Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

深置矩形基础与地基共同作用解析分析

基于集中力作用下的Mindlin解位移公式,推导得到均布荷载作用下的地基柔度系数,对地基上的四周自由板与地基共同作用进行简化计算,得出了考虑埋深时地基基础共同作用的解析公式。在基础板为刚性和弹性、荷载为集中荷载及均布荷载的情况下,对考虑埋深时的Mindlin解与不考虑埋深时的Boussinesq解的计算结果进行比较,表明,埋深比对于基础沉降、地基反力的分布、基础板的弯矩等都有一定的影响。给出了考虑埋深时的沉降修正系数公式,以供工程应用参考。     

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).     

等双轴拉应变对无纺土工织物孔径变化的影响

无纺土工织物作为一种反滤材料,在工程中常受土体作用产生平面双轴拉应变,导致织物孔径变化。基于无纺织物空间网络孔径模型,改进Rawal公式中织物孔径结构总层数的算法,并提出等双轴拉伸下织物孔径分布曲线的解析解。利用自主研发的双轴拉伸仪,将两种针刺无纺织物等双轴拉伸至应变为3%、5%、10%,采用应变控制下的干筛法,进行织物孔径分布曲线测试。将解析解与试验结果进行对比分析,解析解孔径值偏大,所得解析曲线与测试曲线对于较薄织物吻合更好。研究结果表明,随着双轴拉应变的增加,无纺织物孔径增大,其特征孔径O95、O50、O30都近似与拉伸应变呈线性变化关系。     

二维TIM中的传播矩阵与面波相速度

本文利用横向各向同性介质（ＴＩＭ）中的传播矩阵和面波形成条件，导出了面波波慢度方程。对瑞利波给出了各向同性及横向各向同性弹性介质中其相速度的解析解；对于勒夫波，给出了横向各向同性介质中的波慢度方程。     

饱和土半空间中圆柱形孔洞对平面P波的散射

在 Biot饱和多孔介质动力学理论的基础上,首次建立了求解饱和土半空间中圆柱形孔洞对平面 P 波散射问题的波函数展开法。首先。分析了具有圆柱形孔洞的饱和土半空间场地在平面 P 波入射下产生散射波系,并将入射波和散射波的波函数在圆柱坐标下展开。然后,引入边界条件,求出散射波函数的待定系数,从而,得到饱和土半空间中圆柱形孔洞对平面P波的散射问题的解析解。根据所得的波函数的解,可求解区域内的位移、应力的值,同时,分析了入射波频率、入射角对柱面上的应力集中因子的影响。     

Element budgets of pine stands on lignite and pyrite containing mine soils

To analyze the development of pine ecosystems on lignite and pyrite containing mine soils, four pine stands with ages of 3–35 years were investigated in a chronosequence approach. Bulk precipitation, throughfall and soil solution in depths of 20, 40, 70 and 100 cm were studied over a three-year period to determine element fluxes in these forest ecosystems on extreme acidic and saline soils.Element budgets are controlled by the processes induced by pyrite oxidation such as intensive weathering of primary minerals, precipitation and leaching of secondary phases.Despite low water fluxes, element outputs can reach extraordinary high values due to very high concentrations in the soil solution. Although element outputs decrease drastically with stand age, respectively, site age, they exceed those of comparable pine stands on non-mine sites. Nitrogen release from the lignite fraction represents a special characteristic of the examined substrates. Nitrogen losses beneath the rooted zone can be 34 kg N ha⁻¹ yr⁻¹ in 100 cm depth. Element input and output in the examined ecosystems are far from balance. Closed cycling of nutrients seems to be recognizable in the case of potassium.     

边界条件对土层粘弹性地震反应的影响

边界条件是土层粘弹性地震反应必须考虑的问题。对于地表面，一般作为自由边界，而对于地下深处基岩面，边界条件有两种处理方法：一是静止边界，二是非静止边界的。首先给出了在时间域内单层地基一维土层粘弹性地震反应封闭解析解，然后从理论上分析边界条件对土层粘弹性地震反应的影响，认为采用静止边界进行土层地震反应计算得到的地震动加速度时程符合天然地震记录形式，而采用非静止边界进行土层地震反应计算得到的地震动加速度时程初始阶段出现较大幅度的振荡现象，随着土层厚度增加，这种振荡现象逐渐减弱直至消失。当土层阻尼较小或剪切波速增长时，振荡现象加剧；当土层阻尼比较大或剪切波速减小时，振荡现象减弱。此外，采用非静止边界进行土层地震反应计算，表现出随着土层厚度的增加，土层对基岩输入地震动的放大作用逐步转化为吸收作用。     

Pressure Solution of Sulphides in Some Massive Sulphide Zinc—lead Deposits of Western Canada：Its Significance in Mobilization of Ore—forming Materials

Pressure solution is a common phenomenon in massive sulphide zinc-lead deposits of western Canada and may have been an important factor leading to the mobilization of ore-forming materials during diagenesis, deformation and metamorphism of sedimentary ores.The control of ductile shear zones over gold mineralization could be explained in view of pressure solution of gold-bearing miner-als under shearing stress and the tesultant mobilization of this metal.     

CHARACTERISTICS OF FOCAL MECHANISMS AND STRESS FIELD OF YUNNAN AREA

Using the seismic waveform data recorded by regional seismic network of Yunnan and Sichuan and the method of CAP, we calculate and obtain the focal mechanism of 268 earthquakes with the magnitude of M_L≥4.0 occurring in Yunnan during Jan. 1999 to Aug. 2014; then, we analyze the types and the regional feature of the focal mechanism of earthquakes in Yunnan, on the basis of the focal mechanism of 109 earthquakes analyzed by Harvard University. Based on the data of the above focal mechanism solutions, we adopt the method of damped regional-scale stress inversion to calculate the best-fitting tectonic stress tensor of every grid in Yunnan; and adopt the method of maximum principal stress to calculate the direction of maximum horizontal principal stress in Yunnan. The result shows that: (1)the strike-slip type is the most principal type of the earthquake focus in the study area and the second is the normal faulting type; while, the reverse-fault type is relatively small. The spatial distribution of focal mechanism is obvious. This reflects that the dynamic source and acting force are different in different parts of the study area. (2)The direction of the stress field in Yunnan shows a certain spatial continuity. Maximum horizontal principal compressive stress is mainly clockwise from north to south and counterclockwise from the west to the east. The direction of stress field shows inhomogeneity in space. There exist two stress conversion zones respectively in EW and NS direction. The inversion result of stress field shows that the stress field in Yunnan is complex and the principal stress direction changes greatly; and there are obvious differences in different regions.