Tracing the source of metals in Geogas from metal deposits in a loess-covered region北大核心CSCD

In order to test the distribution characteristics of metallogenic elements and the application effectiveness of the traee elements and REE for tracing the source of Geogas anomaly, the distribution characteristics of metallogenetic elements .trace elements and REE in different media of the Jiaolongzhang Pb-Zn deposit underneath the loess have been studied in this paper. Results indicate that the distribution characteristics of Geogas anomalous elements over the concealed orebodies are coincided with those of the enriched elements of ores, while the distribution characteristics of trace elements and REE in background Geogas samples are distinctly different from those of other media, indicating that the source of background Geogas materials is influenced by various factors( geological bodies, lab environment and blank reagent). The similar distribution characteristics of the trace elements in the Geogas samples of anomalous areas and in the ores suggested that Geogas anomaly is affected by concealed orebodies in depth. The difference between REE patterns of the Geogas samples of the anomalous area and those of other solid media might be caused by inadequate analytical precision and low collecting efficiency of the instrument. It is believed that the REE tracing method can provide the information on the source of Geogas anomaly if the analytical precision and collecting efficiency of REE could be constantly increased.     

北祁连地区中寒武世岩相古地理研究

现今地处造山带的北祁连地区在中寒武世时期拉张的构造背景下海域进一步拓宽。通过对北祁连地区中寒武统地层野外调查及室内分析研究,在"构造控盆、盆控相"的思路控制下,以沉积岩性、结构-构造、古生物组合等为基础,在优势相原则的指导下,共划分出浅海陆棚相、半深海相、深海盆地相3种沉积相类型。结合前人的研究资料,编制北祁连地区中寒武世的沉积构造格架及沉积盆地类型图,分析其空间配置关系。在此基础上,采用造山带岩相古地理编图方法,恢复与重建研究区的古地理面貌,编制相应的古地理图。     

新疆塔县达布达尔地区二叠系神仙湾组杂砂岩沉积构造背景分析

新疆塔县达布达尔地区二叠系神仙湾组位于塔阿西构造混杂岩带南侧,总体为一套深海复理石建造,主要以杂砂岩为主。源区岩石没有经过充分的搬运、分选,成熟度比较低。杂砂岩的稀土元素特征表现为轻稀土元素富集和Eu亏损明显的特征,与典型的后太古宙页岩和上地壳非常相似。微量元素含量也接近于大陆上地壳值,说明杂砂岩中的物源来自上地壳。沉积环境分析表明,杂砂岩母岩原岩为大量长英质火成物质和少量沉积物,其形成于深海厌氧环境。大地构造背景分析表明,杂砂岩物源区的构造背景以大陆岛弧为主,兼具活动大陆边缘的性质。结合区域地质构造背景,认为下-中二叠统神仙湾组为裂陷盆地沉积。     

鄂尔多斯盆地杭锦旗探区二叠系下石盒子组盒1段致密砂岩气层测井评价方法

通过储层"四性"关系研究,分析了鄂尔多斯盆地北部杭锦旗探区致密砂岩储层岩性对物性的控制作用及测井曲线对储层岩性、物性和含气性的响应特征。认为二叠系下石盒子组盒1段砂岩石英含量、粒度和孔隙结构是影响物性和含气性的主要因素,储层"四性"关系具有砂岩粒度与石英含量控制物性、物性控制含气性的基本特点。利用交汇图版法与双孔隙度曲线叠合法对研究区二叠系下石盒子组盒1段气层进行了综合识别。根据储层的岩性、物性、孔隙结构等参数,结合单井测试产能特征,将杭锦旗探区二叠系下石盒子组盒1段气层划分为3类进行综合评价,气层以Ⅱ类为主,其次为Ⅰ类。     

琼东南盆地深水区新近系海底扇沉积特征与资源潜力

综合利用钻井、岩心、薄片及分析化验资料研究了琼东南盆地深水区新近系海底扇沉积特征,并利用最新的三维地震资料,通过井震精细标定、多属性融合技术、方差体切片、三维地貌砂体镂空等综合技术手段,精细刻画了海底扇砂体的空间分布特征。研究结果表明,深水区新近系海底扇是由陆架区的砂体滑塌并二次搬运形成,形成过程具有多期次性。受不同物源的影响,海底扇岩性和物性存在较大的差异。海底扇岩性及沉积构造具有砂质滑塌、碎屑流、浊流和深水底流改造的特征。海底扇的沉积微相、厚度、砂泥比和砂泥岩空间配置关系直接控制了地震振幅反射强度和频率的变化。砂体纵向叠置,横向连片,并被后期泥质水道切割分块形成多个岩性圈闭。综合分析认为,深水区海底扇砂体发育区烃源条件优越,储盖配置关系和圈闭条件良好,具备形成大中型岩性油气藏的有利条件,具有较大的油气勘探潜力。     

Numerical simulation of groundwater and early warnings from the simulated dynamic evolution trend in the plain area of Shenyang,Liaoning Province (P.R. China)

Groundwater level is the most direct factor reflecting whether groundwater is in a virtuous cycle. It is the most important benchmark for deciding whether a balance can be struck between groundwater discharge and recharge and whether groundwater exploitation will trigger problems pertinent to environment, ecology and environmental geology. According to the borehole and long-term monitoring wells data in the plain area of Shenyang, a numerical groundwater model is established and used to identify and verify the hydrogeological parameters and balanced items of groundwater. Then the concept of red line levels, the control levels of groundwater is proposed, the dynamic evolution trend of groundwater under different scenarios is analyzed and predicted and groundwater alerts are given when groundwater tables are not between the lower limit and the upper limit. Results indicated: (1) The results of identification and verification period fitted well, and the calculation accuracy of balanced items was high; (2) with the implementation of shutting wells, groundwater levels in urban areas of Shenyang would exceed the upper limit water level after 2020 and incur some secondary disasters; (3) under the recommended scenario of water resources allocation, early-warnings for groundwater tables outside the range would occur in the year of 2020, 2023, 2025 respectively for successive wet, normal and dry years. It was imperative to reopen some groundwater sources and enhance real-time supervision and early-warning to prevent the occurrence of potential problems.     

Dynamic assessment of pollution risk of groundwater source area in Northern China

Based on the dynamic analysis and research of pollution risk of groundwater sources, this paper creates the dynamic assessment method of pollution risk of groundwater source area under the theory of “source-pathway-receptor”, and applies this method to one typical fissure karst groundwater source area in northern China. Following the 30-year petroleum pollutant migration simulation and pollution risk assessment of groundwater source area, this study finds that the very high risk zone is mainly located in Q Petrochemical Company and the surrounding area and the area adjacent to River Z. Within this period of thirty years, the pollution risk of groundwater source area has showed a dynamic trend that features an inverted “V” shape. The ratio of very high risk zone to the total area will be 18.1%, 17.47% and 16.62% during the tenth year, the twentieth year and the thirtieth year separately, and will reach the highest level of 19.45% during the fifteenth year. Meanwhile, the vertical migration distance of pollutant centre concentration changed from the surface soil at the outset to the deepest point of about 250 meters underground during the tenth year. The results of this risk assessment indicate the dynamic feature of pollution risk. The dilution, degradation and migration of petroleum pollutants in groundwater system contribute to an ultimate decline in pollution risk.     

Nano-scale pore structure and fractal dimension of organic-rich Wufeng-Longmaxi shale from Jiaoshiba area,Sichuan Basin: Investigations using FE-SEM,gas adsorption and helium pycnometry

Much attention have been recently paid to the upper Ordovician Wufeng shale (O₃w) and lower Silurian Longmaxi shale (S₁l) in the Jiaoshiba area of Sichuan Basin, which is now the largest producing shale gas field in China. Field emission scanning electron microscopy (FE-SEM), low pressure gas (N₂ and CO₂) adsorption, helium pycnometry, X-ray diffraction and geochemical analyses were performed to investigate the pore structure and fractal dimension of the pores in O₃w-S₁l shale formation in the Jiaoshiba area. FE-SEM images show that organic matter (OM) pores are dominant in the organic-rich samples and these pores are often irregular, bubble-like, elliptical and faveolate in shape, while in organic-poor samples, limited and isolated interparticle (interP), intraparticle (intraP) and OM pores are observed. Reversed S-shaped isotherms obtained from nitrogen adsorption are type Ⅱ, and hysteresis loops indicate that the shape of micropore in the samples is slit-or plate-like. BET surface areas and total pore volume vary from 12.2 to 27.1 m²/g and from 1.8 × 10⁻² to 2.9 × 10⁻² cm³/g, with an average of 19.5 m²/g and 2.3 × 10⁻² cm³/g, respectively. Adsorption volume from both N₂ and CO₂ adsorption increases with respect to TOC contents. Porosities obtained from helium porosimetry are comparable with these from gas (CO₂ and N₂) adsorption in O₃w-S₁l shale. However, porosity determined by quantitative FE-SEM analysis is much smaller, which is mainly related to limited resolution and the small areas of investigation.Based on the Frenkel-Halsey-Hill (FHH) model of low-pressure N₂ adsorption, fractal dimensions of the pores varied from 2.737 to 2.823. Relationships between pore structure parameters and TOC content, mineral composition and fractal dimension reveal that the fractal dimension is mainly associated with micropores. Samples with higher TOC content, higher quartz content and lower clay content tend to contain more heterogeneous micropores, resulting in higher fractal dimensions and more complicated pore structure in shales. Therefore, fractal dimension is an effective parameter to reflect the complexity of pore structure and the degree of micropore development in O₃w-S₁l shale.     

Early Mesozoic Southward Subduction of the Eastern Mongol–Okhotsk Oceanic Plate: Evidence from Zircon U–Pb–Hf Isotopes and Whole‐rock Geochemistry of Triassic Granitic Rocks in the Mohe Area,NE China

In this paper, we present new U–Pb zircon ages, Hf isotope data and major and trace elements for Early Mesozoic granitic rocks in Mohe area in the Erguna Massif of northeast China to elucidate the southward subduction of the eastern Mongol–Okhotsk Oceanic plate in Early Mesozoic. Zircons from two representative intrusions, syenogranites and monzogranites, in the Mohe area are euhedral–subhedral in shape, display oscillatory growth zoning in cathodoluminescence (CL) images, and have Th/U ratios of 0.10–0.72, and in combination these features indicating that the zircons are of igneous origin. U–Pb zircon dating results demonstrate that the syenogranites formed at 245.1 ± 1.4 Ma and monzogranites formed at 212.2 ± 1.7 Ma. These granitic rocks are characterized by high SiO₂, Al₂O₃ and (Na₂O + K₂O), low TFeO, MgO, TiO₂ and P₂O₅ concentrations, belonging to the high‐K calc‐alkaline series. They are enriched in LREE and large ion lithophile elements (e.g., Rb, K, and Sr), depleted in HREE and high field strength elements (e.g., Nb, Ta, Th, and Ti), as well as very weak negative Eu anomalies (Eu/Eu* = 0.48 ~ 1.01). Their zircon εHf(t) values range from −7.9 to −2.0 and range from 0.20 to 0.49, in response to their two‐stage Hf model ages (T_DM2) range from 1.40 Ga to 1.77 Ga range from 0.94 Ga to 1.24 Ga, respectively, indicating that primary magmas of syenogranites were derived from partial melting of newly accreted juvenile crustal material that formed from the enriched mantle during the Mesoproterozoic, monzogranites are generated by partial melting of newly accreted juvenile crustal material that formed from the depleted mantle during the Meso‐ to Neoproterozoic. We conclude, therefore, that the early Mesozoic granitic rocks of the Mohe area are associated with the continuous southward subduction of the Mongol–Okhotsk oceanic plate rather than the Paleo‐Asian and circum‐Pacific tectonic regimes.     

The simulation of LUCC based on Logistic-CA-Markov model in Qilian Mountain area,China

The Qilian mountain area was examined for using the Logistic-CA-Markov coupling model combined with GIS spatial analyst technology to research the transformation of LUCC, driving force system and simulate future tendency of variation. Results show that:(1) Woodland area decreased by 12.55%, while grassland, cultivated land, and settlement areas increased by 0.22%, 7.92%, and 0.03%, respectively, from 1986 to 2014. During the period of 1986 to 2000, forest degradation in the middle section of the mountain area decreased by 1,501.69 km~2. Vegetation cover area improved, with a net increase of grassland area of 38.12 km~2 from 2000 to 2014.(2) For constructing the system driving force, the best simulation scale was 210m×210m. Based on logistic regression analysis, the contribution(weight) of composite driving forces to land use and cover change was obtained, and the weight value was more objectively compared with AHP and MCE method.(3) In the natural scenarios, it is predicted that land use and cover distribution maps of Qilian mountain area in 2028 and 2042, and the Lee-Sallee index test was adopted. Over the next 27 years(2015–2042), farmland, woodland, grassland, settlement areas show an increasing trend, especially settlements with an obvious change of 0.56%. The area of bare land will decrease by 0.89%. Without environmental degradation, tremendous structural change of LUCC will not occur, and typical characteristic of the vertical zone of the mountain would remain. Farmland and settlement areas will increase, but only in the vicinity of Qilian and Sunan counties.