从硫酸锂粗矿中分离富集锂的实验研究

针对从西藏查波措盐湖卤水中获得的硫酸锂粗矿,开展从该矿物中分离提取锂的研究。根据该矿物的组成,设计了去除与锂离子共存的镁、硫酸根等主要离子的工艺路线,通过除镁、硫酸根、钙等过程和蒸发浓缩、结晶分离等步骤,得到了杂质离子含量较低的富锂溶液。实验对除镁步骤的加水量、加料方式、反应时间、Ca O加入量等反应关键控制因素进行了考察,确定了较优的分离条件。     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

四水硝酸钙熔盐的结构研究

用θ~θ液体衍射仪精确测量了Ca(NO3)2.4H2O熔体的X射线衍射数据,通过数据处理给出了熔盐的结构函数和实验径向分布函数曲线,并由r=0.618λ/sinθ对结构函数曲线进行了定性描述;通过理论模型计算获得了熔体配位结构参数。研究结果表明,熔体中至少存在一种带单氧桥键或双氧桥键的双核配合物;并用计算给出的局域结构模型,讨论了熔体结构对晶体生长过程的影响。     

1991年江淮梅雨暴雨与亚洲季风的关系

利用实际大气参数取值进行尺度分析，求得斜压半地转模式中非线性斜压Ｒｏｓｓｂｙ波的非频散周期解的存在条件与解。给出了能够描述非线性特性波动的无量纲拟能效ε，由此推导了非线性特征波动的波速公式及波参数间的一些诊断关系。     

对流云街激发的重力波和波动阻力

大气边界层中的对流活动,可以在其上部稳定层中激发出重力波,并引起垂直动量输送,影响到对流层和平流层中的动量平衡过程.从二层模式中大气波动方程的线性解出发,得出了对流云街激发的重力波波阻解析表达式,并讨论了大气条件对波阻的影响.这些分析可有助于大气环流模式(GCM)中此类重力波波阻参数化表达式的建立和改进.     

Infiltration in unsaturated soils – An analytical approach

An approximate analytical solution has been established for the well known Richards’ equation for unsaturated flow of transports in soils. Despite the importance of Richards’ equation in geotechnical and geoenvironmental applications, most solutions to the problem are generally based on numerical methods often having limitations in application. It is therefore advantageous to explore analytical solutions to the problem. The proposed solution is based on homotopy analysis method (HAM). The method is superior over traditional perturbation techniques in a sense that it is not dependent on the assumption of a small parameter as the initial step. Several simple cases have been explored to describe the application of HAM to Richards’ equation. The results obtained by HAM are also compared with existing solutions to demonstrate the accuracy of the proposed method.     

Semi-analytical solution to one-dimensional consolidation for viscoelastic unsaturated soils

This paper presents a semi-analytical solution to one-dimensional consolidation of viscoelastic unsaturated soils with a finite thickness under oedometric conditions and subjected to a sudden loading. The solution is obtained by using Lee’s correspondence principle based on the semi-analytical solution to one-dimensional consolidation of elastic unsaturated soils. The boundary contains the top surface permeable to water and air and the bottom impermeable to water and air. A typical example is given to show the evolution of excess pore-air and pore-water pressures as well as the total degree of consolidation of the soil layer with time for different ratios of air–water permeability coefficient, elastic modulus and viscoelastic coefficient. The one-dimensional consolidation behavior of viscoelastic unsaturated soil is discussed according to the semi-analytical solution. These results contribute to a better understanding of the consolidation behavior of viscoelastic unsaturated soils.     

飑线的非线性重力波行波解模型

本文提出了一个飑线的非线性重力波行波解模型,并将该模型与实际飑线作了比较,结果表明,该模型可反映出飑线的主要特征.     

广西大厂电气石的成分与成因初探

镁电气石不一定只产于喷气岩或喷气矿床，在花岗岩中也有产出。大厂花岗岩及其有关锡多金属矿床中的电气石属铁镁系列，产于岩体中者富Ｆｅ贫Ｍｇ，产于矿体中者贫Ｆｅ富Ｍｇ，并有随远离源区Ｍｇ含量增高的趋势，与国内外同类矿床电气石成分的演化规律相一致。锡石硫化物矿体中电气石富镁的原因是多方面的，其中Ｍｇ、Ｆｅ两元素亲硫性的明显差别可能是导致Ｆｅ富集于黄铁矿等硫化物中、而Ｍｇ富集于电气石等蚀变矿物内的重要原因