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61.
62.
A. Ankilov A. Baklanov M. Colhoun K. -H. Enderle J. Gras Yu. Julanov D. Kaller A. Lindner A. A. Lushnikov R. Mavliev F. McGovern T. C. O'Connor J. Podzimek O. Preining G. P. Reischl R. Rudolf G. J. Sem W. W. Szymanski A. E. Vrtala P. E. Wagner W. Winklmayr V. Zagaynov 《Atmospheric Research》2002,62(3-4)
During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles. 相似文献
63.
Xiaorong Luo 《Earth and Planetary Science Letters》2002,201(2):431-446
Natural hydrofracturing caused by overpressure plays an important role in geopressure evolution and hydrocarbon migration in petroliferous basins. Its mechanism is quite well understood in the case of artificial hydraulic fracturing triggered by high-pressure fluid injection in a well. This is not so for natural hydraulic fracturing which is assumed to initiate as micro-cracks with large influence on the permeability of the medium. The mechanism of natural hydraulic cracking, triggered by increasing pore pressure during geological periods, is studied using a fracturing model coupled to the physical processes occurring during basin evolution. In this model, the hydraulic cracking threshold is assumed to lie between the classical failure limit and the beginning of dilatancy. Fluid pressure evolution is calculated iteratively in order to allow dynamic adjustment of permeability so that the fracturing limit is always preserved. The increase of permeability is interpreted on the basis of equivalent fractures. It is found that fracturing is very efficient to keep a stress level at the rock’s hydraulic cracking limit: a fracture permeability one order of magnitude larger than the intrinsic permeability of the rock would be enough. Observations reported from actual basins and model results strongly suggest that natural hydraulic cracking occurs continuously to keep the pressure at the fracturing limit under relaxed stress conditions. 相似文献
64.
银川市初夏气溶胶粒子谱分布特征 总被引:4,自引:5,他引:4
利用美制APS—3310A型激光粒谱仪,在中国西北城市银川对大气气溶胶粒子进行现场观测,结合气象条件,并通过理论计算分析,给出了银川市初夏大气气溶胶的日变化特征、3种不同粒径粒子分布特点及飘尘谱分布特征,以期为银川市大气污染总量控制方案及对策提供科学依据。 相似文献
65.
粘粒含量对南京粉细砂液化影响的试验研究 总被引:16,自引:1,他引:16
南京粉细砂是一种以片状颗粒成分为主的粉细砂,与通常的圆形颗粒石英砂有一定区别,片状颗粒成分使得南京粉细砂具有各向异性的性质。通过对不同粘粒含量的南京粉细砂进行液化试验,分析其试验结果发现:对于粘粒含量ρc=5%、10%和15%三种情况,在均压固结情况下,当南京粉细砂达到初始液化时,采用变形标准和孔压标准是一致的;而偏压固结时,只能采用变形标准作为南京粉细砂达到初始液化的标准,此时振动孔压仅达到围压的50%-70%。粘粒含量对南京粉细砂的抗液化强度影响很大,随粘粒含量增加,在不同固结比时,其抗液化强度并不是单调变化,而是在粘粒含量ρc=10%左右处于一个低谷,其抗液化强度最低。 相似文献
66.
We compare flux and concentration footprint estimates of athree-dimensional Lagrangian stochastic dispersion modelapplying backward trajectories with the results of ananalytical footprint model by Kormann and Meixner.The comparison is performed for varying stability regimesof the surface layer as well as for different measurementheights. In general, excellent correspondence is found. 相似文献
67.
铂族元素迁移富集机理的新探 总被引:2,自引:1,他引:2
在岩浆及高温热液中,拍族元素以纳米液态铂族元素单质、铂族元素与其它金属元素的纳米液态合金、纳米液态铂族元素的硫、砷化物迁移。在中、低温热液及表生条件下,除呈上述固态纳米铂族矿物随流体迁移外,还呈配合物形式迁移。然后它们在合适的条件下沉淀富集形成矿床。此外,还讨论了铂族元素与金地球化学条件的异同。 相似文献
68.
Frédérick Delay Hélène Housset-Resche Gilles Porel Ghislain de Marsily 《Mathematical Geology》1996,28(1):45-71
A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed. 相似文献
69.
The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface. 相似文献
70.
A Simple Parameterisation for Flux Footprint Predictions 总被引:9,自引:6,他引:9
Flux footprint functions estimate the location and relative importance of passive scalar sources influencing flux measurements
at a given receptor height. These footprint estimates strongly vary in size, depending on receptor height, atmospheric stability,
and surface roughness. Reliable footprint calculations from, e.g., Lagrangian stochastic models or large-eddy simulations
are computationally expensive and cannot readily be computed for long-term observational programs. To facilitate more accessible
footprint estimates, a scaling procedure is introduced for flux footprint functions over a range of stratifications from convective
to stable, and receptor heights ranging from near the surface to the middle of the boundary layer. It is shown that, when
applying this scaling procedure, footprint estimates collapse to an ensemble of similar curves. A simple parameterisation
for the scaled footprint estimates is presented. This parameterisation accounts for the influence of the roughness length
on the footprint and allows for a quick but precise algebraic footprint estimation. 相似文献