低荧光防塌沥青及低荧光特效封堵防塌降滤失剂的研制与应用

研发了一种具有优良防塌效果的低荧光钻井液用井壁稳定剂，提高石油沥青磺化度，解决降低产品荧光级别的新工艺，突破因荧光干扰测录井导致油储层被误判、漏判的关键技术，磺化反应后期，引入提高产品综合性能的特种材料进行交联反应。介绍了低荧光防塌沥青LF—TEX-1及低荧光特效封堵防塌降滤失剂FSL-1的关键技术原理和生产工艺流程，并对这两种处理剂的性能测试结果进行了分析。实际生产应用表明，他们具有明显的封堵、降失水功能。     

城市垃圾填埋场粘土基防渗浆材的实验研究

文章研制了一种低渗透系数并对污染物有一定吸附阻滞作用的浆材,即膨润土-粉煤灰-水泥(BFS)浆材,用于垃圾填埋场以防治渗沥液渗漏污染周围地下水和土壤。通过正交试验优选出了以膨润土为主的配方:膨润土22%~25%、粉煤灰20%~23%、水泥15%~18%、纯碱1.2%~1.4%、稀释剂TMH加量0.3%~0.45%。该浆材结实率大于99.6%,固结体28d渗透系数小于0.8×10-7cm/s,无侧限抗压强度小于2.0MPa,渗透系数比一般水泥粘土浆材降低约2个数量级。通过采自长春某垃圾填埋场的渗沥液进行固结体的渗透试验,该浆材的固结体对CODCr、氨氮和磷的吸附阻滞率均达到了82%以上。文章的创新点在于浆材配方的选材不但考虑了降低固结体渗透系数,使其符合规范要求,而且考虑了材料成分对渗沥液中污染物的吸附阻滞作用,同时降低了固结体的抗压强度和脆性,使其有一定的塑性和韧性,以适应填埋场的地基变形。     

高含沙泥浆模型试验及其糙率纠正

国内许多年久失修的地下设施在废弃时面临巨大的安全隐患,而利用高含沙泥浆进行填充是有效而经济的方法。在进行填充前,对管道填充的可行性需要建立模型进行试验研究。在模型试验研究时遇到的模型不相似问题是影响模型试验准确性的重要因素,因此要对试验所得数据进行修正。在本次研究中我们通过对于试验所得流速数据进行糙率纠正解决了糙率不相似的问题。     

The Temaguessine Fe-cordierite orbicular granite (Central Hoggar, Algeria): U–Pb SHRIMP age, petrology, origin and geodynamical consequences for the late Pan-African magmatism of the Tuareg shield

The Temaguessine high-level subcircular pluton is intrusive into the LATEA metacraton (Central Hoggar) Eburnian (2 Ga) basement and in the Pan-African (615 Ma) granitic batholiths along a major NW–SE oriented major shear zone. It is dated here (SHRIMP U–Pb on zircon) at 582 ± 5 Ma. Composed of amphibole–biotite granite and biotite syenogranite, it comprises abundant enclaves: mafic magmatic enclaves, country-rock xenoliths and remarkable Fe-cordierite (#Fe = 0.87) orbicules. The orbicules have a core rich in cordierite (40%) and a leucocratic quartz–feldspar rim. They are interpreted as resulting from the incongruent melting of the meta-wacke xenoliths collapsed into the magma: the breakdown of the biotite + quartz assemblage produced the cordierite and a quartz–feldspar minimum melt that is expelled, forming the leucocratic rim. The orbicule generation occurred at T < 850° and P < 0.3 GPa. The Fe-rich character of the cordierite resulted from the Fe-rich protolith (wacke with 4% Fe₂O₃ for 72% SiO₂). Strongly negative ε_Nd (−9.6 to −11.2), Nd T_DM model ages between 1.64 and 1.92 Ga, inherited zircons between 1.76 and 2.04 Ga and low to moderately high I_Sr (0.704–0.710) indicate a Rb-depleted lower continental crust source for the Temaguessine pluton; regional considerations impose however also the participation of asthenospheric material. The Temaguessine pluton, together with other high-level subcircular pluton, is considered as marking the end of the Pan-African magma generation in the LATEA metacraton, resulting from the linear delamination along mega-shear zones, allowing asthenospheric uprise and melting of the lower continental crust. This implies that the younger Taourirt granitic province (535–520 Ma) should be considered as a Cambrian intraplate anorogenic event and not as a very late Pan-African event.     

1.8 Ga Svecofennian post-collisional shoshonitic magmatism in the Fennoscandian shield

At least 14 small (1–11 km across) 1.8 Ga Svecofennian post-collisional bimodal intrusions occur in southern Finland and Russian Karelia in a 600-km-long belt from the Åland Islands to the NW Lake Ladoga region. The rocks range from ultramafic, calc-alkaline, apatite-rich potassium lamprophyres to peraluminous HiBaSr granites, and form a shoshonitic series with K₂O+Na₂O>5%, K₂O/Na₂O>0.5, Al₂O₃>9% over a wide spectrum of SiO₂ (32–78%). Although strongly enriched in all rocks, the LILE Ba and Sr and the LREE generally define a decreasing trend with increasing SiO₂. Depletion is noted for HFSE Ti, Nb and Ta. Available isotopic data show overlapping values for lamprophyres and granites within separate intrusions and a cogenetic origin is thus not precluded. Initial magmas (Mg#>65) in this shoshonitic association are considered to be generated in an enriched lithospheric mantle during post-collisional uplift some 30 Ma after the regional Svecofennian metamorphic peak. However, prior to the melting episode, the lithospheric mantle was affected by carbonatite metasomatism; more extensively in the east than in the west. The melts generated in the more carbonate-rich mantle are extremely enriched in P₂O₅4%, F12,000 ppm, LILE: Ba9000 ppm, Sr7000 ppm, LREE: La600 ppm and Ce1000 ppm. The parental magma underwent 55–60% fractionation of biotite+clinopyroxene+apatite+magnetite+sphene whereupon intermediate varieties were produced. After further fractionation, 60–80%, of K-feldspar+amphibole+plagioclase±(minor magnetite, sphene and apatite), leucosyenites and quartz-monzonites were formed. In the west, where the source was less affected by carbonatite metasomatism, calc-alkaline lamprophyres (vogesites, minettes and spessartites) and equivalent plutonic rocks (monzonites) were formed. Removal of about 50% of biotite, amphibole, plagioclase, magnetite, apatite and sphene produced peraluminous HiBaSr granites. The impact of crustal assimilation is considered to be low. At about 1.8 Ga, the post-collisional shoshonitic magmatism brought juvenile material, particularly enriched in alkalis, LILE, LREE and F, into the crust. Although areally restricted, the regional distribution of the post-collisional intrusions may indicate that larger volumes of 1.8 Ga juvenile material resides in unexposed parts of the crust.     

Geothermal energy prospects in Brazil: A preliminary analysis

Results of geothermal gradient measurements in 44 localities in Brazil are presented. The Precambrian shield areas are found to be characterized by relatively low temperature gradients in the range 6 to 20°C/km while younger sedimentary basins are characterized by gradients in the range 15 to 35°C/km. An inverse correlation between geothermal gradient and tectonic age has been observed. This as well as the favourable hydrological conditions suggest that the best sites for extraction of geothermal energy in Brazil are the younger sedimentary basins. The Parana Basin is found to offer at present the best site for extraction of geothermal energy in Brazil. Preliminary examination of the temperature distributions in the major aquifer (Botucatu sandstone) suggest that this aquifer contains substantial quantities of warm waters in the temperature range 40 to 90°C. The water layer in this confined aquifer is in convective motion and can be considered as a low enthalphy geothermal system. Many of the routine uses to which geothermal waters are put, such as space heating and soil warming, are not applicable in Brazil mainly because of the favourable climatic conditions. Conversion of this geothermal energy into electrical energy is also unlikely to be economical. Hence we do not consider the Parana Basin geothermal system as an independent ec9nomically exploitable energy resource. However, a few other applications are pointed out where geothermal waters can be used as a supplementary or supporting energy source in increasing the efficiency of economically viable systems utilizing hot waters.     

盾构机全站仪激光导向模式误差灵敏度分析

通过对盾构机全站仪激光导向系统的测量原理研究,并对盾构坐标与施工坐标系的旋转模型转换原理分析,建立盾构姿态参数与坐标旋转模型的关系。然后通过全站仪测量激光标靶棱镜和切口坐标与激光标靶相对位置的误差分析得到相关结论。     

东北非与中国胶东造山型金矿对比及对非洲找矿勘查的启示

东北非是一个快速兴起的世界级金矿省,发育大量造山型金矿床.选择东北非努比亚地盾代表性造山型矿床进行总结梳理,认为区内金矿成矿可能受控于努比亚地盾地块拼帖后挤压/压扭向张扭剪切转换的过程,绿片岩相-角闪岩相变质基性火山岩是主要赋矿围岩,剪切带(断层)为主要控矿构造.通过对比,发现努比亚地盾矿集区与胶东矿集区类似,在大规模...     

软土隧道盾构出洞灾害的渗流应力耦合分析

对盾构出洞口涌水涌砂灾害问题作了分析。利用Midas-GTS软件,建立了盾构出洞施工的有限元模型。考虑盾构出洞施工的渗流-应力耦合效应,研究了盾构工作井外加固土体前方高水位工况下,地下水绕加固土体下卧土层的渗流规律以及加固土体前方原状土的沉降规律。研究结果表明,在假定井外加固土体完全隔水情况下,洞门涌水涌砂灾害的发生与否受到土体加固长度、井外地下水等因素影响;土体加固长度的增加对工程安全有利,但成本较高;地下水位的降低能有效减小盾构出洞洞门涌水灾害的发生,需综合考虑工程安全性、经济性和工期等来确定合理的施工参数。     

涡阳花沟区28-5煤田孔粘钻事故的处理实践

介绍了涡阳花沟区28-5煤田孔粘钻事故的原因和处理方法,加强对泥浆比重、滤失性和流变性能的调整,对预防孔内发生粘钻事故有积极作用。