Suspended sediment and total dissolved solid yield patterns at the headwaters of Urumqi River,northwestern China: a comparison between glacial and non‐glacial catchments

In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.     

Submarine groundwater discharge revealed by aerial thermal infrared imagery: a case study on Jeju Island,Korea

Submarine groundwater discharge (SGD) is a global phenomenon that carries large volumes of groundwater and dissolved chemical species such as nutrient, metals, and organic compounds to coastal zones. We report the influence of SGD on the coastal waters of Jeju Island, Korea, using high‐resolution aerial thermal infrared (TIR) mapping techniques and field investigations. An aircraft‐based system was implemented using a cost‐effective TIR camera for aerial TIR mapping. Ground‐based calibrations and system integration with GPS/IMU (global positioning system/inertial measurement unit) were performed for the aerial systems. The aerial surveys showed distinct low‐temperature signatures of SGD along the coasts of Jeju Island, revealing large groundwater inputs from the coastal aquifers to the ocean. Multiple aerial surveys over a range of seasons and tidal stages revealed that SGD rates dynamically affect the sea surface temperature (SST) of the coastal zone. The in‐situ measurements supported that SGD has a substantial influence on the coastal water chemistry as well as SST. Our observations highlight the extent to which aerial‐based TIR mapping can serve as a powerful tool for studying SGD and other coastal processes. Copyright © 2016 John Wiley & Sons, Ltd.     

Dissolved inorganic carbon evolution in neutral discharge from mine tailings piles

We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ¹³C_DIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ¹³C_DIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO_2(aq) because of the loss of excess CO_2(aq) from the discharge. The corresponding enrichment in the δ¹³C_DIC is because of kinetic isotope fractionation accompanying the loss of CO_2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ¹³C_DIC. The insignificant change in the DIC concentrations and the δ¹³C_DIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO_2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO_2(aq) to the atmosphere and the DIC becomes enrich in ¹³C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.     

Root‐zone moisture replenishment in a native vegetated catchment under Mediterranean climate

The root‐zone moisture replenishment mechanisms are key unknowns required to understand soil hydrological processes and water sources used by plants. Temporal patterns of root‐zone moisture replenishment reflect wetting events that contribute to plant growth and survival and to catchment water yield. In this study, stable oxygen and hydrogen isotopes of twigs and throughfall were continuously monitored to characterize the seasonal variations of the root‐zone moisture replenishment in a native vegetated catchment under Mediterranean climate in South Australia. The two studied hillslopes (the north‐facing slope [NFS] and the south‐facing slope [SFS]) had different environmental conditions with opposite aspects. The twig and throughfall samples were collected every ~20 days over 1 year on both hillslopes. The root‐zone moisture replenishment, defined as percentage of newly replenished root‐zone moisture as a complement to antecedent moisture for plant use, calculated by an isotope balance model, was about zero (±25% for the NFS and ± 15% for the SFS) at the end of the wet season (October), increased to almost 100% (±26% for the NFS and ± 29% for the SFS) after the dry season (April and May), then decreased close to zero (±24% for the NFS and ± 28% for the SFS) in the middle of the following wet season (August). This seasonal pattern of root‐zone moisture replenishment suggests that the very first rainfall events of the wet season were significant for soil moisture replenishment and supported the plants over wet and subsequent dry seasons, and that NFS completed replenishment over a longer time than SFS in the wet season and depleted the root zone moisture quicker in the dry season. The stable oxygen isotope composition of the intraevent samples and twigs further confirms that rain water in the late wet season contributed little to root‐zone moisture. This study highlights the significant role of the very first rain events in the early wet season for ecosystem and provides insights to understanding ecohydrological separation, catchment water yield, and vegetation response to climate changes.     

Frequency analysis of nonstationary annual maximum flood series using the time‐varying two‐component mixture distributions

The most popular practice for analysing nonstationarity of flood series is to use a fixed single‐type probability distribution incorporated with the time‐varying moments. However, the type of probability distribution could be both complex because of distinct flood populations and time‐varying under changing environments. To allow the investigation of this complex nature, the time‐varying two‐component mixture distributions (TTMD) method is proposed in this study by considering the time variations of not only the moments of its component distributions but also the weighting coefficients. Having identified the existence of mixed flood populations based on circular statistics, the proposed TTMD was applied to model the annual maximum flood series of two stations in the Weihe River basin, with the model parameters calibrated by the meta‐heuristic maximum likelihood method. The performance of TTMD was evaluated by different diagnostic plots and indexes and compared with stationary single‐type distributions, stationary mixture distributions and time‐varying single‐type distributions. The results highlighted the advantages of TTMD with physically‐based covariates for both stations. Besides, the optimal TTMD models were considered to be capable of settling the issue of nonstationarity and capturing the mixed flood populations satisfactorily. Copyright © 2016 John Wiley & Sons, Ltd.     

Generation of continuous surface soil moisture dataset using combined optical and thermal infrared images

Surface soil moisture (SSM) is a critical variable for understanding water and energy flux between the atmosphere and the Earth's surface. An easy to apply algorithm for deriving SSM time series that primarily uses temporal parameters derived from simulated and in situ datasets has recently been reported. This algorithm must be assessed for different biophysical and atmospheric conditions by using actual geostationary satellite images. In this study, two currently available coarse‐scale SSM datasets (microwave and reanalysis product) and aggregated in situ SSM measurements were implemented to calibrate the time‐invariable coefficients of the SSM retrieval algorithm for conditions in which conventional observations are rare. These coefficients were subsequently used to obtain SSM time series directly from Meteosat Second Generation (MSG) images over the study area of a well‐organized soil moisture network named REMEDHUS in Spain. The results show a high degree of consistency between the estimated and actual SSM time series values when using the three SSM dataset‐calibrated time‐invariable coefficients to retrieve SSM, with coefficients of determination (R²) varying from 0.304 to 0.534 and root mean square errors ranging from 0.020 m³/m³ to 0.029 m³/m³. Further evaluation with different land use types results in acceptable debiased root mean square errors between 0.021 m³/m³ and 0.048 m³/m³ when comparing the estimated MSG pixel‐scale SSM with in situ measurements. These results indicate that the investigated method is practical for deriving time‐invariable coefficients when using publicly accessed coarse‐scale SSM datasets, which is beneficial for generating continuous SSM dataset at the MSG pixel scale.     

Reevaluating suitability estimates based on dynamics of cropland expansion in the Brazilian Amazon

Agricultural suitability maps are a key input for land use zoning and projections of cropland expansion. Suitability assessments typically consider edaphic conditions, climate, crop characteristics, and sometimes incorporate accessibility to transportation and market infrastructure. However, correct weighting among these disparate factors is challenging, given rapid development of new crop varieties, irrigation, and road networks, as well as changing global demand for agricultural commodities. Here, we compared three independent assessments of cropland suitability to spatial and temporal dynamics of agricultural expansion in the Brazilian state of Mato Grosso during 2001–2012. We found that areas of recent cropland expansion identified using satellite data were generally designated as low to moderate suitability for rainfed crop production. Our analysis highlighted the abrupt nature of suitability boundaries, rather than smooth gradients of agricultural potential, with little additional cropland expansion beyond the extent of the flattest areas (0–2% slope). Satellite-based estimates of the interannual variability in the use of existing crop areas also provided an alternate means to assess suitability. On average, cropland areas in the Cerrado biome had higher utilization (84%) than croplands in the Amazon region of northern Mato Grosso (74%). Areas of more recent expansion had lower utilization than croplands established before 2002, providing empirical evidence for lower suitability or alternative management strategies (e.g., pasture–soya rotations) for lands undergoing more recent land use transitions. This unplanted reserve constitutes a large area of potentially available cropland (PAC) without further expansion, within the management limits imposed for pest management and fallow cycles. Using two key constraints on future cropland expansion, slope and restrictions on further deforestation of Amazon or Cerrado vegetation, we found little available flat land for further legal expansion of crop production in Mato Grosso. Dynamics of cropland expansion from more than a decade of satellite observations indicated narrow ranges of suitability criteria, restricting PAC under current policy conditions, and emphasizing the advantages of field-scale information to assess suitability and utilization.     

Modelling the flow of self‐compacting concrete

A Lagrangian particle‐based method, smooth particle hydrodynamics (SPH), is used in this paper to model the flow of self‐compacting concretes (SCC) with or without short steel fibres. An incompressible SPH method is presented to simulate the flow of such non‐Newtonian fluids whose behaviour is described by a Bingham‐type model, in which the kink in the shear stress vs shear strain rate diagram is first appropriately smoothed out. The viscosity of the SCC is predicted from the measured viscosity of the paste using micromechanical models in which the second phase aggregates are treated as rigid spheres and the short steel fibres as slender rigid bodies. The basic equations solved in the SPH are the incompressible mass conservation and Navier–Stokes equations. The solution procedure uses prediction–correction fractional steps with the temporal velocity field integrated forward in time without enforcing incompressibility in the prediction step. The resulting temporal velocity field is then implicitly projected on to a divergence‐free space to satisfy incompressibility through a pressure Poisson equation derived from an approximate pressure projection. The results of the numerical simulation are benchmarked against actual slump tests carried out in the laboratory. The numerical results are in excellent agreement with test results, thus demonstrating the capability of SPH and a proper rheological model to predict SCC flow and mould‐filling behaviour. Copyright © 2010 John Wiley & Sons, Ltd.     

Late Triassic E-MORB-like basalts associated with porphyry Cu-deposits in the southern Yidun continental arc,eastern Tibet: Evidence of slab-tear during subduction?

It is generally believed that andesite–dacite–rhyolite suites and contemporary porphyry Cu deposits are related to subduction in active continental margin settings. However, it is still unclear which tectonic events result in the generation of porphyry Cu deposits and whether asthenospheric mantle material is involved in this process. Widespread andesitic–dacitic felsic intrusions associated with porphyry Cu deposits and rarer basalts have been identified in the Late Triassic southern Yidun arc (SYA) of eastern Tibet. However, few geochronological and geochemical data are available for these basalts, thereby hampering the development of geodynamic models for this magmatic event and the formation of related porphyry Cu deposits in the region. Here we present the first geochemical and SIMS (secondary ion mass spectrometry) zircon U–Pb data of Xiaxiaoliu basalts in the SYA. The age of the Late Triassic Xiaxiaoliu basalts (216.1 ± 2.8 Ma) is consistent with the timing of emplacement of voluminous porphyritic intrusions and the formation of Cu deposits within the SYA (peaking at 215–217 Ma). The Xiaxiaoliu basalts have E-MORB-like trace element patterns that are free of negative Nb–Ta anomalies, and have high ¹⁴³Nd/¹⁴⁴Nd_(t) values, suggesting they were sourced from asthenospheric mantle without any arc-type influence. These observations, combined with the fact that some Late Triassic mineralized porphyritic intrusions within the SYA have adakitic affinities, suggest that the basalts and other igneous rocks and associated porphyry Cu deposits within the SYA were produced by tearing of a westward-dipping slab, triggering the upwelling of asthenospheric mantle material during subduction of the Garze–Litang Ocean crust.