Ore and Skarn Mineralogy of the Yamato Mine,Yamaguchi Prefecture,Japan, with Emphasis on Silver‐, Bismuth‐, Cobalt‐, and Tin‐bearing Sulfides

Assemblages and chemical compositions of ore minerals from the Yamato mine, Yamaguchi Prefecture, Japan, were investigated in detail to clarify its characteristics as a skarn deposit. Special attention was paid to silver‐, bismuth‐, cobalt‐, and tin‐bearing sulfide minerals and native gold at the mine, which are described here for the first time. Samples of arsenopyrite‐dominant massive ore, and garnet‐rich, clinopyroxene‐garnet‐rich, and wollastonite‐bearing skarn ores were collected from the mine dump. Arsenopyrite is the most abundant ore mineral (>80 vol.%) in the massive ore, in association with both As‐poor/free and As‐bearing pyrite. The major ore minerals in the skarn specimens are pyrite, pyrrhotite, arsenopyrite, chalcopyrite, galena, and sphalerite, along with minor argentite, Ag‐Pb‐Bi sulfate, matildite, bismuthinite, native bismuth, molybdenite, scheelite, stannite, stannoidite, cassiterite, cobaltite, gersdorffite, and Co‐rich violarite. In addition, native gold is observed in the interstices of gangue minerals. Based on the mineral assemblages and textures of the specimens examined, the major ore minerals formed in the early stage of mineralization, and the Bi‐, Ag‐, Co‐, Ni‐, As‐ and Sn‐mineralization occurred in the middle stage. Native gold was deposited in the late stage. The estimated formation temperature of the middle mineralization stage was 312±5 °C, according to iron and zinc partitioning between stannite and coexisting sphalerite. The mineralogical properties and mineralization process of the Yamato mine are consistent with those of common skarn‐ and vein‐type ore deposits associated with ilmenite‐series granitoids in the San‐yo and San‐in districts.     

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.     

Influence of long‐period filter cut‐off on elastic spectral displacements

The effect of the long‐period filter cut‐off, T_c, on elastic spectral displacements is investigated using a strong ground‐motion database from Europe and the Middle East. The relation between the filter and oscillator responses is considered to observe the influence of T_c for both analogue and digital records, and the variations with site classification, magnitude, filter order and viscous damping. Robust statistics are derived using the re‐processed European data to generalize the effects of the long‐period filter cut‐off on maximum oscillator deformation demands as a function of these seismological and structural features. Statistics with a 95% confidence interval are derived to suggest usable period ranges for spectral displacement computations as a function of T_c. The results indicate that the maximum period at which spectral displacements can be confidently calculated depend strongly on the site class, magnitude and filter order. The period range where reliable long‐period information can be extracted from digital accelerograms is twice that of analogue records. Copyright © 2006 John Wiley & Sons, Ltd.     

Geochemical Characteristics and Genetic Significance of Datangpo‐Type Manganese Ore Deposits during the Cryogenian Period

The Datangpo‐type manganese ore deposits, which formed during the Nanhuan (Cryogenian) period and are located in northeastern Guizhou and adjacent areas, are one of the most important manganese resources in China, showing good prospecting potential. Many middle‐to‐large deposits, and even super‐large mineral deposits, have been discovered. However, the genesis of manganese ore deposits is still controversial and remains a long‐standing source of debate; there are several viewpoints including biogenesis, hydrothermal sedimentation, gravity flows, cold‐spring carbonates, etc. Geochemical data from several manganese ore deposits show that there are positive correlations between Al₂O₃ and TiO₂, SiO₂, K₂O, and Na₂O, and strong negative correlations between Al₂O₃ and CaO, MgO, and MnO in black shales and manganese ores. U, Mo, and V show distinct enrichment in black shales and inconspicuous enrichment in Mn ores. Ba and Rb show strong positive correlations with K₂O in manganese ores. Cu, Ni, and Zn show clear correlations with total iron in both manganese ores and black shales. ∑REE of manganese ores has a large range with evident positive Ce anomalies and positive Eu anomalies. The Post Archean Australian Shale (PAAS) normalized rare earth element (REE) distribution patterns of manganese ores present pronounced middle rare earth element (MREE) enrichment, producing “hat‐shaped” REE plots. ∑REE of black shales is more variable compared with PAAS, and the PAAS‐normalized REE distribution patterns appear as “flat‐shaped” REE plots, lacking evident anomaly characteristics. δ¹³C values of carbonate in both manganese ores and the black shales show observable negative excursions. The comprehensive analysis suggests that the black shales formed in a reducing and quiet water column, while the manganese ores formed in oxic muddy seawater, which resulted from periodic transgressions. There was an oxidation–reduction cycle of manganese between the top water body and the bottom water body caused by the transgressions during the early Datangpo, which resulted in the dissolution of manganese. Through the exchange of the euphotic zone water and the bottom water, and episodic inflow of oxygenated water, the manganese in the bottom water was oxidized to Mn‐oxyhydroxides and rapidly buried along with algae. In the early diagenetic stage, Mn‐oxyhydroxides were reduced and dissolved in the anoxic pore water and then transformed into Mn‐carbonates by reacting with HCO₃^? from the degradation of organic matter or from seawater. In the intervals between transgressions, continuous supplies of terrigenous clastics and the high productive rates of organic matter in the euphotic zone resulted in the deposition of the black shales enriched in organic matter.     

Application of snowmelt runoff model for water resource management

Snow‐covered areas (SCAs) are the fundamental source of water for the hydrological cycle for some region. Accurate measurements of river discharge from snowmelt can help manage much needed water required for hydropower generation and irrigation purposes. This study aims to apply the snowmelt runoff model (SRM) in the Upper Indus basin by the Astore River in northern Pakistan for the years 2000 to 2006. The Shuttle Radar Topographic Mission (SRTM) data are used to generate the Digital Elevation Model (DEM) of the region. Various variables (snow cover depletion curves (SCDCs), temperature and precipitation) and parameters (degree‐day factor, recession coefficient, runoff coefficients, time lag, critical temperature and temperature lapse rate) are used as input in the SRM. However, snow cover data are direct and an important input to the SRM. Satellite data from the Moderate Resolution Imaging Spectroradiometer (MODIS) are used to estimate the SCA. Normalized difference snow index (NDSI) algorithm is applied for snow cover mapping and to differentiate snow from other land features. Nash–Sutcliffe coefficient of determination (R²) and volume difference (D_V) are used for quality assessment of the SRM. The results of the current research show that for the study years (2000–2006), the average value of R² is 0·87 and average volume difference D_V is 1·18%. The correlation coefficient between measured and computed runoff is 0·95. The results of the study further show that a high level of accuracy can be achieved during the snowmelt season. The simulation results endorse that the SRM in conjunction with MODIS snow cover product is very useful for water resource management in the Astore River and can be used for runoff forecasts in the Indus River basin in northern Pakistan. Copyright © 2011 John Wiley & Sons, Ltd.     

Towards a direct collapse–load method of design for concrete frames subjected to severe ground motions

Most current methods of design for concrete structures under earthquake loads rely on highly idealized ‘equivalent’ static representations of the seismic loads and linear‐elastic methods of structural analysis. With the continuing development of non‐linear methods of dynamic analysis for the overload behaviour and collapse of complete concrete structures, a more direct and more accurate design procedure becomes possible which considers conditions at system collapse. This paper describes an evaluation procedure that uses non‐linear dynamic collapse–load analysis together with global safety coefficients. A back‐calibration procedure for evaluating the global safety coefficients is also described. The aim of this paper is to open up discussion of alternative methods of design with improved accuracy which are necessary to move towards a direct collapse–load method of design. Copyright © 2002 John Wiley & Sons, Ltd.     

Improved seismic hazard model with application to probabilistic seismic demand analysis

An improved seismic hazard model for use in performance‐based earthquake engineering is presented. The model is an improved approximation from the so‐called ‘power law’ model, which is linear in log–log space. The mathematics of the model and uncertainty incorporation is briefly discussed. Various means of fitting the approximation to hazard data derived from probabilistic seismic hazard analysis are discussed, including the limitations of the model. Based on these ‘exact’ hazard data for major centres in New Zealand, the parameters for the proposed model are calibrated. To illustrate the significance of the proposed model, a performance‐based assessment is conducted on a typical bridge, via probabilistic seismic demand analysis. The new hazard model is compared to the current power law relationship to illustrate its effects on the risk assessment. The propagation of epistemic uncertainty in the seismic hazard is also considered. To allow further use of the model in conceptual calculations, a semi‐analytical method is proposed to calculate the demand hazard in closed form. For the case study shown, the resulting semi‐analytical closed form solution is shown to be significantly more accurate than the analytical closed‐form solution using the power law hazard model, capturing the ‘exact’ numerical integration solution to within 7% accuracy over the entire range of exceedance rate. Copyright © 2007 John Wiley & Sons, Ltd.     

Metamorphic and cooling history of the Shimanto accretionary complex,Kyushu, Southwest Japan: Implications for the timing of out‐of‐sequence thrusting

Illite crystallinity, K–Ar dating of illite, and fission‐track dating of zircon are analyzed in the hanging wall (Sampodake unit) and footwall (Mikado unit) of a seismogenic out‐of‐sequence thrust (Nobeoka thrust) within the Shimanto accretionary complex of central Kyushu, southwest Japan. The obtained metamorphic temperatures, and timing of metamorphism and cooling, reveal the tectono‐metamorphic evolution of the complex, and related development of the Nobeoka thrust. Illite crystallinity data indicate that the Late Cretaceous Sampodake unit was metamorphosed at temperatures of around 300 to 310°C, while the Middle Eocene Mikado unit was metamorphosed at 260 to 300°C. Illite K–Ar ages and zircon fission‐track ages constrain the timing of metamorphism of the Sampodake unit to the early Middle Eocene (46 to 50 Ma, mean = 48 Ma). Metamorphism of the Mikado unit occurred no earlier than 40 Ma, which is the youngest depositional age of the unit. The Nobeoka thrust is inferred to have been active during about 40 to 48 Ma, as the Sampodake unit started its post metamorphic cooling after 48 Ma and was thrust over the Mikado unit at about 40 Ma along the Nobeoka thrust. These results indicate that the Nobeoka thrust was active for more than 10 million years.     

Book Review

In this paper, we examine the applicability of spatial optimization as a generative modelling technique for sustainable land‐use allocation. Specifically, we test whether spatial optimization can be used to generate a number of compromise spatial alternatives that are both feasible and different from each other. We present a new spatial multiobjective optimization model, which encourages efficient utilization of urban space through infill development, compatibility of adjacent land uses, and defensible redevelopment. The model uses a density‐based design constraint developed by the authors. The constraint imposes a predefined level of consistent neighbourhood development to promote contiguity and compactness of urban areas. First, the model is tested on a hypothetical example. Further, we demonstrate a real‐world application of the model to land‐use planning in Chelan, a small environmental amenity town in the north‐central region of the State of Washington, USA. The results indicate that spatial optimization is a promising method for generating land‐use alternatives for further consideration in spatial decision‐making.     

Orderliness of Hydrocarbon Accumulation Distribution in Rift Basins of Eastern China

The Cenozoic rift basins in eastern China show a clear temporal and spatial zonation and episodic tectonic evolution, which control their episodic hydrocarbon generation and zonal accumulation. In this paper, based on the study of depositional architecture, hydrocarbon migration system and dynamic evolution in the rift basins, combinations of hydrocarbon accumulation elements were analyzed using sequence stratigraphy. Hydrocarbon distribution in system tracts with different sequence orders was further studied. And we summarized stacking patterns and horizontal combination relationships for different types of reservoirs, such as lithological, tectonic-lithological, tectonic and stratigraphical reservoirs which can be observed from depression center to basin margin. The result reveals that various scales of pools exhibit significant distribution and evolution orderliness in different pool-forming units, i.e., depositional systems, plays and depressions. The regular distribution of various scales of pools is closely related to tectonic evolution and depositional filling in the rift basins. The result can be applied to the fine petroleum exploration in rift basins in eastern China. It will promote the scientific prediction and evaluation of reservoir types and their spatial distribution, lead to the active shifts of exploration targets in different zones, and thus support the stable progress of fine exploration in mature exploration areas.