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131.
Initial coagulation rates of colloidal hematite (-Fe2O3) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 104 in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G
ads
0
>G
coul
0
) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10–7 to 10–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10–3 to 10–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems. 相似文献
132.
The limitations of pulp chemistry measurements in the flotation of a platinum group mineral (PGM) bearing Merensky ore were demonstrated in Part 1 of this article. In this paper the importance of the contribution of the froth structure due to changing froth stability is analysed using the batch flotation data. The effects of mild steel (MS) and stainless steel (SS) milling media and the addition of copper sulphate on the flotation performance of the sulphide minerals in Merensky ore have been evaluated in relation to the changes in stability of the froth phase. The effects of pulp chemistry and froth stability on the flotation of sulphide minerals were distinguished by using two different rate constants (kt and kw). The rate constant (kw) calculated as a function of cumulative water recovery was used to describe characteristics of froth phase and kt was calculated as a function of flotation time. The results revealed that the type of grinding media and copper sulphate addition had an interactive effect on the froth stability. While mild steel (MS) milling increased the froth stability due to the presence of hydrophilic iron hydroxides and colloidal metallic iron, the addition of copper sulphate reduced the stability, especially with stainless steel (SS) milling. Copper sulphate addition had a dual role in the flotation of Merensky ore in that it caused destabilisation of the froth zone as well as activation of selected sulphide minerals. The dominant effect was found to depend on the type of milling media and floatability of the mineral in question and this work has demonstrated the importance of using a combination of measurements to evaluate flotation performance holistically. 相似文献
133.
Strength and stability of frictional sliding of gabbro gouge at elevated temperatures 总被引:7,自引:1,他引:7
To investigate the strength of frictional sliding and stability of mafic lower crust, we conducted experiments on oven-dried gabbro gouge of 1 mm thick sandwiched between country rock pieces (with gouge inclined 35° to the sample axis) at slip rates of 1.22 × 10− 3 mm/s and 1.22 × 10− 4 mm/s and elevated temperatures up to 615 °C. Special attention has been paid to whether transition from velocity weakening to velocity strengthening occurs due to the elevation of temperature.Two series of experiments were conducted with normal stresses of 200 MPa and 300 MPa, respectively. For both normal stresses, the friction strengths are comparable at least up to 510 °C, with no significant weakening effect of increasing temperature. Comparison of our results with Byerlee's rule on a strike slip fault with a specific temperature profile in the Zhangbei region of North China shows that the strength given by experiments are around that given by Byerlee's rule and a little greater in the high temperature range.At 200 MPa normal stress, the steady-state rate dependence a − b shows only positive values, probably still in the “run-in” process where velocity strengthening is a common feature. With a normal stress of 300 MPa, the values of steady-state rate dependence decreases systematically with increasing temperature, and stick-slip occurred at 615 °C. Considering the limited displacement, limited normal stress applied and the effect of normal stress for the temperatures above 420 °C, it is inferred here that velocity weakening may be the typical behaviour at higher normal stress for temperature above 420 °C and at least up to 615 °C, which covers most of the temperature range in the lower crust of geologically stable continental interior. For a dry mafic lower crust in cool continental interiors where frictional sliding prevails over plastic flow, unstable slip nucleation may occur to generate earthquakes. 相似文献
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多数岩质边坡稳定性分析已基本解决了常走向单坡面临空的边坡平面滑动问题。然而,在路堑边坡工程和自然边坡中有很多边坡坡面并不是平面,它包含多个坡面。多坡面边坡包含两个或多个不同走向的坡面。多坡面边坡几何特征不同于单坡面边坡,所以滑动条件也不一样。在赤平投影图上,多坡面的滑动包络线是组成边坡的每个坡面单独投影包络线的组合。为了探讨方便,只讨论了双坡面临空岩质边坡的滑动破坏模式,并将其分为双坡面临空下的平面破坏和楔形体破坏。在赤平投影图上,双坡面滑动区域定义为双坡面边坡滑动包络图中两侧坡面的真倾线之间的面积。如果有一两个节理面真倾向线落在滑动区内,滑动破坏才可能发生。 相似文献
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140.
用直线和曲线滑面两种模型,模拟预应力锚索加固含有水平软弱层的高陡边坡的潜在滑动面,通过对锚索加固的力学机理分析来阐述预应力在滑动面主滑方向上产生分力的原因。从锚索受力角度上对锚索倾角的取值范围进行探讨,结合实际造孔过程有不同程度的孔斜或弯曲以及获取较好的锚固灌浆效果,就仰角锚固和俯角锚固两种锚固条件分别得出锚索倾角的取值范围,并以此来判定锚索的预应力是否会在滑动面走向方向上产生不利于坡体稳定的下滑力。 相似文献