Soil sodium and potassium adsorption ratio along a Mediterranean–arid transect

Changes in the relationship between soil soluble ions and rainfall were studied on hillslopes at seven research sites that represent four climatic regions: Mediterranean, semi-arid, mildly arid and arid. At each site, soil samples were taken in several seasons and the ratio between the Na⁺ plus K⁺ content and the Ca²⁺ plus Mg²⁺ content (sodium and potassium adsorption RATIO=SPAR) was determined. In general, SPAR increased with increasing aridity except for the most arid site in which the soil contains a gypsic layer. The relationship between SPAR and rainfall was non-linear. An abiotic threshold, characterized by a sharp change in the SPAR, was found around the 200 mm isohyet: sites that receive less than 200 mm annual rainfall showed significantly higher SPAR than those that receive more than 200 mm, where SPAR was very low.     

鄂西南渔塘坝硒矿区硒污染成因探讨

本文讨论了由风化作用与首次发现的烧石灰两种因素构成的硒污染，对硒矿石的可溶性及不等时可溶性硒浸取试验表明，不断运动的，成分复杂的，具有一定酸碱度的天然水溶液对硒矿石长期作用后，能分解出大量的元素硒，这些元素硒是参与形成亚硒酸盐和硒酸盐的源泉。由此说明，风化作用是硒污染的因素之一。     

南海北部大气气溶胶水溶性成分谱分布特征

通过对南海腹地岛屿测站和南海北岸测站气溶胶样品中水溶性成分的分析，以及与华南大陆清洁测点和城市测点的对比，结果表明:海岛测点气溶胶总质量与诸离子浓度均大大低于海岸与大陆测点。其分布以三峰型出现的比较多，海岛与海岸气溶胶中水溶性成分以SO2-4，Cl-与Ca2+，Na+为含量比重最大的离子成分；与华南大陆测点相比，Cl-，Na+比重显著增加而NH+4的含量比重有所下降。     

甘肃黑河中下游影响绿洲植被发育的某些因素

黑河下游额济纳绿洲区和中下游沿黑河干流河床附近的潜水位埋深较浅,是维系地表植被生长的重要因素。中游高台附近潜水位存在每年双峰值的变化,较之下游额济纳绿洲潜水位每年单峰值的变化更有利于植被的生长。在包气带剖面中,同一时刻水土势、含水量、含盐量随深度的变化趋势基本相同。采样点包气带土壤中易溶离子含量相对较低,全盐量小于5%,中游采样点土壤中以HCO3-为主,下游以SO42-为主,由SO42-、Cl-和Na+、Ca2+组成的盐类构成了包气带土壤中的主要盐分。土壤中易溶离子含量自地表至潜水面之间随深度总体上呈减小趋势。植被的根系分布对包气带土壤含水量、水土势和易溶离子含量随深度的分布有着重要的影响,在植物根系发育带的土壤中含水量、水土势和易溶离子含量升高。     

绿鳍马面鲀(Navodon septentrionalis)鱼头酸溶性与酶溶性胶原蛋白的分离纯化及理化性质研究

利用酸溶法和酶溶法制备马面鲀鱼头酸溶性胶原蛋白(ASC)和酶溶性胶原蛋白(PSC),并对所制备的ASC和PSC的氨基酸组成、SDS-PAGE、红外光谱、黏度和热变性温度,以及溶解度等性质进行分析。结果表明:马面鲀鱼头中ASC和PSC的提取率分别为0.94%±0.07%和3.91%±0.14%。Gly(265.0和251.8残基/1000残基)、Ala(111.0和107.6残基/1000残基)和Pro(87.0和83.1残基/1000残基)含量较高,而His和Tyr的含量较少,且未检测到Cys。ASC和PSC中亚氨基酸(Pro和Hyp)含量为169.3和160.6残基/1000残基。氨基酸组成分析、SDS-PAGE和红外光谱(FTIR)证实ASC和PSC均属于I型胶原蛋白,热变性温度分别为17.6°C和16.5°C。在酸性p H值范围内,ASC和PSC的溶解度较高;当Na Cl溶液浓度高于2%,ASC和PSC的溶解度会显著降低。综上,相对于哺乳动物类胶原蛋白,马面鲀鱼头ASC和PSC的亚氨基酸含量和热变性温度较低,结构稳定性差,易于降解,可作为胶原蛋白肽的制备原料进行开发。     

高易溶盐非饱和伊犁原状黄土的临界状态特性

为探究伊犁地区高易溶盐含量黄土的临界状态特性,针对不同易溶盐含量的非饱和伊犁原状黄土,开展了控制吸力和净围压的三轴固结剪切试验。研究结果表明：在常吸力固结剪切条件下,非饱和伊犁原状黄土的强度随含盐量的增加存在峰值;含盐量一定,不同吸力非饱和土的q-p或e-p临界状态线均为平行直线,q- 临界状态线可归一为饱和土临界状态线表示的一条直线,其斜率随含盐量的增加呈幂函数降低;非饱和土e-p临界状态线的斜率 大于饱和土的斜率 ,两者均随含盐量的增加先减后增,相同有效净平均应力下非饱和土和饱和土的临界状态孔隙比之比 与气体饱和度1- 可以归一化;q-p平面上初始屈服曲线和后继屈服曲线均可近似假定为对称于 线的椭圆,吸力和应力对屈服曲线的硬化作用是等向的。     

长春地区季冻土基本性质对水分迁移的影响

以长春-四平线（一号样）、长春-松原线（二号样）以及长春-吉林北线（三号样）3段公路土样为研究对象,从微观结构出发,结合物理化学试验和力学试验,评价了长春地区季冻土的性质对水分迁移的影响,为长春地区季冻土的水分迁移研究、道路冻胀翻浆的防治等提供试验依据。从试验得出,长春地区季节冻土孔隙直径大部分分布在<5 μm区间,有利于水分迁移;土样矿物质含量较高,阳离子交换量比较大,粘粒含量较高,颗粒形状也较规则,水化比表面积较高,有利于水化膜形成;外载荷会对水分迁移程度产生影响,整体上三号样水分迁移量最大,一号样次之,二号样最小。     

太平洋东部ES0103柱状样品中可溶有机质的组成变化及其早期成岩作用

利用2001年采自太平洋东部ES0103站位的多管沉积物柱状样品,采用GC/MS对沉积物中的可溶有机质(氯仿沥青"A")及其族组成(饱和烃、芳烃、非烃和沥青质)、正构烷烃、类异戊二烯烃和萜类化合物进行了定量分析,结果表明:(1)氯仿沥青"A"中的非烃较饱和烃和芳烃的含量高,反映出该海区沉积物中有机质的演化程度较低.(2)正构烷烃的碳分子数范围多为nC14～nC34,CPI值略显奇偶优势,轻重烃比值(nC23-/nC24 )较低;类异戊二烯烃的Pr/Ph值较低,显示出该海区沉积物中的烃类是在较强的还原环境下形成的低成熟烃类,其母质来源主要为大型低等水生生物.(3)总有机碳与显晶蜡产率、氯仿沥青"A"均呈明显正相关关系,表明有机质相对富集层位所处的沉积环境也有利于高蜡烃的形成,成烃演化与成岩作用阶段有较好的对应关系.而萜类化合物的Ts/Tm值在表层和深部差别不大,显示出典型的低成熟烃类的特征.由此可见, ES0103柱状样品所处海区的沉积物为在较强还原环境中形成的,其有机质演化程度较低,为早期成岩作用阶段的产物.     

Methane adsorption in the low–middle-matured Neoproterozoic Xiamaling marine shale in Zhangjiakou,Hebei

The adsorption capacity of high–over-matured shale has been widely investigated, but the adsorption capacity and the main factors influencing low–middle-matured, type II kerogen-containing, and organic-rich marine shale have been rarely explored. This research conducts organic geochemistry, mineralogical composition, adsorption isotherm tests to reveal the adsorption and main influencing factors of the different geochemistry characteristics, mineralogical compositions, temperature and pressure conditions of the low–middle-matured Neoproterozoic Xiamaling marine shale in Zhangjiakou, Hebei. The investigated shale is in a low–middle maturity stage, contains type II kerogen and is rich in organic matter. The results show that the total organic carbon (TOC) content of the Xiamaling shale is positively correlated with the methane adsorption capacity, which is the most important influencing factor on the adsorptive property of shale. The methane adsorption capacity first decreases to the minimum value as the temperature reaches 360°C equivalent Ro (EqRo = 1.0%), then increases and reaches the maximum value at 620°C (EqRo = 3.28%) and finally decreases again as the temperature rises at the last simulation stage. The mineral components exhibit an insignificant influence on the methane absorbability because of organic-matter coatings. The TOC-normalised methane adsorption capacity is positively correlated with the illite–smectite and clay-mineral contents but shows no significant correlation with brittle minerals, such as quartz. Soluble organic matter and kerogen caused the methane dissolution and adsorbtion, respectively. The strong dissolution property of the soluble organic matter is the most important cause of the larger adsorption capacity of the original shale compared with that of the residual samples. Moreover, the methane adsorption capacity of the Xiamaling shale decreases with increasing temperature, and increases with pressure below the critical pressure but decreases exceeding the critical pressure.     

Abundance, Sources and Speciation of Trace Elements in Humus-Rich Streams Affected by Acid Sulphate Soils

The behaviour of trace elements (Al, As, Cd, Co, Cr,Cu, Fe, Mn, Ni, V, Zn) was studied in five humus-richstreams (dissolved organic carbon = 14–40 mg/L)impacted by acid sulphate soils developed in marinesulphide-bearing fine-grained sediments. During heavyrainfalls in autumn, on which the study focusses, themetals Al, Cd, Co, Cu, Mn, Ni and Zn are extensivelyleached from these acidic soils (pH = 2.5–4.5), whileAs, Cr, Fe and V are not leached more strongly fromthis soil type than from areas of till and peat. Aspeciation experiment, based on anion and cationexchange of the stream waters in the field, showedthat (1) the metals Al, Cd, Co, Mn, Ni and Zn aretransported in the streams mainly as inorganiccations, (2) Cu exists mainly in cationic form but isalso to a significant extent associated with dissolvedhumic substances, (3) Fe occurs mainly in the anionicfraction explained by organic coating on colloidal Feoxyhydoxides and (4) the hydrochemistry of As, Cr andV is complex as these elements may exist in severalunquantified anionic fractions and to a minor extentin cationic species/forms. Whereas the proportion ofacid sulphate soils in the catchments had a largeimpact on concentrations levels of several elements inthe stream waters, these soils did not have a largeaffect on the speciation of elements in water.