辽宁深井承压水位潮汐响应函数的初步研究

介绍了辽宁省地震水动态监测网19口井固体潮汐响应函数的计算结果,基于M2波潮汐因子及其月离散相对误差,分析了各观测井潮汐响应函数对地壳应变的响应灵敏度、潮汐因子的动态稳定性和监测效能。结果表明:在所列19口观测井中,如果以M2波潮汐因子0.2m/10-9作为潮汐响应幅值的下限,则除甘沟子以外的18口井可用于潮汐响应函数的研究;如果以M2波潮汐因子的月离散相对误差20%作为选择观测井的上限,则除瓦房店楼房井、岫岩1井、周家井、丹东变电所井、牛四井、容2井和阜新市甘沟子等井以外的12口井可用于潮汐参数的动态特征研究。     

海潮对数字垂直摆倾斜仪记录的影响浅析

宁波地震台数字垂直摆倾斜仪记录的EW、NS向固体潮在同一数量级,与理论固体潮有较大的差异,且与浙江省其它地区地震台的记录迥然不同。该台倾斜资料与海水潮汐关系密切,用其分钟值绘出的矢量图日规律性较强。本文对此作了初步分析与探讨。     

龙门山国家地质公园飞来峰成因的新证据

近来发现四川彭州（原称彭县）、什邡一带的飞来峰是第四纪冰川作用形成的。笔者等在塘坝子、葛仙山等飞来峰的底界及周边，多次发现飞来峰是压在早更新世的冰水堆积层之上。葛仙山北寨门、丁家湾，什邡大垭口等剖面的地质现象，充分说明塘坝子、葛仙山等飞来峰是第四纪中更新世时“飞”来，压盖上去的。同时可见飞来峰与第四系之间是“冷接触”，找不到确切的断层证据。笔者等还用现有的区域地质调查资料及新的地质成果，编制了1：10万更新世时的彭县至汶川的地质剖面图，并设想了冰雪层掩盖情况。那时岷江尚未剥蚀下切，按现在标高计的5000m处，即在光光山、太子城之上约1000m的“天”上。当时应在该处出露的石炭系-二叠系石灰岩，就是塘坝子、葛仙山飞来峰的根部。塘坝子、葛仙山就是从那里被冰川作用剪切、从母体分离的石灰岩，滑动、随冰川固体流，滑移到彭县来的。笔者还从理论上阐述了塘坝子、尖峰顶、天台山等如此巨大的山体，能被冰川作用拔起、挖掉、推走的原因和根据。从而解释了飞来峰“飞”行的过程。顺理成章，合乎自然，揭开了飞来峰之迷。     

鄂尔多斯盆地能源矿产氯仿沥青Sm-Nd同位素研究

对鄂尔多斯盆地石油、煤、含铀砂岩及其围岩的氯仿沥青进行了Sm-Nd同位素研究。结果表明,盆地流体(包括深部流体)活动具有多期性,且后期的流体活动对铀矿床的形成具有重要作用;赋存于同一套地层中的含铀砂岩沥青、煤沥青及石油沥青,虽然均具有富集地幔特征,但并非同期活动的产物;东胜矿区侏罗系直罗组煤沥青和盆地西南部陈家山矿区侏罗系延安组的煤沥青,源区时代上存在较大差异,伴生沥青并非全部由煤的热演化形成,可能还存在外来流体的加入,且东胜直罗组煤的伴生沥青较延安组煤的伴生沥青来源深度更大;盆地内马岭油田的直罗组石油沥青、陈家山延安组煤层石油沥青及其煤沥青在源区特征上具有内在联系。     

GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。     

地幔流体的交代作用——来自碱性正长岩及其深源岩石包体的证据

滇西玉龙县小桥头硅化霓辉正长斑岩中,含有较多镁铁-超镁铁质深源包体岩石。经岩相学和电子探针及扫描电镜分析发现,伴随交代蚀变,寄主岩和各类镁铁-超镁铁质包体岩石中,普遍发育沿粒间和矿物晶体裂隙或解理纹贯入或穿插的黑色不透明物质,主要由微晶硅酸盐矿物和磁铁矿组成。本文研究认为,硅酸盐矿物与磁铁矿在背散射电子图像中表现为熔离特征,这种在透光显微镜下呈黑色不透明的微晶固体,是引发交代蚀变、具熔浆流体特点和超临界流体性质的地幔流体交代作用的一种微观表现。     

Evaluation of Simultaneous Analyte Leaching/Vapour Phase Introduction for Direct Osmium Isotope Ratio Measurements in Solid Samples by Double-Focusing Sector Field ICP-MS

The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g^?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of ¹⁸⁷ Os/¹⁸⁸Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate ¹⁸⁷ Os/¹⁸⁸ Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g^?1 to > 100 ng g^?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations.     

中国城市固体废弃物甲烷排放研究

The greenhouse effect of methane (CH4) is only inferior to that of carbon dioxide (CO2). As an important anthropogenic emission source, the calculation of the emission amount of CH4 from waste treatment in landfills plays an important role in compiling greenhouse gases inventory and in estimating the climate change effects caused by increasing of greenhouse gases. Based on the previous work, and according to the sampling and analysis on municipal solid waste (MSW) in typical cities, the degradable organic carbon (DOC) percentile was identified in typical cities in recent years. According to the IPCC greenhouse gases inventory guideline and default method of CH4 emission from MSW landfills, and in light of MSW managing situation in different regions, the amount of CH4 emission was calculated. The results show that the amount of CH4 emission decreases geographically from east to west and it increases temporally from 1994 to 2004 in China.     

全球水分布和气压变化对固体地球质心位置的影响

根据IERS决议,国际地球参考系的原点是地球固体部分、海洋和大气的共同质量中心因此,地球上流体部分质量分布变化会改变固体地球质心相对于国际地球参考系原点的位置变化．空间技术如SLR和GPS的观测结果表明,固体地球质心可能有幅度达10毫米的位置变化,所以给出固体地球质心位置变化以及地球物理原因已成为重要问题.本文采用了全球4000多个地面气象台站从1949到1982年的月平均降水、温度和气压值,对水和大气的分布变化引起的固体地球质心位置变化进行了计算,得出水储量分布变化对固体地球质心运动比气压分布变化有更大的贡献,固体地球质心位置变化的最大值可达4毫米．     

A coupled model for prediction of settlement and gas flow in MSW landfills

Prediction of long‐term settlement and control of gas pollution to the environment are two principle concerns during the management of municipal solid waste (MSW) landfills. The behavior of settlement and gas flow in MSW landfills is complicated due to the combined effect of mechanical deformation of the solid skeleton and continuous biodegradation of the waste. A one‐dimensional settlement and gas flow model is presented in this paper, which is capable of predicting time evolution of settlement as well as temporal and spatial distribution of gas pressure within multi‐layered landfills under a variety of operating scenarios. The analytical solution to the novel model is evaluated with numerical simulation and field measurements. The resulting efficiency and accuracy highlight the capability of the proposed model to reproduce the settlement behavior and gas flow in MSW landfills. The influences of operating conditions and waste properties on settlement and gas pressure are examined for typical MSW landfills. Copyright © 2009 John Wiley & Sons, Ltd.