粉状煤系土的物理力学特性

采用不同天气下的原位及室内试验方法,对广东云浮地区粉状煤系土的工程地质性质进行了测试,系统研究了煤系土的物理力学特性,重点论述了粉状煤系土不同干密度、不同含水率下抗剪强度和现场静力触探比贯入阻力的变化规律,提出了粉状煤系土的多项强度指标,建立了具有实用参考价值的经验性公式。研究结果为合理评价粉状煤系土的特性、路基处理和边坡处治提供理论依据,具有一定的实际意义。     

水平推力桩在大位移情况下m值的确定

根据《港口工程桩基规范局部修订》关于m法的新解释,结合某码头2根大直径钢管嵌岩桩的试桩资料总结了m值与泥面处位移 的指数关系以及m值对桩受力特性的影响,发现规范建议的m值难以适应大位移情况下的取值要求。建议通过收集大量有关大位移情况下的试桩资料,根据m值和泥面处位移 的指数关系,统计分析出在各种土质条件下相应于某一大位移时m值的取值范围,为工程设计提供依据。     

非饱和粉质粘土固结压缩特性及体变试验研究

为进一步研究与基质吸力相关联的非饱和土固结压缩特性,扩展非饱和土固结理论在工程实际中的适用性,通过分析非饱和粉质粘土水土特征曲线变化规律,对非饱和土固结变形机理进行研究。试验结果表明：非饱和土的最终沉降量仅与土骨架的压缩模量有关。对于不同饱和度的非饱和土而言,固结速度随初始饱和度的增加而减小,饱和土固结过程所需要的时间比非饱和土固结过程所需要的时间短。由于孔隙流体的压缩性导致高饱和土体的瞬时沉降比低饱和土体的瞬时沉降小,但高饱和土体的后期固结沉降受饱和度和吸力的影响,比低饱和土体要大得多。      

黑河中下游荒漠区植物多样性分布对土壤水分变化的响应

基于对黑河流域中下游荒漠区植被和土壤生境的调查分析,以土壤水分在各调查样地中的差异来反映研究区的生态水文特征,采用种的丰富度和多度来代表荒漠植物多样性研究了荒漠植物,包括隐花植物多样性分布对土壤水分变化的响应。土壤水分变化不仅直接影响着荒漠植物的多样性,而通过影响其它生境因子又间接地影响着多样性的维持。因此,如何维持中下游相对稳定的土壤水分来源是该区荒漠植物多样性保育今后所要面临的挑战。     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

Sulfur Isotopic Study of the Toyoha Deposit, Hokkaido, Japan Comparison between the Earlier-Stage and the Later-Stage Veins

Abstract: The sulfur isotopic ratios (δ³⁴S) of ore minerals from the Toyoha deposit, Hokkaido, one of the largest Pb–Zn–Ag polymetallic vein-type deposits in Japan, were studied. More than 90% of the δ³⁴S values of the studied sulfide minerals collected from the Toyoha deposit range from +5 to +9%, with an average of approximately +7% irrespective of the mineral species, veins, elevations, depth, mineralization stages and mineral assemblages. Relatively uniform δ³⁴S values obtained in this study suggest that the reduced aqueous sulfur species predominated over the oxidized sulfur in the ore solution throughout the mineralization stages. Thus, the source of sulfur for the ore sulfides is postulated to be magmatic.
The temperature obtained from the fluid inclusion study and the temperature of the sulfur isotopic geothermometer are not consistent. This suggests that each mineral precipitated under disequilibrated conditions with respect to the sulfur isotope.
The change in redox conditions presumably encountered between the mineralization stages did not account for the isotopic fluctuations since the isotopic exchanges between the oxidized and reduced aqueous sulfurs are much slower than the rate of oxidation of the ore solution.     

重质碳酸钙表面改性及充填丁苯橡胶试验研究

重质碳酸钙是一种重要的无机矿物填料，经过表面改性，可以将其由普通填料变成性能优越的功能填料。本次研究选用鄂西优质重质碳酸钙为试验样品，采用干法表面化学改性方法对重质碳酸钙实施了改性，通过测定改性重质碳酸钙的活化率、湿润接触角、固液悬浮体的粘度、白度及表面化学成分对其性能进行考察，并对改性效果进行评价。在丁苯橡胶中的应用试验显示，改性重质碳酸钙充填丁苯橡胶的性能良好，其应用前景广阔。     

塔里木河下游物种多样性与地下水位灰色关联分析

根据植被样地资料和地下水埋深观测资料, 运用灰色关联法对物种多样性与地下水埋深的关系进行了分析. 结果表明: 在塔里木河下游, 物种多样性与地下水埋深变化关系密切, Shannon-Weiner指数、 Simpson指数、 Margalef指数、 Menhinick指数、 JSW指数和JSI指数与地下水埋深之间的灰色综合关联度都在0.70以上, 其中物种多样性指数Simpson指数与地下水埋深变化的灰色综合关联度最高, 为0.866, 其关联度数值体现了地下水埋深对物种多样性变化的主导性.     

土壤及河流沉积物中Hg、As、Sb的同时测定

Hg、As、Sb是土壤和河流沉积物的常规测定项目。本文采用新型三通道原子荧光分析仪,建立了同时测定土壤和河流沉积物中这三种元素的新方法。通过优化仪器工作条件,选择合适的样品处置方法,得到Hg、As、Sb的检出限分别为0.03mg/kg、0.009mg/kg和0.03mg/kg,精密度分别为3.5%、7.8%和5.5%,准确度分别为95%～103%、91%～107%(加标回收率)和±6.4%。与现有测定方法相比,本方法的样品消化完全,实验简便,分析速度和准确度高,能充分满足分析要求。     

土动力学与岩土地震工程研究进展

指出了土动力学与岩土地震工程领域课题的特点与研究方法,并从土的动力特性与本构理论、动荷载作用下饱和土的液化、岩土体的地震变形与稳定性分析、土与结构动力相互作用、数值分析方法、物理模型试验与技术6个方面评述了国内外研究进展与发展趋势,建议了应着重研究的学科前沿与关键科学问题,希望能对今后的科研工作有一定的启迪作用