of groundwater, soil water and stream water along with hydrological measurements. An input–output budget for the catchment was established based on data from the International Co‐operative Programme on Integrated Monitoring at this site. The catchment was heavily acidified by deposition of anthropogenic sulphur, with pH in stream water between 4·4 and 4·6. There was also no relationship between stream flow and pH, which is indicative of chronic acidification. Indications of microbial reduction of sulphate were found in some places near the stream, but the near‐stream zone did not have a general impact on the sulphate concentration in discharging groundwater. The near‐stream zone was a source of dissolved organic carbon (DOC) in the stream, which had a median DOC of 6·8 mg L¹. The influence on stream acidity from organic anions was overshadowed by the effect of sulphate, however, except during a spring flow episode, when additional organic matter was flushed out and the sulphate‐rich ground water was mixed with more diluted event water. Ion exchange was not an important process in the near‐stream zone of the Kindla catchment. Different functions of the near‐stream zone relating to discharge acidity are reported in the literature. In this study there was even a variation within the site. There is therefore a need for more case studies to provide a more detailed understanding of the net effects that the near‐stream zone can have on stream chemistry under different circumstances. Copyright © 2001 John Wiley & Sons, Ltd.     

五硼酸钾溶液中含硼物种分布研究

采用物种分布图和核磁共振实验研究了五硼酸钾溶液中含硼物种的类型、含量和溶液浓度间关系。研究表明五硼酸钾在稀溶液中几乎全部水解为B(OH)3和B(OH)4-;在较浓溶液中主要物种为B3O3(OH)4-和B(OH)3,而B5O6(OH)4-和[B4O5(OH)42-]的含量较小。核磁共振实验研究给出了B(OH)4-, B3O3(OH)4-和B5O6(OH)4-的生成常数K1, K3, K5,研究得出B5O6(OH)4-含量很少的原因是其解聚为其它类型硼酸根离子。外加离子促进五硼酸根离子的生成,而高温条件促进B5O6(OH)4-发生解聚反应。     

Increased light availability enhances tolerance against ocean acidification-related stress in the calcifying macroalga Halimeda opuntia

Although the adverse impacts of ocean acidification (OA) on marine calcifiers have been investigated extensively, the anti-stress capabilities regulated by increased light availability are unclear. Herein, the interactive effects of three light levels (30 μmol photons/(m2·s), 150 μmol photons/(m2·s), and 240 μmol photons/(m2·s) combined with two pCO₂ concentrations (400 ppmv and 1400 ppmv) on the physiological acclimation of the calcifying macroalga Halimeda opuntia were investigated using a pCO₂-light coupling experiment. The OA negatively influenced algal growth, calcification, photosynthesis, and other physiological performances in H. opuntia. The relative growth rate under elevated pCO₂ conditions significantly declined by 13.14%?41.29%, whereas net calcification rates decreased by nearly three-fold under OA conditions. Notably, increased light availability enhanced stress resistance through the accumulation of soluble organic molecules, especially soluble carbohydrate, soluble protein, and free amino acids, and in combination with metabolic enzyme-driven activities, OA stress was alleviated. The carotenoid content under low light conditions increased markedly, and the rapid light curve of the relative electron transport rate was enhanced significantly by increasing light intensities, indicating that this new organization of the photosynthetic machinery in H. opuntia accommodated light variations and elevated pCO₂ conditions. Thus, the enhanced metabolic performance of the calcifying macroalga H. opuntia mitigated OA-related stress.     

Evolution of pore structure and hydraulic conductivity of randomly distributed soluble particle mixture

The plane strain behavior of particulate mixtures containing soluble particles was investigated by conducting both laboratory tests and numerical analysis. To perform the laboratory experiments, soluble mixtures were prepared using photoelastic disks and ice disks with diameters in the ratios (D_{ice disk}/D_{photoelastic disk}) of 0.5 and 0.7, and the evolution of the force chain and pore structure was monitored during the dissolution of the ice disks. Subsequently, numerical analysis was conducted by using the 2‐dimensional discrete element method for the soluble mixtures, and it was compared with the experimental results. Additionally, parametric studies were implemented by varying the particle size ratios between the soluble and non‐soluble particles and the volumetric fraction of the soluble particles. The results of the laboratory experiments and numerical analysis demonstrate that (1) after the dissolution of the soluble particles, the pore fabric of the specimens changed, resulting in a force chain changes, local void increases, and coordination number decreases; (2) the effects of soluble particles on the macro‐behaviors of the mixtures could be divided into 3 zones based on the particle size ratios between the soluble and non‐soluble particles and volumetric fraction of soluble particles. These zones were as follows: (Zone 1)—with a small total soluble volume, slight decrease in the in situ lateral pressure (K₀), and minor increase in the hydraulic conductivity (k); (Zone 2)—with a moderate soluble particle; the dissolution generated a honey‐comb particle structure; (Zone 3)—the total soluble volume was very large, and the high volumetric fraction of the dissolving particle collapsed the pore structure, decreasing in the in situ lateral pressure (K₀) but increasing the hydraulic conductivity (k). The horizontal stress returned to almost the original level, and the internal arching formation increased significantly with the hydraulic conductivity (k).     

水在兰州地区红层风化泥岩抗剪强度中的综合效应

水与岩土相互作用是导致岩土抗剪强度降低的主要原因之一,这种宏观表象是地下水与岩土发生了一系列复杂的力学、物理和化学方面相互作用的综合结果。因此,查明水与岩土的相互作用模式是掌握岩土抗剪强度变化机理的关键所在。本文以兰州地区红层风化泥岩为对象,采用直剪试验方法,初步探讨了快剪条件下,孔隙水化学成分及pH改变时,该类风化泥岩抗剪强度的变化特点。结果显示,在快剪条件下,水在该类风化泥岩抗剪强度中的力学效应(孔隙水压力效应)与物理、化学效应同时存在,但力学效应明显强于物理效应和化学效应。地下水物理效应和化学效应的强弱与风化泥岩可溶盐含量及其化学成分、粘粒含量及其矿物成分有关。     

原油污染对栉孔扇贝抗氧化酶活性的影响

以原油水溶性成分(water soluble fraction of crude oil,WSF)为污染物,采用暴露实验法,研究了栉孔扇贝(Chlamys farreri)鳃和消化腺组织中超氧化物歧化酶(Superoxide Dismutase,SOD)和过氧化氢酶(Catalase,CAT)活性的变化.结果表明,WSF污染下,鳃和消化腺组织SOD和CAT酶活性随暴露时间增加一般表现为降低-升高-降低的趋势,酶活性达到最高的时间随浓度不同而变化.第1天时消化腺SOD在0.08 mg/L浓度下被诱导,而后随时间增加表现为抑制效应;浓度为0.21和0.88 mg/L时消化腺SOD酶活性被抑制,随暴露时间延长而活性增加.暴露时间为4d时,石油烃浓度在0.08和0.88 mg/L时鳃组织SOD酶活性均被抑制,而浓度为0.21 mg/L时被诱导.消化腺和鳃组织SOD可以作为扇贝被污染胁迫的指标.     

几种海藻中无机阴离子的组成及与海水环境的关系

采用色谱法分析获得了10种常见海藻中的 F–、Cl–、组成特征,并初步探讨了其阴离子组成与海水环境的初步关系.结果表明,主要无机阴离子总含量褐藻高于绿藻和红藻,且存在显著性差异;褐藻和绿藻门的羽藻容易富集碘,是良好的生物碘源.通过多元统计分析显示 Cl–与 I–相关程度最密切(r=0.681),其次是主要是F–、SO ?和缩因子与海水中该元素逗留时间的对数相关统计表明,孔石莼、浒苔和鼠尾藻的相关系数大于0.9,说明某些海藻与海水中的非金属无机元素的分布迁移有密切的联系,研究近岸区域海藻中无机非金属元素的组成可为揭示元素生物地球化学循环提供重要讯息.PO ?与 I–以及34 PO ?与 Cl–;主成分 1 34 24 NO?贡献比较大,主成分2主要是3 PO ?、Cl–及I–贡献比较大.海藻中阴离子的浓34 SO ?、24 PO ?、34 NO?、I–等无机阴离子的3