2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸的合成及其应用——多元显色体系光度法测定金属材料中的镍

报道了新显色剂2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸(BTACB)的合成,研究了在十二烷基硫酸钠(NaLS)存在下Ni~(2+)与BTACB形成蓝紫色配合物的条件,其λ_(max)~(MR)=600nm,ε=2.79×10~4L·mol~(-1)·cm~(-1),Ni在0～0.6μg/ml范围内服从比尔定律,反应具有一定的选择性。方法已用于直接测定铝合金、纯镁及含一定量Co的钢铁中痕量Ni和经萃取分离后测定纯钴中痕量Ni。     

哌啶树脂在富集分离中应用研究——Ⅰ.岩石矿物中痕量银的分离富集及测定

本文采用410哌啶树脂分离岩石矿物中基体元素后富集痕量Ag。交换酸度为0.25—3.5mol/LHCl介质,树脂柱上的Ag用热的0.5—1.0％硫脲解脱,并以火焰原子吸收法测定。方法简便、快速,用于岩矿中痕量Ag的富集和测定结果满意。     

Fast sequential indicator simulation: Beyond reproduction of indicator variograms

Sequential Indicator Simulation (SIS), although widely used, is relatively slow, and requires tedious inference of a large number of indicator variogram models. SIS is designed only to estimate class proportions and to reproduce indicator variogram models; the statistics of the continuous attribute being simulated,z-histogram and variogram, may be poorly reproduced. Several implementations of the SIS algorithm are proposed resulting in better reproduction of statistics yet with better CPU performance.     

A projective approach to orbit determination from three sight-lines

Concepts from projective geometry are used to provide a coherent framework for the determination of orbits from observation data comprising lines of sight at three known times. A novel way of presenting the results in a finite diagram is introduced, The effectiveness of the approach is demonstrated by an example, using a simple spreadsheet. A computer-graphic implementation is recommended.     

Modelling and distance determination of planetary nebulae

At present the lack of a good, generally accepted distance scale is the major limitation in the study of Planetary Nebula (PN) evolution and their distribution. We describe our fully self-consistent method to derive the physical parameters of a PN, including its distance, from a set of observables. For this we calculate various models and search for a best fit of the model predictions to the observables. An accurate determination of the angular diameter is important for a good distance determination. We think that we shall achieve an accuracy of 30% in distance. We estimate the error in stellar temperature at less than 15% and the uncertainty in the abundances at 0.10 dex.     

Yarkovsky detection opportunities: II. Binary systems

We consider the possibility of detecting the Yarkovsky orbital perturbation acting on binary systems among the near-Earth asteroids. This task is significantly more difficult than for solitary asteroids because the Yarkovsky force affects both the heliocentric orbit of the system's center of mass and the relative orbit of the two components. Nevertheless, we argue these are sufficiently well decoupled so that the major Yarkovsky perturbation is in the simpler heliocentric motion and is observable with the current means of radar astrometry. Over the long term, the Yarkovsky perturbation in the relative motion of the two components is also detectable for the best observed systems. However, here we consider a simplified version of the problem by ignoring mutual non-spherical gravitational perturbations between the two asteroids. With the orbital plane constant in space and the components' rotation poles fixed (and assumed perpendicular to the orbital plane), we do not examine the coupling between Yarkovsky and gravitational effects. While radar observations remain an essential element of Yarkovsky detections, lightcurve observations, with their ability to track occultation and eclipse phenomena, are also very important in the case of binaries. The nearest possible future detection of the Yarkovsky effect for a binary system occurs for (66063) 1998 RO₁ in September 2006. Farther out, even more statistically significant detections are possible for several other systems including 2000 DP₁₀₇, (66391) 1999 KW₄ and 1996 FG₃.     

北斗卫星ECOM光压模型参数选择策略分析

以ECOM经验光压模型为基础,利用北斗卫星3年的精密星历进行轨道拟合,获得了ECOM光压参数的变化规律,给出了北斗3类卫星的ECOM光压参数选择策略。从北斗卫星姿态控制模式出发,通过卫星星体受照分析,指出在北斗卫星地影期零偏航状态下,由于太阳对卫星帆板的不正照,导致与动态偏航姿态相比,光压摄动力存在与轨道周期相关的分量,需要在ECOM 5参数的基础上增加D向周期分量进行吸收。通过MGEX全球网数据定轨试验,本文提出的方法可使零偏段定轨重叠段位置精度提高50%~80%。     

星地跟踪网的导航卫星精密轨道确定及预报

针对区域跟踪网不能覆盖导航卫星全弧段从而导致卫星定轨精度低的问题,简述了导航卫星和低轨卫星联合定轨模型,然后利用星地跟踪网观测数据同时确定了低轨卫星和导航卫星精密轨道,并根据实验结果详细分析了低轨卫星在联合定轨中所起到的作用。计算结果表明,引入低轨卫星之后,全球网和区域网定轨精度分别平均提高了20.0%和44.3%,区域网6h和24h的轨道预报精度分别优于10cm、13cm,利用星地跟踪网观测数据联合定轨方案是一种提高定轨精度并削弱对地面站依赖性的有效方法。     

星载GPS的多目标跟踪数据处理方法

针对测量船外测数据对多个目标进行定轨精度较低的问题,该文提出了星载GPS数据、测量船外测数据的融合处理方法。在多目标测控任务中,航天测量船船载设备获取的外测数据仅包含一个主跟踪目标的测角数据和多个跟踪目标的测距数据,且测角数据精度较低,该文采用由星载GPS数据获取的等效测角数据和由测量船外测设备获取的测距数据进行定轨,经过分析试算,该方法有效弥补了船载外测设备测角数据精度较低的问题,提高了初轨确定的能力以及卫星星间距离的解算精度。     

Simultaneously simulate vertical and horizontal expansions of a future urban landscape: a case study in Wuhan,Central China

While there are extensive studies of urban 2D forms, research on the varying geometric features and spatial distribution patterns of urban 3D spaces is comparatively rare. In this paper, we propose a coupled model, known as BPANN-CBRSortCA, which is based on a back propagation artificial neural network (BPANN) and case-based reasoning technology with sort cellular automaton (CBRSortCA) to simulate future urban building heights and their spatial distribution. BPANN–CBRSortCA uses BPANN to predict the vertical extrusion of building heights and uses CBRSortCA to simulate horizontal urban expansion. The BPANN–CBRSortCA model is innovative because of its capabilities to simultaneously project urban growth in the vertical and horizontal dimensions. The proposed model also overcomes the limitations of the traditional cellular automata models that cannot simulate ‘diffused’ urban expansion. This research used Wuhan City as a case study to simulate vertical and horizontal urban expansion from 2015 to 2025. The results showed the following: (1) in the next 10 years, new build-up will mainly appear along the edge of Hongshan and Hanyang Districts or will occupy bare land in the form of ‘filling’ and (2) the tallest buildings will be mainly located to the south of East Lake in Hongshan District and on undeveloped land within the city. These simulation results can provide a reference for future urban planning.