等离子体发射光谱法分析毒砂单矿物

研究了大孔膦酸树脂对毒砂中主、次和痕量元素的吸附行为及洗脱条件,结合巯基棉和TBP柱分离技术,建立了两个分离流程。在J-A1160型多道直读光谱仪上实现了毒砂单矿物中包括主量元素Fe和As在内的20个元素测定。主量元素As和Fe的相对标准偏差(n为5～10)分别为1.03％和0.9％,其它元素在5％～11％范围。流程经实际试样分析验证,结果与化学法相符。     

CONCENTRATION AND FLUX OF CO_2, TURBULENCE FLUXES AND RADIATION BALANCE IN THE NEAR SURFACE LAYER OVER WHEAT FIELD

The gradient of CO_2 concentration, photosynthetically active radiation (PAR). net radiation.soil heat flux, profiles of wind speed, and air temperature and humidity were measured above awheat field during May and June 1985 at Beijing Agro-Ecosystems Experimental Station. Beijing,China. Fluxes of carbon dioxide, sensible heat, latent heat and momentum were calculated byusing the aerodynamic method. The observation site. equipment, calibration techniques, theerrors associated with the measurement, and the computational procedures are described. Theresults show that the diurnal variations of amplitude of CO_2 concentrations were 103.8 to 27. 0. 86.3 to 22.8 and 69.8 to 11.6 ppm: the average CO_2 concentrations were 331.5. 339.9 and 364.6 ppmfor the photosynthesis type, and 369.6. 364.0 and 375.2 ppm for the respiration type at 1. 2 and10 m above surface, respectively, from May 14 to June 15. In the daytime, transfer direction ofthe CO_2 fluxes and gradients is from air to crop canopy, and at noon (1100 to 1300 BT (BeijingTime)) the transfer rate reaches negative maximum value. At night, transfer of CO_2 fluxes andgradients is in the reversed direction and reaches positive maximum in the early morning (0400 to0600 BT). There are strong negative correlations between CO_2 flux and the net radiation (Rn),available energy (H LE). photosynthetically active radiation (PAR) and momentum flux (τ).     

塔克拉玛干沙漠中的古河道与地下水

塔克拉玛干沙漠中发育有众多的古河道，其密集区主要集中在大沙漠中部。不同河流的古河道，含水层岩性有明显差异，地下水的富水性也明显不同。但沿古河道，地下水富水性均较两侧好，水质也相对较好，多为淡水和微咸水，为在沙漠区寻找水资源提供了方向     

The influence of stiffness of the true triaxial testing machine on the rupturing and acoustic emission of rocks and its correlation with seismic activities

This paper introduces how the ratioR of the characteristic stiffness of rock samplevs. the stiffness of testing machines would influence the rupturing process and the acoustic emission (AE) on the part of the tested rock samples. Result of the experiment shows: WhenR>0.20, the rock sample would rupture abruptly; whereas whenR<0.20, the rock samples would rupture slowly. When the samples rupture abruptly, the time-dependent variation of the AE rate takes such a pattern:peak value—stable low values—rises to the maximum value (concentration)—drops back to the minimum value (quiescence)—(rises again)—ruptures. Moreover, smallerR-value tends to be associated with longer quiescence and vice versa. WhenR>1.50, no pre-failure quiescence is detected. When the rock samples rupture slowly, the variation pattern of the AE rate (after the stress has increased to more than 50% of the rupturing stress) is as the following:stable low (or high) values—rises (or drops) to its maximum (or minimum) values and then continues for some time—ruptures. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,13, 223–233, 1991. This study is supported by the Chinese Joint Seismological Science Foundation.     

本溪水洞洞穴空气CO2浓度与温、湿度的空间分布和昼夜变化特征

洞穴空气CO2浓度是影响洞穴次生化学沉积物沉积和溶蚀的重要因素之一。基于对本溪水洞洞穴空气CO2浓度、温度和湿度连续两个昼夜的系统观测结果,结合洞外大气CO2浓度、温度和湿度数据,初步分析了本溪水洞洞穴空气CO2浓度空间分布特征和昼夜变化规律：（1）洞穴空气CO2浓度自洞口开始快速增高至一定深度后趋于稳定,这个快速升高的距离与不同季节洞穴交换能力有关,秋季大约是370 m。洞穴CO2浓度稳定区的空间差异可能主要与洞穴结构和裂隙发育情况有关,在洞体变小的倚天长剑景点附近出现峰值,而在洞体变大的石瀑布景点和游客无法进入的源头区出现低谷。（2）观测期间,洞穴空气CO2浓度总体上呈递降趋势,基本上与游客数量有关。（3）在洞穴空气CO2浓度急剧上升的近洞口段,洞穴空气CO2浓度每个昼夜出现两个峰值,分别对应正午12时和午夜前后。本溪水洞洞穴空气CO2浓度的这种变化特点,受游客与工作人员的呼吸排放和洞穴与大气间的气体交换作用的双重影响。     

Water pollution in gold mining industry: a case study in Roşia Montană district, Romania

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.     

2013-2015年合肥市PM2.5重污染特征研究

综合利用中国环境监测网公布的合肥市2013-2015年大气污染物浓度数据和合肥市气象站的常规气象资料,以及激光雷达探测资料、公益性行业（气象）专项（GYHY201206011）获得的气溶胶离子成分分析结果,分析了合肥市PM_2.5重污染（日均浓度>150 μg/m3）特征。结果表明:（1）2013-2015年,合肥市PM_2.5浓度和重污染天数空间分布差异明显,东北部多、西南部少,1月各站差异最大。除了低浓度日（日均浓度≤35 μg/m3）,PM_2.5浓度都存在明显的日变化,午后低、早晚高,且随着污染程度加重,早上峰值出现时间推后。（2）重污染日臭氧以外的气态污染物浓度都显著上升。（3）重污染日常伴随着霾和轻雾天气,以稳定、小风天气为主,重污染日白天相对湿度偏高、风速偏小,600 m以下的消光系数显著增大且峰值高度降低。（4）重污染日PM_2.5中水溶性无机离子含量增高,其中NO₃-含量的占比增加最多,超过了SO₄2-的占比。      

渤海叶绿素 a 浓度与环境因素的响应关系研究

基于 2003－2018 年的遥感反演和再分析数据, 分别在时域和频域上分析了渤海海表面温度、光合有效辐射、气溶 胶厚度、风速与叶绿素 a 浓度之间的响应关系。通过傅里叶变换在频域上得到各因素之间的相关性系数, 其显著高于直接在 时域上计算得到的相关性系数, 表明由于相位差的影响, 直接在时域进行相关性分析很可能会低估各因素之间的相关性。傅 里叶变换后的频谱图显示, 叶绿素 a 浓度存在一年、半年、4 个月与季节周期; 风速与气溶胶厚度存在明显的一年和半年周 期; 海表面温度和光合有效辐射具有明显的一年周期, 半年周期较其他几个因素不明显。交叉谱分析的结果表明： 叶绿素 a 浓度和所选的环境因子都在一年周期下具有最大的交叉振幅, 表明在此频率下响应最大; 风速、气溶胶厚度、光合有效辐射 分别超前于叶绿素 a 浓度约 5.0 个月、0.2 个月、0.2 个月, 海表面温度则滞后 1.9 个月。各环境因子之间相互关联, 共同影 响叶绿素 a 浓度的时间分布。     

上海市PM_(10)浓度四季遥感模型研究

通过分析2001—2012年上海市PM_(10)浓度(由API(Air Pollution Index)转化得到)的变化规律,构建了上海市PM_(10)浓度的遥感反演模型。结果表明:1)上海市PM_(10)浓度存在季节性变化,应分别建立遥感反演模型。2)分析MODIS气溶胶光学厚度(Aerosol Optical Depth,AOD)产品与PM_(10)浓度之间的相关性发现,AOD须经过垂直和湿度订正才可与PM_(10)建立较好的关系。3)结合垂直和湿度订正分别建立的上海市PM_(10)浓度春夏秋冬四季的遥感反演模型均通过了拟合度检验,其中春季模型采用指数函数、夏季和秋季模型采用二次多项式函数、冬季采用幂函数、全年采用二次多项式函数,利用此四季模型反演上海市PM_(10)浓度具有较高的可信度。     

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.