Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.     

Lagged rejuvenation of groundwater indicates internal flow structures and hydrological connectivity

Large proportions of rainwater and snowmelt infiltrate into the subsurface before contributing to stream flow and stream water quality. Subsurface flow dynamics steer the transport and transformation of contaminants, carbon, weathering products and other biogeochemistry. The distribution of groundwater ages with depth is a key feature of these flow dynamics. Predicting these ages are a strong test of hypotheses about subsurface structures and time-varying processes. Chlorofluorocarbon (CFC)-based groundwater ages revealed an unexpected groundwater age stratification in a 0.47 km² forested catchment called Svartberget in northern Sweden. An overall groundwater age stratification, representative for the Svartberget site, was derived by measuring CFCs from nine different wells with depths of 2–18 m close to the stream network. Immediately below the water table, CFC-based groundwater ages of already 30 years that increased with depth were found. Using complementary groundwater flow models, we could reproduce the observed groundwater age stratification and show that the 30 year lag in rejuvenation comes from return flow of groundwater at a subsurface discharge zone that evolves along the interface between two soil types. By comparing the observed groundwater age stratification with a simple analytical approximation, we show that the observed lag in rejuvenation can be a powerful indicator of the extent and structure of the subsurface discharge zone, while the vertical gradient of the age-depth-relationship can still be used as a proxy of the overall aquifer recharge even when sampled in the discharge zone. The single age stratification profile measured in the discharge zone, close to the aquifer outlet, can reveal the main structure of the groundwater flow pattern from recharge to discharge. This groundwater flow pattern provides information on the participation of groundwater in the hydrological cycle and indicates the lower boundary of hydrological connectivity.     

Northward cooling of the Kuncha nappe and downward heating of the Lesser Himalayan autochthon distributed to the south of Mt. Annapurna,western central Nepal

We investigated the tectonothermal history of the Lesser Himalayan sediments (LHS), which are tectonically overlain by the Higher Himalayan Crystalline. Fission‐track dating and the track length measurement of detrital zircons obtained from the Kuncha nappe and the Lesser Himalayan autochthonous sediments in western central Nepal revealed northward cooling of the nappe and possible downward heating of the autochthon by the overlying hot nappe. Nine zircon fission‐track (ZFT) ages of the nappe showed northward‐younging linear distribution from 11.6 Ma in the front at Tamghas, 6 Ma in the central at Naudanda, and 1.6 Ma in the northernmost point at Tatopani. Thermochronological invert calculation of the ZFT length elucidated that the Kuncha nappe gradually cooled down (30 °C/Myr) at the front and rapidly cooled down (120 °C/Myr) at the root zone. In contrast, the ZFT age of the Chappani Formation, located just beneath the Kuncha nappe in the central part, demonstrated a totally reset age of 6.8 Ma, whereas the Virkot Formation, structurally far from the nappe, yielded a partially reset age of 457.3 Ma. This suggests that the LHS underwent downward heating, resulting in a thermal print on the upper part of the LHS; however, the thermal effect was not sufficient to anneal ZFT totally in the deeper part. Presently, the nappe cover is eroded and denuded from this area. Detrital zircons from the Chappani Formation in Tansen area to the south of the Bari Gad Fault did not show any evidence of annealing, suggesting that nappe never covered the LHS distributed to the south of the fault.     

Northward younging zircon fission‐track ages from 13 to 2 Ma in the eastern extension of the Kathmandu nappe and underlying Lesser Himalayan sediments distributed to the south of Mt. Everest

This study is concerned with the tectono‐thermal history of the Kathmandu nappe and the underlying Lesser Himalayan sediments (LHS) that are distributed in eastern Nepal. We carried out zircon fission‐track(ZFT) dating and obtained 16 ZFT ages from the eastern extension of the Kathmandu nappe, the Higher Himalayan Crystalline, Kuncha nappe, and the Main Central Thrust (MCT) zone. The ZFT ages of the frontal part of the Kathmandu nappe range from 13.0 ±0.8 Ma to 10.7 ±0.7 Ma and exhibit a northward‐younging tendency. These Middle Miocene ZFT ages indicate that the frontal part of the Kathmandu nappe remained at a temperature above 240 °C until the termination of its southward emplacement at 12–11 Ma. The ZFT ages of the LHS range from 11.1 ±0.9 Ma in the southern part of the Okhaldhunga Window to 2.4 ±0.3 Ma of the augen gneiss in the northern margin and also exhibit a northward‐younging age distribution. The ZFT ages show the northward‐younging linear distribution pattern (?0.16 Ma/km) along the across‐strikesection from the frontal part of the Kathmandu nappe to the root zone, without a significant age gap. This distribution pattern indicates that the Kathmandu nappe, the underlying MCT zone, and the Kuncha nappe cooled from the frontal zone to the root zone as a thermally united geologic body at a temperature below 240 °C. An older ZFT age (456.3 ±24.3 Ma), which was partially reset at the axial part of the Midland anticlinorium in the central part of the Okhaldhunga Window, was explained by downward heating from the “hot” Kathmandu nappe. The above evidence supported a model that southward emplacement of the hot Kathmandu nappe resulted in a thermal imprint on the upper part of the LHS; however, the lower part did not reach 240 °C.     

Timing and development of sedimentation of the Cleaverville Formation and a post‐accretion pull‐apart system in the Cleaverville area,coastal Pilbara Terrane,Pilbara, Western Australia

In the Cleaverville area of Western Australia, the Regal, Dixon Island, and Cleaverville Formations preserve a Mesoarchean lower‐greenschist‐facies volcano‐sedimentary succession in the coastal Pilbara Terrane. These formations are distributed in a rhomboidal‐shaped area and are unconformably overlain by two narrowly distributed shallow‐marine sedimentary sequences: the Sixty‐Six Hill and Forty‐Four Hill Members of the Lizard Hills Formation. The former member is preserved within the core of the Cleaverville Syncline and the latter formed along the northeast‐trending Eighty‐Seven Fault. Based on the metamorphic grade and structures, two deformation events are recognized: D₁ resulted in folding caused by a collisional event, and D₂ resulted in regional sinistral strike‐slip deformation. A previous study reported that the Cleaverville Formation was deposited at 3020 Ma, after the Prinsep Orogeny (3070–3050 Ma). Our SHRIMP U–Pb zircon ages show that: (i) graded volcaniclastic–felsic tuff within the black shale sequence below the banded iron formation in the Cleaverville Formation yields an age of (3 114 ±14) Ma; (ii) the youngest zircons in sandstones of the Sixty‐Six Hill Member, which unconformably overlies pillow basalt of the Regal Formation, yield ages of 3090–3060 Ma; and (iii) zircons in sandstones of the Forty‐Four Hill Member show two age peaks at 3270 Ma and 3020 Ma. In this way, the Cleaverville Formation was deposited at 3114–3060 Ma and was deformed at 3070–3050 Ma (D₁). Depositional age of the Cleaverville Formation is at least 40–90 Myr older than that proposed in previous studies and pre‐dates the Prinsep Orogeny (3070–3050 Ma). After 3020 Ma, D₂ resulted in the formation of a regional strike‐slip pull‐apart basin in the Cleaverville area. The lower‐greenschist‐facies volcano‐sedimentary rocks are distributed only within this basin structure. This strike‐slip deformation was synchronous with crustal‐scale sinistral shear deformation (3000–2930 Ma) in the Pilbara region.     

Low‐temperature thermochronological database of bedrock in the Japanese Islands

To provide better access to thermochronological data and understand the long‐term denudation history of the Japanese Islands, we compiled a low‐temperature thermochronological dataset of fission‐track (FT) and (U–Th–Sm)/He (He) ages for apatite and zircon in bedrocks. These thermochronometric ages are compiled from 90 literature sources and 1,096 localities, and include 418 apatite FT ages, 851 zircon FT ages, 42 apatite He ages, and 30 zircon He ages. Many FT ages have been reported previously; however, the number of He ages is limited in the Japanese Islands. The compiled data are spatially biased; for instance, more data are reported for the Chubu and Kinki districts and the Pacific coast of the Shikoku Island, whereas less data were available for the Tohoku and Chugoku districts. For better understanding arc‐scale uplift‐denudation history, further thermochronological research in the lesser‐studied regions and more He thermochronometric measurements are desired. This compilation will be updated and provided on the website of the Fission‐Track Research Group in Japan ( http://ftrgj.org/index.html ).     

宁河-昌黎断裂基于浅层地震勘探资料研究

宁河—昌黎断裂长约170 km,为燕山隆起、山海关隆起与黄骅拗陷的分界断裂,断裂西南起自宁河,向东北经南套南、大夫庄南、杨家坨,过昌黎转向东入海,断裂走向NE50°~70°,倾向SE,为上陡下缓的铲形正断层,该断裂为一条地壳基底深断裂,控制了南侧黄骅坳陷北段中、新生代沉积。河北省工程地震勘察研究院于2007年、2014年先后在昌黎、滦南、唐海、丰南布设了4条浅层地震勘探测线对宁河—昌黎断裂进行了探测,浅层地震勘探应用美国GEOMETRICS公司STRATAVISOR NX96高分辨数字地震勘探系统,采用70 kg冲击震源,单边激发多次覆盖观测系统,覆盖次数12次。应用Vista地震处理软件系统,通过对数据进行真振幅恢复、地表一致性振幅补偿等处理方法,获得高质量的地震勘探时间剖面。为获得断裂活动时代的重要信息,通过浅层地震勘探处理过程中的中间数据获得地震剖面时—深转换速度参数,从而获得地震勘探深度剖面,结合测线附近地层层序资料,与地震勘探深度剖面进行对比分析,从而获得断裂的上断点埋深和最新活动时代认识。浅层地震勘探剖面揭示,宁河—昌黎断裂浅部由一条主断层和一条次级断层组成;断层上断点埋深40~110 m,断裂活动时代具有分段活动特征,断裂北段活动时代为晚更新世早期,南段为晚更新世中期;断裂走向为北东的段落,为正断层,走向为北西的段落,以走滑运动为主。     

Seismic responses of postyield hardening single–degree-of-freedom systems incorporating high-strength elastic material

It is widely accepted that ductility design improves the seismic capacity of structures worldwide. Nevertheless, inelastic deformation allows serious damage to occur in structures. Previous studies have shown that a certain level of postyield stiffness may reduce both the peak displacement and residual deformation of a structure. In recent years, several high-strength elastic materials, such as fiber-reinforced polymer (FRP) and high-strength steel bars, have been developed. Application of these materials can easily provide a structure with a much higher and more stable postyield stiffness. Many materials, members, and structures that incorporate both high-strength elastic materials and conventional materials show significant postyield hardening (PYH) behaviors. The significant postyield stiffness of PYH structures can help effectively reduce both peak and residual deformations, providing a choice when designing resilient structures. However, the findings of previous studies of structures with elastic-perfectly plastic (EPP) behavior or small postyield stiffness may not be accurate for PYH structures. The postyield stiffness of a structure must be considered an important primary structural parameter, in addition to initial stiffness, yielding strength, and ductility. In this paper, extensive time history and statistical analyses are carried out for PYH single–degree-of-freedom (SDOF) systems. The mean values and coefficients of variation of the peak displacement and residual deformation are obtained and discussed. A new R-μ_p-T-α relationship and damage index for PYH structures are proposed. A theoretical model for the calculation of residual deformation is also established. These models provide a basis for developing the appropriate seismic design and performance evaluation procedures for PYH structures.     

4A沸石吸附模拟核素Sr,Cs后的组分变化和结构表征

通过4A沸石吸附模拟核素Sr,Cs前后的化学成分分析、X衍射分析和红外光谱分析等手段方法,分析探讨了模拟核紊Sr,Cs在4A沸石的赋存状态,结果表明：4A沸石与模拟核素Sr,Cs之间主要以离子交换的方式发生作用,Sr^2 ,Cs^ 取代4A沸石中的可交换离子Na^ ,占据4A沸石a笼中的6元环和8元环。导致4A沸石的晶胞参数增大,晶格发生畸变。