张广才岭南部杨木岗组的厘定及物源分析

本文通过岩石组合特征和区域对比，将张广才岭南部西蛤拉河子—大锅盔一带分布的浅变质地层重新厘定为杨木岗组。为了确定杨木岗组的形成时代和沉积物源，进行了碎屑锆石U- Pb年代学和微体古生物地层学研究。锆石大多数呈自形—半自形晶，显示典型振荡岩浆生长环带，暗示其岩浆成因。该地层中测得的两组碎屑锆石U- Pb产生多组谐和年龄，其中PM010- TW样品56个测点最小峰值(谐和)年龄为307 Ma，DB02- TW样品51个测点最小峰值(谐和)年龄为275 Ma；覆盖在杨木岗组之上的中生代二浪河组安山岩的定年结果为181. 1±0. 9 Ma，表明杨木岗组形成于早二叠世晚期。杨木岗组中获取疑源类化石组合出现了新元古代晚期—早寒武世和奥陶纪地层常见分子，结合碎屑锆石年龄结果，反映杨木岗组沉积时周围存在早古生代和中—新元古代地质体。碎屑沉积岩Al2O3/TiO2平均值为24. 44，稀土元素球粒陨石标准化曲线具有轻稀土富集、重稀土稳定和负Eu异常特征，结合碎屑锆石的年龄频数可以看出，确定杨木岗组的沉积物主要来源于沉积盆地周围的晚古生代早期中酸性火成岩，次要物源由沉积盆地周边的早古生代地质体和近地表的中—新元古代地质体提供。佳木斯地块为松嫩- 张广才岭地块上晚古生代地层的形成提供了部分物源，暗示佳木斯地块与松嫩- 张广才岭地块于早二叠世之前已完成拼合。     

Detrital zircon reference for the North China block

U–Pb analyses of 250 single detrital zircons from Upper Proterozoic to Ordovician strata collected from the Zhuozi Shan in north-central China provide a detrital zircon reference for the North China block, a major crustal entity in the Asian tectonic collage. The results, which range in age from 1.72 to 2.97 Ga, shed new light on the age of the crystalline basement in North China, much of which is covered by younger sedimentary units. In addition, this detrital zircon reference can be used to help determine the provenance of clastic sedimentary units and for assessing validity of paleogeographic and regional tectonic models that include the complex history of Asian continental amalgamation, terrane accretion, and subsequent translation that is ongoing today.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

Lermontovskoe Tungsten Skarn Deposit: the Oldest Mineralization in the Sikhote-Alin Orogen, Far East Russia

Abstract. Lermontovskoe tungsten skarn deposit in central Sikhote-Alin is concluded to have formed at 132 Ma in the Early Cretaceous, based on K-Ar age data for muscovite concentrates from high-grade scheelite ore and greisenized granite. Late Paleozoic limestone in Jurassic - early Early Cretaceous accretionary complexes was replaced during hydrothermal activity related to the Lermontovskoe granodiorite stock of reduced type. The ores, characterized by Mo-poor scheelite and Fe^3+- poor mineral assemblages, indicate that this deposit is a reduced-type tungsten skarn (Sato, 1980, 1982), in accordance with the reduced nature of the granodiorite stock.
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism.     

Cretaceous isochron ages from K–Ar and Ar / Ar dating of eclogitic rocks in the Tso Morari Complex, western Himalaya, India

The Tso Morari Complex, which is thought to be originally the margin of the Indian continent, is composed of pelitic gneisses and schists including mafic rock lenses (eclogites and basic schists). Eclogites studied here have the mineral assemblage Grt + Omp + Ca-Amp + Zo + Phn + Pg + Qtz + Rt. They also have coesite pseudomorph in garnet and quartz rods in omphacite, suggesting a record of ultrahigh-pressure metamorphism. They occur only in the cores of meter-scale mafic rock lenses intercalated with the pelitic schists. Small mafic lenses and the rim parts of large lenses have been strongly deformed to form the foliation parallel to that of the pelitic schists and show the mineral assemblages of upper greenschist to amphibolite facies metamorphism. The garnet–omphacite thermometry and the univariant reaction relations for jadeite formation give 13–21 kbar at 600 °C and 16–18 kbar at 750 °C for the eclogite formation using the jadeite content of clinopyroxene (X_Jd = 0.48).

Phengites in pelitic schists show variable Si / Al and Na / K ratios among grains as well as within single grains, and give K–Ar ages of 50–87 Ma. The pelitic schist with paragonite and phengite yielded K–Ar ages of 83.5 Ma (K = 4.9 wt.%) for paragonite–phengite mixture and 85.3 Ma (K = 7.8 wt.%) for phengite and an isochron age of 91 ± 13 Ma from the two dataset. The eclogite gives a plateau age of 132 Ma in Ar/Ar step-heating analyses using single phengite grain and an inverse isochron age of 130 ± 39 Ma with an initial ⁴⁰Ar / ³⁶Ar ratio of 434 ± 90 in Ar/Ar spot analyses of phengites and paragonites. The Cretaceous isochron ages are interpreted to represent the timing of early stage of exhumation of the eclogitic rocks assuming revised high closure temperature (500 °C) for phengite K–Ar system. The phengites in pelitic schists have experienced retrograde reaction which modified their chemistry during intense deformation associated with the exhumation of these rocks with the release of significant radiogenic ⁴⁰Ar from the crystals. The argon release took place in the schists that experienced the retrogression to upper greenschist facies metamorphisms from the eclogite facies conditions.     

Quaternary bedrock erosion and landscape evolution in the Sør Rondane Mountains, East Antarctica: Reevaluating rates and processes

Rates and processes of rock weathering, soil formation, and mountain erosion during the Quaternary were evaluated in an inland Antarctic cold desert. The fieldwork involved investigations of weathering features and soil profiles for different stages after deglaciation. Laboratory analyses addressed chemistry of rock coatings and soils, as well as ¹⁰Be and ²⁶Al exposure ages of the bedrock. Less resistant gneiss bedrock exposed over 1 Ma shows stone pavements underlain by in situ produced silty soils thinner than 40 cm and rich in sulfates, which reflect the active layer thickness, the absence of cryoturbation, and the predominance of salt weathering. During the same exposure period, more resistant granite bedrock has undergone long-lasting cavernous weathering that produces rootless mushroom-like boulders with a strongly Fe-oxidized coating. The red coating protects the upper surface from weathering while very slow microcracking progresses by the growth of sulfates. Geomorphological evidence and cosmogenic exposure ages combine to provide contrasting average erosion rates. No erosion during the Quaternary is suggested by a striated roche moutonnée exposed more than 2 Ma ago. Differential erosion between granite and gneiss suggests a significant lowering rate of desert pavements in excess of 10 m Ma^− 1. The landscape has been (on the whole) stable, but the erosion rate varies spatially according to microclimate, geology, and surface composition.     

Early Cretaceous U–Pb zircon ages for the Copiapó plutonic complex and implications for the IOCG mineralization at Candelaria, Atacama Region, Chile

Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike–sill system exposed in the Candelaria open pit have been dated with the U–Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz–monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu–Au mineralization (Re–Os molybdenite ages at ∼115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria–Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz–monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu–Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified ⁴⁰Ar/³⁹Ar and K/Ar systematic in some areas.     

The evolution of groundwater in the Tyrrell catchment, south-central Murray Basin, Victoria, Australia

The Tyrell catchment lies on the western margin of the Riverine Province in the south-central Murray Basin, one of Australia’s most important groundwater resources. Groundwater from the shallow, unconfined Pliocene Sands aquifer and the underlying Renmark Group aquifer is saline (total dissolved solids up to 150,000 mg/L) and is Na-Cl-Mg type. There is no systematic change in salinity along hydraulic gradients implying that the aquifers are hydraulically connected and mixing during vertical flow is important. Stable isotopes (¹⁸O+²H) and Cl/Br ratios indicate that groundwater is entirely of meteoric origin and salts in this system have largely been derived by evapotranspiration of rainfall with only minor halite dissolution, rock weathering (mainly feldspar dissolution), and ion exchange between Na and Mg on clays. Similarity in chemistry of all groundwater in the catchment implies relative consistency in processes over time, independent of any climatic variation. Groundwater in both the Pliocene Sands and Renmark Group aquifers yield ages of up to 25 ka. The Tyrrell Catchment is arid to semi-arid and has low topography. This has resulted in relatively low recharge rates and hydraulic gradients that have resulted in long groundwater residence times.     

Hydrochemistry and isotope geochemistry as tools for groundwater hydrodynamic investigation in multilayer aquifers: a case study from Lomellina, Po plain, South-Western Lombardy, Italy

A multicriteria approach in studying hydrodynamics of a multilayer aquifer system has been used in the Lomellina region (Northern Italy). It involves the reconstruction of the hydrogeological framework coupled to the definition of the hydrochemical and isotopic features of the aquifers. A shallow phreatic aquifer, reaching depths of about 60–80 m from the surface, and deeper aquifers containing confined groundwater, were distinguished. Groundwater generally shows mineralisation decreasing with depth; dissolved ions depict calcium-bicarbonate hydrochemical facies and stable isotopes define the recharge mechanisms, the origin of groundwater, and the hydraulic confinement of deep aquifers. The phreatic aquifer is fed by local infiltration and by streams and irrigation channels. Tritium and Carbon-14 groundwater dating indicate long residence times (on the order of thousands of years) for confined aquifers. The confined aquifers show essentially passive hydrodynamic conditions and maintain a higher piezometric level than the phreatic aquifer. This inhibits the possibility of recent water penetrating far below the surface. The hydrogeological setting of the Lomellina region displays features which are common to other sectors of the Po plain. As a consequence, the results of this study, although conducted on a restricted area, are highly illustrative of groundwater hydrodynamics in large sedimentary aquifers.     

Detrital Zircon of 4100 Ma in Quartzite in Burang, Tibet

A detrital zircon aged 4.1 Ga is discovered by the SHRIMP U-Pb method in a quartzite in Burang County, western Tibet. This is presently the oldest single-grain detrital zircon in China. The Th-U ratios of the two testing points of the 〉4.0 Ga zircon are between 0.76 and 0.86, indicating their magmatic origin. This discovery has offered an important age for investigating the geological evolution of the Qinghai-Tibet Plateau.