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31.
Oscillatory zoning in low δ18O skarn garnet from the Willsboro wollastonite deposit, NE Adirondack Mts, NY, USA, preserves a record of the temporal evolution of mixing hydrothermal fluids from different sources. Garnet with oscillatory zoning are large (1–3 cm diameter) euhedral crystals that grew in formerly fluid filled cavities. They contain millimetre‐scale oscillatory zoning of varying grossular–andradite composition (XAdr = 0.13–0.36). The δ18O values of the garnet zones vary from 0.80 to 6.26‰ VSMOW and correlate with XAdr. The shape, pattern and number of garnet zones varies from crystal to crystal, as does the magnitude of the correlated chemistry changes, suggesting fluid system variability, temporal and/or spatial, over the time of garnet growth. The zones of correlated Fe content and δ18O indicate that a high Fe3+/Al, high δ18O fluid mixed with a lower Fe3+/Al and δ18O fluid. The high δ18O, Fe enriched fluids were likely magmatic fluids expelled from crystallizing anorthosite. The low δ18O fluids were meteoric in origin. These are the first skarn garnet with oscillatory zoning reported from granulite facies rocks. Geochronologic, stable isotope, petrologic and field evidence indicates that the Adirondacks are a polymetamorphic terrane, where localized contact metamorphism around shallowly intruded anorthosite was followed by a regional granulite facies overprint. The growth of these garnet in equilibrium with meteoric and magmatic fluids indicates an origin in the shallow contact aureole of the anorthosite prior to regional metamorphism. The zoning was preserved due to the slow diffusion of oxygen and cations in the large garnet and protection from deformation and recrystallization in zones of low strain in thick, rigid, garnetite layers. The garnet provide new information about the hydrothermal system adjacent to the shallowly intruded massif anorthosite that predates regional metamorphism in this geologically complex, polymetamorphic terrane. 相似文献
32.
Zuoheng Zhang Jingwen Mao Jianmin Yang Zhiliang Wang Zhaochong Zhang 《Resource Geology》2003,53(2):101-114
Abstract. The Ta'ergou tungsten deposit in Gansu province, northwestern China, is located in the western part of the North Qilian Caledonian orogen, and consists of scheelite skarn bodies and wolframite quartz veins. The tungsten‐bearing skarn developed by the replacement of carbonate layers intercalated in the Precambrian schist and amphibolite whereas wolframite‐quartz ore veins developed along a group of fractures that cut through horizontal skarns. The Ta'ergou tungsten deposit is genetically related to the Caledonian Yeniutan granodiorite intrusion and occurs ca. 500 m wide in the exo‐contact zone 300 ~ 500 m apart from the intrusion. The granodiorite displays a lower grade of differentiation, low content of SiO2 and high contents of mafic components. There are three types of fluid inclusions in the wolframite‐quartz vein systems, i. e. aqueous, CO2‐H2O and CO2‐rich. The homogenization temperature of aqueous inclusion ranges from 140 to 380d?C and their salinities from 6.4 to 17.4 equivalent wt% NaCl. Laser Raman spectroscopy shows that the inclusions contain a relatively high content of CO2. The δ34S values of skarn type sulfides range from +8.1 to +12.7 per mil and those of quartz vein sulfides from +9.3 to +14.9 per mil, similar to sulfides of the granodiorite with from +6.0 to +11.7 per mil. The δ18O values of quartz are between +10.5 and +13.3 per mil and those of wolframite between +3.4 and +5.1 per mil. The δ18O water values of ore forming fluids range from +0.6 to +6.4 per mil and suggest the mixture of magmatic fluids with meteoric water formed the ore‐forming fluids. It has been proved that Precambrian strata in the west sector of North Qilian region are enriched in tungsten. We propose the strata were remelted to be tungsten‐granitoid during subduction. The polymetallic tungsten was gradually accumulated into the roof pendants of the granite intrusion by fractional crystallization and then was deposited by hydrothermal fluids during metasomatism and infilling along fractures. On the other hand, the granite intrusion also acted as “heating machine” to make hydrothermal fluids leach out the metals from Precambrian strata and these metals joined the ore‐forming hydrothermal system. 相似文献
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34.
M. Barbaro R. Herrera Urbina C. Cozza D. Fuerstenau A. Marabini 《International Journal of Mineral Processing》1997,50(4):275-287
A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation. 相似文献
35.
应用增量方法不仅能够从理论上准确计算所有固体矿物的O同位素分馏系数,而且能够定量预测;(1)热力学平衡条件下共生矿物之间的18O富集顺序;(2)岩石化学成分与O同位素组成之间的关系;(3)矿物结构变化对O同位素组成的影响;(4)同质多相转变和矿物反应中的氧同位素继承性。本文对这些规律性预测进行了概要性介绍,并给出实例予以说明。 相似文献
36.
37.
四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨 总被引:6,自引:0,他引:6
四川盆地西部宫钾卤水以深层卤水形式赋存于地下4000余m的中三叠统雷口坡组四段(T2l4)盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比,其中含K+含量异常高,构成液态钾矿资源;Br-、I-、B(3+)、Li+等稀有组分也远超过综合利用工业品位,为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因,具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。 相似文献
38.
柿竹园钨多金属矿床的Re-0s同位素等时线年龄研究 总被引:28,自引:0,他引:28
柿竹园钨多金属矿床产于千里山复式岩体与泥盆系碳酸盐岩的接触部位。其成矿时代以往都是用矿体附近的花岗岩体年龄来间接推断。我们最近采用辉钼矿的Re-Os等时线定年法直接测定了与千里山第一期花岗岩有关的夕卡岩型矿体的矿化年龄为151.0±3.5Ma。该年龄晚于第一期花岗岩,但早于第二期花岗岩,从而证实了钨多金属矿化在花岗岩系列的早期早阶段也可以成矿。该年龄与野外观察的地质情况十分吻合,而辉钼矿是热液矿床中的常见矿物,说明这种测年方法是一种研究热液矿床成矿时代及其成因的重要手段。 相似文献
39.
40.
安徽省大别山南部宿松杂岩变质作用研究 总被引:7,自引:13,他引:7
宿松杂岩的变质作用可分为3个阶段:早期、主期和晚期阶段。主期阶段的矿物组合在云母片岩中为石榴石+多硅白云母+石英+磁铁矿±钠云母±绿帘石/黝帘石;在白云母钠长(二长)片岩和片麻岩中为石榴石+多硅白云母+钠长石+石英+绿帘石/黝帘石±冻蓝闪石;在石榴石钠长角闪岩中为石榴石+冻蓝闪石+钠长石+黝帘石+石英±钠云母±金红石/磁铁矿。根据多种地质温压计和变质反应可以推测主期变质条件为:T=520℃~580℃,P=1.2~1.4GPa,地热梯度为12℃/km,相当于高压过渡型。晚期阶段变质条件为:T=460℃~480℃,P=0.6~0.7GPa,为中压绿帘角闪岩相。宿松杂岩的变质条件介于其南部的蓝闪绿片岩相和北部的榴辉岩相之间,三者是扬子板块向华北板块之下俯冲到不同深度的产物。 相似文献