川西甲基卡花岗伟晶岩型锂矿床中熔体、流体包裹体固相物质研究

川西甲基卡二云母花岗岩和伟晶岩内发育大量原生熔体包裹体和富晶体流体包裹体。为了查明甲基卡成矿熔体、流体性质与演化特征,运用激光拉曼光谱和扫描电镜鉴定了甲基卡花岗伟晶岩型锂矿床中二云母花岗岩及伟晶岩脉不同结构带内的原生熔体、流体包裹体的固相物质。分析结果表明,甲基卡二云母花岗岩石英内熔体包裹体的矿物组合为磷灰石+白云母、白云母+钠长石、白云母+石墨;伟晶岩绿柱石内富晶体流体包裹体的矿物组合主要为刚玉、富铝铁硅酸盐+刚玉+锂辉石、锂辉石+石英+锂绿泥石;伟晶岩锂辉石内富晶体流体包裹体的矿物组合主要为磷灰石、锡石、磁铁矿、石英+钠长石+锂绿泥石、萤石、富钙镁硅酸盐+富铁铝硅酸盐+富铁硅酸盐+石英;花岗岩浆熔体与伟晶岩浆熔体(流体)具有一定的差异,成矿熔体、流体成分总体呈现出碱质元素(Na、Si、Al)、挥发分(F、P、CO_2)含量增高及基性元素(Fe、Mg、Ca)降低的特征;包裹体中子矿物与主矿物的化学成分具有一定的差别,揭示出伟晶岩熔体(流体)存在局部岩浆分异作用,具不混溶性及非均匀性。因此认为,伟晶岩熔浆(流体)为岩浆分异与岩浆不混溶共同作用的产物,挥发分含量的增高(F、P、CO_2)使伟晶岩能够与稀有金属组成各类络合物或化合物,这对于稀有金属成矿起到了至关重要的作用。     

Crystallization Conditions and Mineral Chemistry in the East of Tafresh,Central Iran,with Insights into Magmatic Processes

The Tafresh granitoids are located at the central part of the Urumieh-Dokhtar Magmatic Arc(UDMA) in Iran. These rocks, mainly consisting of diorite and granodiorite, were emplaced during the Early Miocene. They are composed of varying proportions of plagioclase + K-feldspar + hornblende ± quartz ± biotite. Discrimination diagrams and chemical indices of amphibole phases reveal a calc-alkaline affinity and fall clearly in the crust-mantle mixed source field. The estimated pressure, derived from Al in amphibole barometry, is approximately 3 Kb. The granitoids are I-type, metaluminous and belong to the calc-alkaline series. They are all enriched in light rare earth elements and large ion lithophile elements, depleted in high field strength elements and display geochemical features typical of subduction-related calc-alkaline arc magmas. Most crystal size distribution(CSD) line patterns from the granitoids show a non-straight trend which points to the effect of physical processes during petrogenesis.The presence of numerous mafic enclaves, sieve texture and oscillatory zoning along with the CSD results show that magma mixing in the magma chamber had an important role in the petrogenesis of Tafresh granitoids. Moreover, the CSD analysis suggests that the plagioclase crystals were crystallized in a time span of less than 1000 years, which is indicative of shallow depth magma crystallization.     

High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.     

吉林省红旗岭矿区7号岩体群地质特征及对地质找矿的指导意义

红旗岭矿区的南东部存在7、32、33号三个岩体,一般统称为7号岩体群。7号岩体是矿区发现含铜、镍矿最大的岩体,32与33号岩体分布在7号岩体的北西部。通过对这三个岩体的地质特征进行分析,利用3Dmine软件建模技术,对三个岩体、岩相、矿体建立三维模型。对模型进行观察、分析,结合成岩成矿地质理论,发现三个岩体是由来自7号岩体的南东部深部岩浆源生成的,岩浆由7号岩体的南东部深部向北西方向侵入,地质历史上三个岩体是一个大岩体,只是经过长期的风化剥蚀和地质构造改造形成目前的3个岩体,显示7号岩体的南东部深部具有找矿潜力。     

安徽金寨银水寺铅锌矿床流体包裹体和同位素地球化学特征

银水寺铅锌矿床位于大别造山带北缘,是该区最大的矽卡岩型矿床。矿体主要发育在中元古界庐镇关岩群仙人冲组大理岩与郑堂子组千枚岩之间的层间破碎带以及正长花岗斑岩与大理岩的接触带中。矿床先后经历了四个成矿阶段,矽卡岩阶段(Ⅰ)、石英.白钨矿阶段(Ⅱ)、石英.硫化物阶段(Ⅲ)、碳酸盐阶段(Ⅳ)。矽卡岩阶段(Ⅰ)主要发育绿帘石、阳起石、石英、绿泥石、磁铁矿及少量金属硫化物等;石英.白钨矿阶段(Ⅱ)主要发育石英、方解石、萤石及少量白钨矿和金属硫化物;石英.硫化物阶段(Ⅲ)广泛发育闪锌矿、方铅矿、黄铜矿等金属硫化物及石英、方解石、萤石、绿泥石等;碳酸盐阶段(Ⅳ)主要发育方解石、石英及少量黄铁矿。矿床中发育三种类型流体包裹体,包括富CO2水溶液包裹体(AC类)、气液两相水溶液包裹体(L类)和含子晶多相包裹体(S型)。根据流体包裹体岩相学、显微测温、激光拉曼研究结果,矽卡岩阶段主要有富CO2包裹体和气液两相水溶液包裹体,均一温度为314~400℃、盐度变化范围较大(1.1%~19.3%NaCleqv);石英.白钨矿阶段发育气液两相水溶液包裹体、含子晶多相包裹体和富CO2包裹体,后两者均一温度相近(263~349℃)、盐度差异较大(32.8%~41%NaCleqv和0.8%~6.1%NaCleqv),表明流体发生了沸腾作用;石英.硫化物阶段主要发育气液两相水溶液包裹体,均一温度为230~332℃,盐度为0.2%~8.9%NaCleqv;碳酸盐阶段只发育气液两相水溶液包裹体,显示低温(162~245℃)、低盐度(0.2%~5.6%NaCleqv)的特征。矿床不同成矿阶段石英、绿帘石中流体包裹体中水H-O同位素研究结果表明,δ18Ofluid值从早到晚逐渐减小,其中矽卡岩阶段为–1.3‰~4.7‰、石英.硫化物阶段为–5.1‰~–3.1‰,表明银水寺矿床早期成矿流体主要为岩浆来源,并在成矿过程中不断有大气降水的加入。石英流体包裹体中CO2的C同位素测试结果表明,矽卡岩阶段δ13CV-PDB值为–9.2‰,石英.硫化物阶段为–25.8‰~–15.4‰,表明早期成矿流体中碳质主要来自岩浆,石英-硫化物阶段有大量有机碳加入,其可能与流体和富含有机质的地层反应有关。矿石中主要金属硫化物的δ34S值(1.7‰~4.4‰)显示了深源硫的特征。Pb同位素变化范围集中(206Pb/204Pb=16.55~16.705,207Pb/204Pb=15.369~15.459,208Pb/204Pb=37.463~37.767),显示壳幔混源的特点。随着成矿作用的进行,岩浆流体与碳酸盐围岩地层发生水岩交代反应形成矽卡岩,该过程造成了成矿矽卡岩阶段磁铁矿和少量闪锌矿的沉淀;断裂活动造成热液体系压力下降,流体发生沸腾,CO2、HF进入气相并逃逸促使矿床中钨的沉淀;同时大气降水沿裂隙灌入,混合作用导致流体的温度、盐度降低,Cl–浓度下降,造成矿床中铅锌的大面积沉淀。     

安徽巢湖苏湾地区综合地质特征及找矿远景

安徽巢湖苏湾地区构造格架位于郯庐断裂带东侧滁州—苏湾金多金属矿成矿带。对近年来取得的地质成果,包括成矿地质特征、物化探特征、地球化学特征、矿化蚀变特征等进行系统分析研究,认为灯影组中段为研究区主要赋矿层位,是研究区重要找矿远景区,F1断层为主要控岩控矿构造,地磁异常为寻找类似山里许铁铜金矿的远景部位。     

河北武安坦岭多斑斜长斑岩中基质矿物特征及其研究意义

河北武安坦岭斜长斑岩具有多斑斑状结构,基质为显微晶质结构。岩相学观察表明,斜长石斑晶有一个宽广的核部和一个宽度可变的条纹长石反应边,个别核部包含有角闪石、黑云母等矿物。基质矿物主要由蓝透闪石、条纹长石(An0Ab8.4Or91.5～An0.1Ab57.3Or42.6)、石英、钾长石(An0.3Ab5.9Or93.7～An0.3Ab4.7Or95.2)、钠长石(An0.2Ab98.3Or1.5～An0.1Ab99.2Or0.7)、磁铁矿、赤铁矿、钛铁矿、磷灰石、榍石和锆石等11种矿物组成。角闪石温压计计算结果得出,基质角闪石核部的结晶压力高于边部,核部为34.05 MPa,对应的结晶温度为660.35℃,结晶深度为1.29km;边部的结晶压力为24.32MPa,结晶温度为598.32℃,结晶深度为0.92km;而斜长石斑晶中的角闪石形成时压力为159.51～178.19MPa,温度为817.68～819.79℃,对应的形成深度为6.03～6.73km。基质角闪石在Al2O3-TiO2图上落在壳源区,而斑晶中的角闪石和黑云母都落在壳幔混合区。斜长石、条纹长石、磁铁矿和磷灰石的微量和稀土元素测试数据显示,其都具有相对富集LILE、亏损HFSE的特点,暗示了基质矿物的形成有流体参与。ICT三维扫描结果显示,斜长斑岩基质中的孔隙体积含量约为3.428%,铁质体积含量为4.371%,且铁氧化物和孔隙具弱连通性。通过讨论分析,笔者得出:(1)坦岭斜长斑岩中斜长石斑晶具有明显的交代结构,且晶体本身没有明显熔蚀现象,这些特征表明大量的斜长石斑晶快速上升,即"冻结岩浆房"的活化机制与流体密切相关;(2)斜长斑岩中基质矿物有十一种,且矿物类型复杂,不符合平衡系统矿物相律,应属于流体晶矿物组合;(3)坦岭斜长斑岩的基质"岩浆"可能是一种富Fe、K、P、Si、Na等元素的熔体-流体流;(4)多斑斜长斑岩的形成经历了(1)深度6～7km的深部岩浆房形成斜长石堆晶→(2)富Fe、K、P、Si、Na等元素的熔体-流体流加入深部岩浆房,冻结岩浆房活化→(3)由于流体超压,含大量斜长石斑晶的熔体-流体在地壳浅部(0.9～1.2km)呈小岩株状或岩脉状就位。多斑斜长斑岩为深部找矿提供了有力的线索。     

Mineralogy,Fluid Inclusions,and Sulfur Isotopes of the Huanzala Deposits,Peru: Early Skarn and Late Polymetallic Replacement Style Mineralizations

Carbonate‐replacement polymetallic mineralization at the Huanzala deposits (9°51′S, 77°00′W) was conducted in two contrasting stages that occurred in almost the same location. Early‐stage mineralization has a relation with a granodiorite porphyry stock, whereas the late‐stage mineralization is genetically associated with quartz porphyry sills. The early stage involved low to intermediate sulfidation Cu–Zn–(Pb) mineralization associated with metasomatic skarn, and the late stage involved high to intermediate sulfidation Cu–Zn–Pb–(Mn) mineralization associated with hydrothermal alteration characterized by paragonitic sericitization. The orebodies are hosted by steeply dipping (approximately 60°NE) Lower Cretaceous carbonate rocks in a relatively narrow range of approximately 4 km in horizontal extent and less than 1 km in depth. The pathway of the early‐stage brine‐derived fluids (300–>400°C, >33 wt% NaCl equivalent) along a plot of log against 1000/T is best explained by the progressive dual decline of the value and the temperature under rock‐buffering conditions; this decline saw the pathway progress through the stability field of pyrrhotite to reach that of pyrite and promoted a decrease in FeS from 14.5 to 1.6 mol% in the sphalerite. In contrast, an explanation for the pathway of the late‐stage fluids (140–290°C, 3–13 wt% NaCl equivalent) is given by an almost isothermal decline at approximately 270°C, with passing through the stability field of pyrite–bornite to reach that of chalcopyrite, promoting an increase in FeS from 0.1 to 1.6 mol% in the sphalerite, suggesting gas‐buffering conditions. The ore formation pressure records in the fluid inclusions illustrate an approximately 2‐km erosion during the roughly 2‐Myr total lifetime of the hydrothermal system.     

航空磁测在黑龙江伊春地区夕卡岩型锌多金属矿的找矿应用

依据1：5万高精度航磁异常和地质特征进行选区,结合1：2万综合物化探查证技术,在小兴安岭伊春地区航磁异常区发现了夕卡岩型锌多金属矿,体现了航空磁测技术在夕卡岩型多金属矿找矿中的适用性.查证结果认为,下寒武统含大理岩地层与侵入岩接触部位航磁异常区是重要的夕卡岩型多金属矿找矿靶区,赋矿部位显示低阻高极化地球物理特征;土壤地球化学特征表现为地层与侵入岩接触部位存在Ag、As、Sb、Mo、W、Bi、Pb、Cu、Zn元素组合异常,异常套合好,Sb异常值高,出现于内带,Zn常见于中带.     

鲁西齐河地区铁矿控矿特征及找矿标志

山东省齐河县境内发育有矽卡岩型铁矿,近年来该区铁矿勘查和研究工作取得了较大进展。本文通过对研究区内铁矿勘查研究成果进行统计分析,旨在对其控矿特征和找矿标志进行探讨来促进该区铁矿找矿工作。研究区内铁矿控矿地层为奥陶纪碳酸盐岩和石炭纪-二叠纪碎屑岩地层,成矿地质体为燕山晚期中基性侵入岩体;铁矿体主要赋存于地层和岩体的接触带处,且在碳酸盐岩、碎屑岩地层中和侵入岩体中也赋存有部分铁矿体。区内铁矿体赋存类型多样,其中以接触带赋存式为主,且含有断裂充填式、层间充填式、裂隙贯入式、捕虏体构造式等。铁矿体形态复杂,呈层状、似层状、囊状、透镜状等;矿床典型蚀变分带特征为闪长岩带-蚀变闪长岩带-内矽卡岩带-铁矿体-外矽卡岩带-大理岩化带-灰岩带。该区成矿作用以接触扩散交代作用、接触渗滤交代作用为主,此外还有富矿热液充填作用等。研究区内铁矿找矿标志主要包括地层标志（奥陶纪碳酸盐岩和石炭纪-二叠纪碎屑岩地层）、岩体标志（中基性侵入岩体,且发育有钠长石化的蚀变闪长岩）、构造标志（地层与岩体接触带、构造交汇部位、层间滑脱部位、脆性裂隙部位等）、围岩蚀变标志（磁铁矿化、矽卡岩化、钠长石化、蛇纹石化、金云母化等与成矿关系密切）、地球物理标志（明显的高值磁异常和化极磁异常部位、重力异常梯度带和高-低电阻转换带）。在今后铁矿勘查过程中,需要在综合研究该区控矿特征的基础上,可利用多种找矿标志进行相互配合、互为补充和综合研究,以期达到预期勘查效果。