植物样品中无机元素分析的样品前处理方法和测定技术

植物样品中无机元素的分析测定在环境地球化学和生物地球化学的研究中起着重要作用。植物样品中元素含量一般较低,须选用科学合理的前处理技术和灵敏度高、精密度好、检出限低的测定方法。本文针对植物样品前处理方法和无机元素分析测定技术的研究进展、优势与不足进行评述。前处理方法主要根据样品和待测元素的性质进行选择:干法灰化所用试剂少、空白值低,但组织致密型的样品不易灰化完全、高温下易造成元素挥发损失;湿法消解样品消解较为完全,但试剂消耗大、空白值高、操作繁琐;微波消解可以防止部分易挥发元素损失,用酸量少、消解速度快,但称样量相对较小,不适于需要大称样量的样品分析。几乎所有针对元素分析的仪器分析技术都可以用于植物样品分析,主要根据仪器适用的元素、必要的干扰校正以及基体改进等方面进行选择:电感耦合等离子体质谱法可同时测定植物样品中40种以上的元素,高分辨质谱的检出限可达fg/mL;电感耦合等离子体发射光谱法适用于某些植物样品中含量较高的P、K、Na等元素的测定;原子吸收光谱法可分析元素达70余种,是普及程度最高的仪器分析技术之一;原子荧光光谱法与氢化物发生技术的联用,在元素含量较低的植物样品分析中技术优势更加明显;新兴的激光诱导击穿光谱技术已被应用于植物样品分析,无需复杂的样品前处理,操作简单快速,可实现原位、在线、实时、多元素同时检测;其他选择性强、灵敏度高的分析技术,满足了一些特定元素不能用常规分析技术测定的需求。当前主流分析技术的样品前处理方法都存在着缺陷,固体进样技术将成为植物样品分析领域的发展方向之一。     

Repeating aftershocks of the great 2004 Sumatra and 2005 Nias earthquakes

We investigate repeating aftershocks associated with the great 2004 Sumatra–Andaman (Mw 9.2) and 2005 Nias–Simeulue (Mw 8.6) earthquakes by cross-correlating waveforms recorded by the regional seismographic station PSI and teleseismic stations. We identify 10 and 18 correlated aftershock sequences associated with the great 2004 Sumatra and 2005 Nias earthquakes, respectively. The majority of the correlated aftershock sequences are located near the down-dip end of a large afterslip patch. We determine the precise relative locations of event pairs among these sequences and estimate the source rupture areas. The correlated event pairs identified are appropriately referred to as repeating aftershocks, in that the source rupture areas are comparable and significantly overlap within a sequence. We use the repeating aftershocks to estimate afterslip based on the slip-seismic moment scaling relationship and to infer the temporal decay rate of the recurrence interval. The estimated afterslip resembles that measured from the near-field geodetic data to the first order. The decay rate of repeating aftershocks as a function of lapse time t follows a power-law decay 1/t^p with the exponent p in the range 0.8–1.1. Both types of observations indicate that repeating aftershocks are governed by post-seismic afterslip.     

CFL-03型风廓线雷达收发对接技术的改进

在风廓线雷达的数据应用过程中,雷达获取数据的准确性至关重要,而风廓线雷达的收发对接过程又直接影响获取数据的准确性,因此,对雷达的收发对接技术进行研究非常重要。一般来说,对于该类型风廓线雷达的对接方法采用一种间接测试的方法,对接过程中要反复调整频综脉冲、发射脉冲、收发开关脉冲、封闭脉冲等的波形作用时间和脉宽。另外,收发开关脉冲的后沿并非标准矩形脉冲的后沿,位置难以确定,其后沿设置的位置离发射脉冲太近会产生高频头被击穿烧毁的现象,太远则会影响低层风的测风质量。以CFL-03型风廓线雷达为例,介绍了风廓线雷达的一般收发对接技术和改进的对接技术,以及频综、发射脉冲、收发开关脉冲、封闭脉冲等相关时序的确定方法。经过实践验证,两种对接技术都满足了设备的使用要求,而改进的收发对接技术,更直观形象,易于操作。     

参数化地震子波估计模型定阶方法研究综述

参数化模型地震子波提取中模型阶数的确定对子波提取的精度至关重要,笔者针对因果地震子波MA、ARMA模型,总结了目前比较成熟的四类定阶方法：相关分析法、信息量准则法、线性代数法及基于优化算法的模型定阶方法,分析比较发现这些算法都存在不同程度的缺陷,只能在各自的适用范围内得到较好的定阶结果,针对算法在子波建模应用中的不足提出了改进建议;同时分析比较了基于高阶累积量的非因果系统模型定阶的各种方法,并对非因果地震子波模型定阶进行了展望.     

Determination of the Tropospheric Hydroxyl Radical by Liquidphase Scrubbing and HPLC: Preliminary Results

A preliminary study was carried out toexamine the feasibility of measuring tropospherichydroxyl radicals (OH) by liquidphase scrubbing andhigh performance liquid chromatography (HPLC). Thepotential advantages of this approach are itssimplicity, portability, and low expense. Thesampling system employs glass bubblers to trapatmospheric OH into a buffered solution of salicylicacid (o-hydroxybenzoic acid, OHBA). Rapidreaction of OH with OHBA produces a stable fluorescentproduct, 2,5-dihydroxybenzoic acid (2,5-DHBA), whichis determined by reverse-phase HPLC and fluorescencedetection. Our preliminary field results indicatethat this method is most suitable for OH measurementsin clean tropospheric air, where interferences fromother atmospheric species appear to be negligible orminor relative to polluted air. In clean air, thesampling period is about 45–90 minutes, which yieldsa detection limit of approximately 3–6 ×10⁵ radicalscm^-3. During an OHintercomparison experiment at the Caribou samplingsite in Colorado, our liquidphase scrubber method wascompared with the ion-assisted mass spectrometry (MS)method. Our results were within the same range asthose of the ion-assisted MS method (1–5 ×10⁶ radicals cm^-3) within our precision atthat time (about ±30–50%). Preliminary testsin Pullman, WA indicated that the method might alsofunction in moderately polluted air by acidifying thescrubbing solution or by adding a scavenger tosuppress interferences. In Pullman, mid-day OHconcentrations were usually in the range of 2–20 ×10⁶ radicals cm^-3. Nighttime OHconcentrations were always low, either at or slightlyabove the detection limit.     

THE STUDY OF RETRIEVAL THEORY AND METHODS FROM SATELLITE REMOTE SENSING FOR METEOROLOGICAL PARAMETERS OVER EASTERN ASIA-PARTI:ISPRM AND SRRM

A review of ten-year's practice in developing the improved simultaneous physical retrievalmethod(ISPRM)is given in the hope that some creative ideas can be drawn from it.Theimprovement upon the SPRM is associated with the under-determinedness of this ill-posed inverseproblem.In our experiment,the precondition is observed that prior information must beindependent of the satellite measurements.The well-posed retrieval theory has told us that theforward process is fundamental for the retrieval,and it is the bridge between the input of satelliteradiance and the output of retrievals.In order to obtain a better result from the forward process.the full advantage of every prior information available must be taken.It is necessary to turn the ill-posed inverse problem into the well-posed one.Then by using the Ridge regression or Bayesalgorithm to find the optimal combination among the first guess,the theoretical analogueinformation and the satellite observations,the impact of the under-determinedness of this inverseproblem on the numerical solution is minimized.     

PRB数字地质填图前期数据准备及PRB过程字典库建立

PRB数字地质填图前期数据准备包括软硬件准备、地形图数值化、前人资料的收集和室内录入、多元数据的叠加和整合、PRB过程字典库的编制等方面.PRB过程字典库由结构化字典、填缺式字典和描述性字典3部分组成.结构化字典和填缺式字典可直接查询, 为1~1.5级字典, 描述性字典为2级字典, 需要2级查询.不同的字典类型均以文本文档的形式存在, 文件名后缀为.DIC.      

冻土中微裂纹尺寸的识别与确认

在对冻土微观结构试验观测的基础上,提出了对冻土中微裂纹尺寸进行识别和确认的方法,给出了3种典型土质在不同温度下的微裂纹尺寸参考值,为应用冻土强度破坏准则进行定量计算与分析提供依据。将冻土微裂纹损伤区作为冻土体的缺陷处理,并按“当量化裂纹”原则,把冻土微裂纹损伤区简化为“当量裂纹”,如此给出了理论估算微裂纹尺寸的新途径。把理论计算与试验观测结果进行比较,二者符合较好。     

四川稀土矿（氟碳铈矿）稀土总量的测定方法

氟碳铈矿矿样经高氟酸分解、脱硅后,稀土元素以氢氧化物和草酸盐形成进行沉淀与干扰元素分离,氢氧化物沉淀使稀土与钙、镁分离,草酸盐沉淀,使稀土与铁、铝、锆、钛等元素分离。适应矿石稀土含量１％～７４％的含量测定。该方法用于氟硕铈矿稀土总量的测定,方法简便、快速、准确。     

The role of constraints on joint hypocentre determination in seismotectonic studies

In this paper we show how the performance of the joint hypocentre determination (JHD) method can be improved, leading to reduced instability in cases close to singularity. The method has been extended by imposing a number of constraints introduced by other authors, and adding a new one. We tested the stability of the method and the relative advantages of the various constraints by simulating a geometrical space distribution of hypocentres recorded by a regional seismic network. We then applied this method to deep earthquakes that occurred in the Southern Tyrrhenian Sea subduction zone and to the seismicity of the Northern Apennines, which is moderately deeper than the typical shallow seismicity of the Apennines. The results obtained from the analysis of synthetic data and actual earthquakes confirm that the JHD method produces less scatter in the hypocentral determinations with respect to the standard locations. The main conclusion of our study is that we can significantly reduce the systematic mislocations that result from applying JHD to very clustered seismicity if we introduce the appropriate set of constraints.