Isotopic evidence of TSR origin for natural gas bearing high H_2S contents within the Feixianguan Formation of the northeastern Sichuan Basin, southwestern China

Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be…     

Erratic judgements: re-evaluating solutional erosion rates of limestones using erratic-pedestal sites, including Norber, Yorkshire

The re-interpretation of surface karst landforms in Northern England has led to a re-examination of well-known erratic-pedestal sites that were the origin for karst denudation rates applied extensively, on the supposition that erratics protect underlying limestone from rainwater solution. Height of the pedestal has been used to calculate long-term solutional-lowering, as much as 50 cm in 15 ka (33.3 mm/ka) from UK sites. The sites include Norber and Scar Close, Yorkshire, UK. This paper shows that the sites have been misinterpreted, in particular at Norber where the erratics lie on a pre-existing structurally stepped surface. Norber and several other sites also experience much mechanical weathering, in relatively weak, well-fractured limestones, a process which must be distinguished from solution. Sites in strong, less-fractured limestones demonstrate lower rates, which are sounder indications of land surface lowering. Some pedestals have been confirmed as partly resulting from solutional weathering in surrounding soil and vegetation. Re-evaluation reduces solution rates to 3–13 cm in 15 ka. Applying such rates has profound implications for understanding limestone landscapes, challenging orthodox views.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

Semi‐analytical solution to one‐dimensional consolidation for unsaturated soils with semi‐permeable drainage boundary under time‐dependent loading

This paper presents semi‐analytical solutions to Fredlund and Hasan's one‐dimensional consolidation of unsaturated soils with semi‐permeable drainage boundary under time‐dependent loadings. Two variables are introduced to transform two coupled governing equations of pore‐water and pore‐air pressures into an equivalent set of partial differential equations, which are easily solved by the Laplace transform. The pore‐water pressure, pore‐air pressure and settlement are obtained in the Laplace domain. Crump's method is adopted to perform the inverse Laplace transform in order to obtain semi‐analytical solutions in time domain. It is shown that the present solutions are more general and have a good agreement with the existing solutions from literatures. Furthermore, the current solutions can also be degenerated into conventional solutions to one‐dimensional consolidation of unsaturated soils with homogeneous boundaries. Finally, several numerical examples are provided to illustrate consolidation behavior of unsaturated soils under four types of time‐dependent loadings, including instantaneous loading, ramp loading, exponential loading and sinusoidal loading. Parametric studies are illustrated by variations of pore‐air pressure, pore‐water pressure and settlement at different values of the ratio of air–water permeability coefficient, depth and loading parameters. Copyright © 2017 John Wiley & Sons, Ltd.     

Torsional dynamic response of a large‐diameter pipe pile in viscoelastic saturated soil

An analytical solution is developed in this paper to investigate the dynamic response of a large‐diameter end‐bearing pipe pile subjected to torsional loading in viscoelastic saturated soil. The wave propagation in saturated soil and pile are simulated by Biot's two‐phased linear theory and one‐dimensional elastic theory, respectively. The dynamic equilibrium equations of the outer soil, inner soil, and pile are established. The solutions for the outer and inner soils in frequency domain are obtained by Laplace transform technique and the separation of variables method. Then, the dynamic response of the pile is obtained on the basis of the perfect contacts between the pile and the outer soil as well as the inner soil. The results in this paper are compared with that of a solid pile in elastic saturated soil to verify the validity of the solution. Furthermore, the solution in this paper is compared with the classic plane strain solution to verify the solution further and check the accuracy of the plane strain solution. Numerical results are presented to analyze the vibration characteristics and illustrate the effect of the soil parameters and the geometry size of the pile on the complex impedance and velocity admittance of the pile head. Finally, the displacement of the soil at different depth and frequency is analyzed. Copyright © 2014 John Wiley & Sons, Ltd.     

An analytical solution for deforming twin‐parallel tunnels in an elastic half plane

The interaction between twin‐parallel tunnels affects the tunnelling‐induced ground deformation, which may endanger the nearby structures. In this paper, an analytical solution is presented for problems in determining displacements and stresses around deforming twin‐parallel tunnels in an elastic half plane, on the basis of complex variable theory. As an example, a uniform radial displacement was assumed as the boundary condition for each of the two tunnels. Special attention was paid to the effects of tunnel depth and spacing between the two tunnels on the surface movement to gain deep insight into the effect of the interaction between twin‐parallel tunnels using the proposed analytical approach. It is revealed that the influence of twin tunnel interaction on surface movements diminishes with both the increase of the tunnel depth and the spacing between the two tunnels. The presented analytical solution manifests that, similar to most of the existing numerical results, the principle of superposition can be applied to determine ground deformation of twin‐parallel tunnels with a certain large depth and spacing; otherwise, the interaction effect between the two tunnels should be taken into account for predicting reliable ground movement. Copyright © 2014 John Wiley & Sons, Ltd.     

Displacement analytical prediction of shallow tunnel based on unified displacement function under slope boundary

For slope condition of ground surface, the asymmetrical deformation about the vertical center line and the horizontal center line of the tunnel cross section can be formed. A unified displacement function expressed by the Fourier series is presented to express the asymmetrical deformation of the tunnel cross section. Five basic deformation modes corresponding to the expansion order 2 are a complete deformation mode to reflect deformation behaviors of the tunnel cross section under slope boundary. Such this complete displacement mode is implemented into the complex variable solution for analytically predicting tunneling-induced ground deformation under slope boundary. All of these analytical solutions are verified by good agreements of the comparison between the analytical solutions and finite element method results. A parameter study is carried out to investigate the influence of deformation modes of the tunnel cross section, geometrical conditions of the tunnel and the slope angle, and “Buoyancy effect” on the displacement field. Finally, the proposed method is consistent with measured data of the Hejie tunnel in China qualitatively. The presented solution can provide a simplified indication for evaluating the ground deformation under slope condition of ground surface.     

A multidirectional semi‐analytical method for analysis of laterally loaded pile groups in multi‐layered elastic strata

A semi‐analytical method for calculating the response of single piles and pile groups subjected to lateral loading is developed in this paper. Displacements anywhere in the soil domain are tied to the displacements of the piles through decay functions. The principle of virtual work and the calculus of variations are used to derive the governing differential equations that describe the response of the piles and soil. The eigenvalue method and the finite difference technique are used to solve the system of coupled differential equations for the piles and soil, respectively. The proposed method takes into account the soil surface displacement along and perpendicular to the loading direction and produces displacement fields that are very close to those produced by the finite element method but at lower computational effort. Compared with the previous method that considered only the soil displacement along the loading direction, accounting for the multi‐directional soil displacement field produces responses for the piles and soil that are closer to those approximated by the finite element method. Copyright © 2016 John Wiley & Sons, Ltd.