大气CO2浓度非均匀分布及其对地表升温影响的研究进展与展望

在气候变化和全球治理挑战日益严峻的背景下,CO₂排放及代价评估日益受到学术界和决策者的关注。当前全球范围包括联合国政府间气候变化专门委员会（IPCC）评估在内的几乎所有研究都是基于全球平均CO₂浓度来驱动气候模式的,但基于全球CO₂平均分布设定开展模拟影响评估在学术界多有争议。首先,综述了大气CO₂非均匀分布的证据,评述了大气CO₂浓度非均匀分布与地表升温过程的互馈机制。其次,从自然和人为2个维度,梳理了大气CO₂浓度非均匀分布形成的原因,并评估了其对地表升温的影响。最后,评述了当前大气CO₂浓度非均匀分布研究中存在的问题,进一步展望了其发展趋势,为把握全球与区域碳排放现状及气候变化影响提供科学判据。     

Interannual variations of the air-sea carbon dioxide exchange in the different regions of the Pacific Ocean

Interannual variations of the air-sea CO 2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model.Two numerical experiments are performed,including the control run that is forced by climatological monthly mean physical data and the climate-change run that is forced by interannually varying monthly mean physical data.Climatological monthly winds are used in both runs to calculate the coefficient of air-sea CO 2 exchange.The analysis through the differences between the two runs shows that in the tropical Pacific the variation of export production induced by interannual variations of the physical fields is negatively correlated with that of the air-sea CO 2 flux,while there is no correlation or a weak positive correlation in the subtropical North and South Pacific.It indicates that the variation of the physical fields can modulate the variation of the air-sea CO 2 flux in converse ways in the tropical Pacific by changing the direct transport and biochemical process.Under the interannually varying monthly mean forcing,the simulated EOF1 of the air-sea CO 2 flux is basically consistent with that of sea surface temperature(SST) in the tropical Pacific,but contrary in the two subtropical Pacific Ocean.The correlation coefficient between the regionally integrated air-sea CO 2 flux and area-mean SST shows that when the air-sea CO 2 flux lags SST by about 5 months,the positive coefficient in the three regions is largest,indicating that in the tropical Pacific or on the longer time scale in the three regions,physical processes control the flux-SST relationship.     

Global air-sea surface carbon-dioxide transfer velocity and flux estimated using ERS-2 data and a new parametric formula

Using data from the European remote sensing scatterometer（ERS-2） from July 1997 to August 1998,global distributions of the air-sea CO₂ transfer velocity and flux are retrieved.A new model of the air-sea CO₂ transfer velocity with surface wind speed and wave steepness is proposed.The wave steepness（5） is retrieved using a neural network（NN） model from ERS-2 scatterometer data,while the wind speed is directly derived by the ERS-2 scatterometer.The new model agrees well with the formulations based on the wind speed and the variation in the wind speed dependent relationships presented in many previous studies can be explained by this proposed relation with variation in wave steepness effect.Seasonally global maps of gas transfer velocity and llux are shown on the basis of the new model and the seasonal variations of the transfer velocity and llux during the 1 a period.The global mean gas transfer velocity is 30 cm/h after area-weighting and Schmidt number correction and its accuracy remains calculation with in situ data.The highest transfer velocity occurs around 60°N and 60°S,while the lowest on the equator.The total air to sea CO₂ llux（calculated by carbon） in that year is 1.77 Pg.The strongest source of CO₂ is in the equatorial east Pacific Ocean, while the strongest sink is in the 68°N.Full exploration of the uncertainty of this estimate awaits further data.An effectual method is provided to calculate the effect of waves on the determination of air-sea CO₂ transfer velocity and fluxes with ERS-2 scatterometer data.     

Effects of low pCO2 conditions on sea urchin larval size

Ocean acidification results from an increase in the concentrations of atmospheric carbon dioxide (CO₂) impacts on marine calcifying species, which is predicted to become more pronounced in the future. By the end of this century, atmospheric pCO₂ levels will have doubled relative to the pre‐industrial levels of 280 ppm. However, the effects of pre‐industrial pCO₂ levels on marine organisms remain largely unknown. In this study, we investigated the effects of pre‐industrial pCO₂ conditions on the size of the pluteus larvae of sea urchins, which are known to be vulnerable to ocean acidification. The larval size of Hemicentrotus pulcherrimus significantly increased when reared at pre‐industrial pCO₂ level relative to the present one, and the size of Anthocidaris crassispina larvae decreased as the pCO₂ levels increased from the pre‐industrial level to the near future ones after 3 days' exposure. In this study, it is suggested that echinoid larvae responded to pre‐industrial pCO₂ levels. Ocean acidification may be affecting some sensitive marine calcifiers even at the present pCO₂ level.     

石英原料在太阳能产业及其他高科技工业中的应用前景——以哈萨克斯坦和埃及为例

人类开发应用石英具有悠久的历史：早在石器时代,人类就曾将石英作为装饰品、工具、法器、武器、日用品等应用;在工业时代,石英主要作为玻璃原料及冶金熔剂使用;当代,石英广泛应用于许多工业和高科技领域。近年来,石英作为可再生能源及其它高科技领域用的材料,特别是以石英为原料制备多晶硅及单晶硅作为微电子学材料及太阳能利用材料方面展示了广阔的前景。但这个领域对石英纯度的要求很高,通过传统的提纯和晶体生长技术将石英转化为硅很不经济,因为传统方法大量使用氯、氯化氢及四氯化硅对环境有负面影响。而开发闭路循环技术系统或使用高纯度石英原料足解决这个问题的重要途径,前者取决于化学冶金技术水平,而后者则取决于矿产地质。因此,高纯度石英的找矿评价及工业硅的提纯是大力发展太阳能产业的重要途径。目前,以石英为原料进行高纯半导体材料和微电子材料等的合成在有些国家已经大规模工业化,并形成产业,如太阳能产业和高科技工业。据预测,在2010至2012年间,高纯石英原料将会短缺且竞争激烈。根据发达国家的实践经验,在哈萨克斯坦建立用于太阳能和其它高科技工业的高纯石英基地具有重要的理论和现实意义。哈萨克斯坦高纯石英资源丰富,在哈萨克斯坦中部,变质成因的石英脉及交代型的石英岩很普通,在东部、中部、南部和西部,石英结晶仡岗岩则很多,水晶矿床则主要集中在哈萨克斯坦的西南地区,花岗岩侵入体的水晶矿以及粒状石英脉几乎在哈萨克斯坦到处都有分布,结晶花岗岩则分布在哈萨克斯坦北部和南部地区,但是该国针对高纯石英的工业化研究与应用则很少。埃及的石英原料也很丰富,主要矿床位于该国中部和东南部地区,工业化研究与应用也很少。建议这两个国家将高纯石英原料作为太阳能产业及其它高科技产业发展的重点研究领域。     

氢氟酸溶矿硅钼蓝比色法测定磷矿中的二氧化硅

在pH=2.0~2.7左右的酸性介质中,硅酸根离子与钼酸铵生成黄色的硅钼酸络合物,然后加入抗坏血酸使其还原成稳定的硅钼蓝,借此测定硅的质量分数。     

长三角地区城市土地与能源消费CO2排放的时空耦合分析

探究城市土地与碳排放的时空耦合关系,是协调城市土地与生态环境亟待解决的重要问题。基于重心模型、总体耦合态势模型和空间耦合协调模型,使用建成区面积、能源消费和DMSP/OLS夜间灯光等数据,分析了1995—2013年长三角地区城市土地与能源消费碳排放的时空耦合特征,并考虑空间因素的影响,构建空间滞后面板Tobit模型分析其驱动因素。结果表明：① 1995—2013年,建成区面积与碳排放量总体上均呈增加趋势。建成区面积由1251 km ²,增加至4394 km ²,碳排放量由30389.49万t,增加至90405.22万t。城市土地与碳排放间呈显著的正相关;② 城市土地与碳排放空间差异明显,上海、南京、杭州、苏州和无锡的城市建成区面积相对较大,碳排放相对较高;③ 长三角地区城市土地与碳排放耦合关系总体上呈减弱-增强-波动的态势。协调关系处于不断演化过程中,低协调阶段的城市数量明显减小,高协调阶段的城市数量明显增加,且呈集聚分布特点。南京、无锡、苏州、杭州和宁波处于高协调阶段;④ 空间滞后面板Tobit模型结果表明：城镇化对城市土地与碳排放耦合协调度具有驱动和制动的双重作用。同时,人口密度、经济水平、产业结构和空间因素对其也具有重要影响。     

湿地生态系统碳通量研究进展

湿地碳循环在全球气候变化中起着重要作用,而湿地碳通量研究是湿地碳循环研究的关键问题。由于湿地独特的土壤、植被以及水文过程,使得湿地碳通量有别于其他类型的生态系统。湿地温室气体特别是CO2和CH2的释放水平具有明显的时空变化特征,其通量变化与许多外部因素相关,包括土壤状况、水文条件、植被类型、外源氮等。对近年来湿地生态系统碳汇功能变化以及影响碳通量相关因子的研究成果进行了系统的分析和综述。现有的研究表明,土壤状况对湿地碳通量影响较复杂,在一定范围内,表层土壤温度与气体排放密切相关,甚至呈正相关关系;土地利用／覆盖也影响湿地碳通量变化,导致湿地温室气体排放增加;水文条件特别是水位高度对湿地CO2和CH2排放的影响不同,高水位不利于CO2排出,CH2则与之相反;植被对湿地碳排放也起到正、负两方面作用,并且物种各异。还讨论了湿地碳通量研究进展的瓶颈问题,特别对植被演替较快的潮滩湿地碳通量研究做了展望。     

中国CO2地质埋存关联技术的现状

CO2地质埋存是减少CO2净排放量的有效措施之一。CO2地质埋存技术在发达国家已有十几年的研究历史。目前,我国这方面的研究工作刚刚起步,因此,很有必要对我国CO2地质埋存的技术现状进行调查。CO2地质埋存过程主要包括3个要素：从发电厂或者工业生产过程中回收CO2;将CO2运送到埋存场地;CO2注入与埋存。其中的很多技术在现有工业以及石油、天然气开采等行业中已经存在。对我国现有工业以及石油、天然气开采等行业中涉及到的CO2回收、运输以及注入与埋存等技术的现状进行了初步调查,并与国外进行对比。结果表明,我国CO2地质埋存技术现状与国外存在一定的差距,但还是有一定的技术基础,尤其是在CO2回收与注入方面有一定的实践经验。     

赣中变质岩带中矽线石的初步研究

赣中变质岩带在空间上具递增变质带分布特征,根据随变质作用增强而出现的新变质矿物及矿物组合划分出绢云母绿泥石带、黑云母带、铁铝石带、十字石带、矽线石带,部分地段还出现混合岩带。矽线石发育于矽线石带的含榴矽线云母片岩、含矽线斜长变粒岩中,化学成分与其寄主岩石的化学成分、成物成分有一定的关系,富含Al、K和云母的含榴矽线云母片岩,其中的矽线石中Al含量相对高,K含量很低。而富含Si、Ca、Na、K和斜长石,贫Al和云母的含矽线斜长变粒岩,其中的矽线石中Al、Na含量相对稍低,K含量稍高。