原子掺杂对单元材料结晶能力的影响

2009年我们建立了一个凝结势模型用以预测材料形成单晶体的能力,表明单元体材料(Ni,Al,Cu,Ar,Mg)的结晶能力随凝结势的增大而单调增强.本文将凝结势模型应用于二元材料体系,并结合分子动力学模拟研究了6% Al原子掺杂对于Ni单晶材料结晶能力的影响.模拟结果发现,Al元素的掺杂会大大减弱Ni单晶的结晶能力,在此基础上提出了二元材料体系凝结势的定义,表明凝结势模型可广泛应用于预测二元体材料的结晶能力.     

The complex variable reproducing kernel particle method for two-dimensional elastodynamics

On the basis of the reproducing kernel particle method (RKPM), a new meshless method, which is called the complex variable reproducing kernel particle method (CVRKPM), for two-dimensional elastodynamics is presented in this paper. The advantages of the CVRKPM are that the correction function of a two-dimensional problem is formed with one-dimensional basis function when the shape function is obtained. The Galerkin weak form is employed to obtain the discretised system equations, and implicit time integration method, which is the Newmark method, is used for time history analysis. And the penalty method is employed to apply the essential boundary conditions. Then the corresponding formulae of the CVRKPM for two-dimensional elastodynamics are obtained. Three numerical examples of two-dimensional elastodynamics are presented, and the CVRKPM results are compared with the ones of the RKPM and analytical solutions. It is evident that the numerical results of the CVRKPM are in excellent agreement with the analytical solution, and that the CVRKPM has greater precision than the RKPM.     

Single electron loss in the collisions of C3 + and atomic hydrogen

This paper studies the projectile electron loss cross sections of C^{3 +} colliding with atomic hydrogen in the frame work of extended over-barrier model at intermediate velocities (25 keV/u--600 keV/u). The electron loss is calculated in terms of the interaction between the screened target nucleus and the active projectile electron and of the interaction between projectile electron and target electron. Compared with the convergent close-coupling calculations, screening and anti-screening calculations, this model satisfactorily reproduces the experimentally obtained energy dependence of the electron-impact ionisation cross sections and the single electron loss cross sections over the energy range investigated here.     

Brillouin scattering study on elastic and piezoelectric properties of laser irradiated ZnO single crystals

Brillouin light scattering technique can be successfully used to determine the whole set of elastic and piezoelectric constants of a ZnO single crystal irradiated by different laser energy densities, into a micron range (radiation layer thickness). It is found that the scattering intensity, the linewidth and the Brillouin scattering shift of acoustic phonons are all strongly dependent on laser energy density. Based on the sound propagation equations and these results, the directional dependences of the compressional and shear moduli of the irradiated ZnO sample in the (001) plane are investigated. It is found that under an appropriate laser condition, 248 nm KrF excimer laser irradiation can significantly improve the surface quality and increase the elastic properties of ZnO single crystal. This procedure has potential applications in the fabrication of ZnO-based surface acoustic wave and optic-electronic devices.     

不同预处理方法对南海东沙海域沉积物粒度的影响

通过采用不同方法对东沙沉积物样品进行了预处理,并采用综合法进行了粒度分析,以探讨东沙沉积物中碳酸盐和有机质对其粒度的影响。结果表明,去除有机质后沉积物的平均粒径和63～4μm粒径范围内的组分明显减小,有机质含量变化与平均粒径变化呈明显负相关,说明东沙沉积物中有机质的沉积是伴随细粒悬浮物质和胶体物质沉积下来的,且对细颗粒有明显的絮凝作用;去除碳酸盐后沉积物的平均粒径呈减小趋势,但粒径范围内组分含量的变化不明显,且碳酸盐含量的变化与沉积物粒径变化的关系也不甚密切。     

Impact of hydrographic parameters and seasonal variation in sediment fluxes on coral status at Chumbe and Bawe reefs,Zanzibar, Tanzania

Coral reefs which are an important resource to coastal communities and nation at large are adversely affected by rate of sediment flux to the reefs. However, there is little information on seasonal trend in sediment flux and its impact at the reefs off Zanzibar. Two years’ monthly data on sedimentation at Chumbe and Bawe reefs were used to assess seasonal variability in sediment flux and its implication on the coral status. Sediment flux to the Bawe reefs for the duration of the study ranged from 0.2 to 41.5 mg cm⁻² d⁻¹, while it ranged from 0.8 to 65.8 mg cm⁻² d⁻¹ at the Chumbe reefs. Sediment fluxes at Bawe reefs were highest between November and March, while they were highest between April and September at Chumbe reefs. Generally, sediment fluxes at Bawe reefs were low compared to those at Chumbe. The total sediment input to the reefs ranged from 4615 to 123,403 kg d⁻¹ for Bawe reefs and 2750 to 79,636 kg d⁻¹ for Chumbe reefs. High sediment fluxes at Bawe reefs between November and March; and the Chumbe reefs between April and September can be attributed to water currents and wind pattern in the east African region which are under the influence of the monsoons. The observed trend suggests that the period for coral transplant as a management option for the two sites should be different. Coral transplant can be undertaken in such a way that stress of the corals due to sedimentation can be felt after they have overcome stress from transplant process and temperature. The results from this study contribute to the much needed information for coral transplant, restoration, and management.     

沂水南小尧金矿锆石U-Pb同位素特征及其地质意义

沂水南小尧金矿产于沂沐断裂带汞丹山凸起上,赋矿围岩为古元古代花岗岩。通过对南小尧金矿矿石中的锆石采用LA—CPMS法进行单颗粒锆石微区U—Pb同位素年龄测定,获得锆石谐和年龄（2438±13）Ma的结果,为赋矿围岩的形成年龄;而下交点（116±20）Ma大致为金矿的形成年龄。结合南小尧金矿石中钾长石矿物K—Ar年龄为（94．29±1．38）Ma的结果分析。本区金矿的形成时代应在早白垩世中-晚期。     

Cadmium and phosphorus cycling in the water column of the South China Sea: The roles of biotic and abiotic particles

The concentrations of cadmium, phosphorus, and aluminum in size-fractionated phytoplankton, zooplankton, and sinking particles are determined using ICPMS to evaluate the roles of biotic and abiotic particles on the cycling and ratios of Cd and P in the water column. Plankton were collected with a filtration apparatus equipped with 10-, 60-, and 150-μm aperture plankton nets on two occasions (2002 and 2006), and sinking particles were sampled by moored sediment traps deployed at depths of 120, 600, and 3500 m from 2004 to 2005. In contrast to what our previous study revealed, i.e., that most of the other bioactive trace metals in plankton were strongly correlated with abiotic Al and adsorbed on phytoplankton [Ho, T.Y., Wen, L.S., You, C.F., Lee, D.C., 2007. The trace metal composition of size-fractionated plankton in the South China Sea: biotic versus abiotic sources. Limnol Oceanogr 52, 1776–88.], Cd/P ratios, ranging from 0.12 to 0.34 mmol/mol P, did not vary with Al and exhibited fairly consistent values among different sizes of plankton, showing that Cd was mostly incorporated on an intracellular basis. In terms of the sinking particles, fluxes in Cd and P as well as in Cd/P ratios were strongly influenced by both biotic and abiotic particles. Overall, the Cd/P ratios in the sinking particles ranged from 0.03 to 1.2 mmol/mol, with the highest value observed in traps at 120 m during the productive season. The lowest value was observed in deep water during high flux periods for lithogenic particles. At surface depth, flux and Cd/P ratios were elevated during the most productive season in the region. The elevated ratios in the traps at 120 m were most likely related to preferential uptake of Cd for the dominant species (coccolithophores) during the productive period. Relatively, Cd/P ratios sharply decreased with increasing Al flux in deep water and ratios were much lower than the expected Cd/P ratios obtained from the relative portion of lithogenic and biogenic particles, indicating that the adsorption of soluble P into lithogenic particles was significant in the deep water during high lithogenic particle flux periods. Using averaged annual fluxes and standing stock in the water column, the residence time of biogenic Cd and P are 0.10 and 0.20, 250 and 100, and 9100 and 5000 years respectively in the top 120 m, 600 m, and water column as a whole, also showing preferential removal for Cd in the euphotic zone but relatively higher removal rates for P in the deep water. Our study suggests that the shift in microalgal community structure along with input of lithogenic minerals are both potentially important factors in influencing Cd/P ratios in oceanic water on a geological time scale.     

闽江口入海悬沙输运的数值模拟

闽江河口位于福建省东部,本文利用欧拉-拉格朗日差分方法模拟闽江口及附近海域在不同径流下的潮流场,并建立拉格朗日水质点跟踪方法近似模拟了悬沙在海域中的迁移过程．水质点运动轨迹计算结果表明,闽江口悬沙在外海主要向南方或东南方输运,其轨迹呈现螺旋线．在洪峰流量下,悬沙运移距离较远．     

椒江河口洪季最大浑浊带核部的悬沙分选机制

以实测悬沙粒径、流速、含沙量资料为基础,通过悬沙不同粒级组分、中值粒径以及粒度参数的统计,分析椒江河口最大浑浊带核部悬沙粒径分布变化特性。研究表明,悬沙粒径分选主要受物质来源、潮流动力作用下底部部分物质再悬浮和絮凝沉降3个因素的影响。其中第二个因素起主导作用,大潮期比小潮期显著,第三个因素的作用主要发生在涨落憩前后低流速期,并在表层较近底层的水体明显。