龙滩水电站坝址区平洞地垢量的估算

龙滩水电站坝址区大部分平洞均存在结垢现象，且从洞口往里，碳酸钙厚度逐渐变薄。从土壤CO2对岩溶作用的驱动、土壤与外界CO2浓度的差异对碳酸钙结垢的影响出发，结合降雨资料及左岸岩体渗透张量的特征，粗略估算了强、弱微风化带内每平方米洞壁的结垢量，估算的结果与 洞壁的 实际情况相符。     

A Compilation of Silicon and Thirty One Trace Elements Measured in the Natural River Water Reference Material SLRS-4 (NRC-CNRC)

The natural river water certified reference material SLRS-4 (NRC-CNRC, National Research Council-Conseil National de Recherches Canada) has been routinely analysed for major and trace elements by six French laboratories. Most measurements were made using inductively coupled plasma-mass spectrometry. For silicon and thirty one trace elements (rare earth elements, Ag, B, Br, Cs, Ga, Ge, Li, P, Pd, Rb, Se, Th, Ti, Tl, W, Y and Zr), no certified values are assigned by NRC-CNRC. We propose some compilation values and related uncertainties according to the results obtained by the different laboratories.     

Carbon dioxide and methane in the Arctic atmosphere

Fifty flask air samples were taken during April 1986 from a NOAA WP-3D Orion aircraft which flew missions across a broad region of the Arctic as part of the second Arctic Gas and Aerosol Sampling Program (AGASP II). The samples were subsequently analyzed for both carbon dioxide (CO₂) and methane (CH₄). The samples were taken in well-defined layers of Arctic haze, in the background troposphere where no haze was detected, and from near the surface to the lower stratosphere. Vertical profiles were specifically measured in the vicinity of Barrow, Alaska to enable comparisons with routine surface measurements made at the NOAA/GMCC observatory. Elevated levels of both methane and carbon dioxide were found in haze layers. For samples taken in the background troposphere we found negative vertical gradients (lower concentrations aloft) for both gases. For the entire data set (including samples collected in the haze layers) we found a strong positive correlation between the methane and carbon dioxide concentrations, with a linear regression slope of 17.5 ppb CH₄/ppm CO₂, a standard error of 0.6, and a correlation coefficient (r²) of 0.95. This correlation between the two gases seen in the aircraft samples was corroborated by in situ surface measurements of these gases made at the Barrow observatory during March and April 1986. We also find a similar relationship between methane and carbon dioxide measured concurrenty for a short period in the moderately polluted urban atmosphere of Boulder, Colorado. We suggest that the strong correlation between methane and carbon dioxide concentrations reflects a common source region for both, with subsequent long-range transport of the polluted air to the Arctic.     

Low-level atmospheric sulfur dioxide measurement using HPLC/fluorescence detection

An automated technique for measuring SO₂ in ambient air has been developed. Air is passed through a gas/liquid exchange coil with an aqueous absorber solution containing 10 µM formaldehyde and 0.84 mM Na₂EDTA. The SO₂ rapidly equilibrates with bisulfite (HSO ₃ ^– ) and sulfite (SO ₃ ^2– ) in the aqueous solution. The aqueous S(IV) is subsequently reacted with o-phthaladehyde in the presence of excess ethanolamine to form a fluorescent isoindole in a continuous flow stream. This derivative is then separated using reversed phase HPLC and detected via fluorescence with excitation and emission wavelengths at 330 and 380 nm, respectively. The lower limit of detection is 7 pptv (S/N=3), with a measurement period of eight minutes per sample. The instrument response is linear over several orders of magnitude.     

Grab sampling for the determination of sulfur dioxide and dimethyl sulfide in air by isotope dilution gas chromatography/mass spectrometry

Developments allowing the direct determination of sulfur dioxide and dimethyl sulfide in grab samples by gas chromatography/mass spectrometry with isotopically labeled standards (GC/MS/ILS) are reported. Isotopomers of DMS and SO₂ are used as internal standards. Spiked air samples are dried to a dew point of <–60 °C and trapped cryogenically in loops of Teflon tubing. Sealed samples are transported to the laboratory under liquid nitrogen and later subjected to GC/MS analysis. Holding times of up to one month do not result in significant sample loss. For samples collected in a clean marine environment, concentrations of SO₂ and DMS greater than 5 and 8 pptv, respectively, are significantly different from blanks at the 95% confidence level. Average measurement precision derived from a propagation of errors are 9% for SO₂ and 42% for DMS at concentrations from 5–15 pptv.Improvements are outlined which should provide sensitivity and precision comparable to that of on-site GC/MS. The technique will allow increased flexibility for the determination of trace sulfur species in the field under conditions where deployment of a mass spectrometer is not possible.     

硅同位素动力学分馏的实验研究及地质应用

由于硅在自然界中没有化学阶态变化，主要呈硅氧四面体形式存在，因此硅同位素的热力学分馏很小，由此产生的硅同位素变化不大。溶液中ＳｉＯ２沉淀过程的同位素动力学分馏是引起自然界硅同位素明显变化的主要原因。本文实验测定了溶液中ＳｉＯ２沉淀过程的硅同位素动力学分馏系数α，并结合所测定的硅同位素动力学分馏系数对现代海底黑烟囱、太古代条带状磁铁石英岩、风化成因粘土矿物的δ＾３０Ｓｉ值明显偏低；浅海碳酸盐台地中硅     

二维的大气CO2——大西洋碳循环模式

本文描述了一个二维（纬度×深度）的大西洋碳循环模式，模拟了大气和海洋间CO2的交换以及碳在海洋中的输送过程。模式在运行时使用了一个12层的三维动力学模拟的海洋环流的结果。大西洋被划分成397个网格箱，每个箱子中各种形式的碳的含量、总碱度、溶解的无机营养物和溶解氧的浓度以及几种14C(碳14)同位素的值分别得到求解。模式稳定状态的计算采用解大型稀疏线性方程组的直接解法。计算结果与“地球化学的海洋研究（GEOSECS）”的实际观测数据对比，表明模式较好地再现了实际大西洋中几种化学量的分布。     

Eruptive activity at Mount St Helens,Washington, USA, 1984–1988: a gas geochemistry perspective

The results from two different types of gas measurement, telemetered in situ monitoring of reducing gases on the dome and airborne measurements of sulfur dioxide emission rates in the plume by correlation spectrometry, suggest that the combination of these two methods is particularly effective in detecting periods of enhanced degassing that intermittently punctuate the normal background leakage of gaseous effluent from Mount St Helens to the atmosphere. Gas events were recorded before lava extrusion for each of the four dome-building episodes at Mount St Helens since mid-1984. For two of the episodes, precursory reducing gas peaks were detected, whereas during three of the episodes, COSPEC measurements recorded precursory degassing of sulfur dioxide. During one episode (October 1986), both reducing gas monitoring and SO₂ emission rate measurements simultaneously detected a large gas release several hours before lava extrusion. Had both types of gas measurements been operational during each of the dome-building episodes, it is thought that both would have recorded precursory signals for all four episodes. Evidence from the data presented herein suggests that increased degassing at Mount St Helens becomes detectable when fresh upward-moving magma is between 2 km and a few hundred meters below the base of the dome and between about 60 and 12 hours before the surface extrusion of lava.     

A Modeling Study of Climate Change and Its Implication for Agriculture in China Part II: The Implication of Climate Change for Agriculture in China

The potential CO2-induced impacts on the geographical shifts of wheat growth zones in China were studied from seven GCMs outputs. The wheat growth regions may move northward and westward under the condition of a doubling CO2 climate. The wheat cultivation features and variety types may also assume significant changes. Climatic warming would have a positive influence in Northeast China, but high temperature stress may be produced in some regions of central and southern China. Higher mean air temperatures during wheat growth, particularly during the reproductive stages, may increase the need for earlier-maturing and more heat-tolerant cultivars.     

A Modeling Study of Climatic Change and Its Implication for Agriculture in C

The trends and features of China’s climatic change in the past and future are analysed by applying station obser-vations and GCM simulation results. Nationally, the country has warmed by 0.3oC in annual mean air temperature and decreased by 5% in annual precipitation over 1951-1990. Regionally, temperature change has varied from a cooling of 0.3oC in Southwest China to a warming of 1.0oC in Northeast China. With the exception of South China, all regions of China have shown a declination in precipitation. Climatic change has the features of increasing remark-ably in winter temperature and decreasing obviously in summer precipitation. Under doubled CO2 concentration, climatic change in China will tend to be warmer and moister, with increases of 4.5oC in annual mean air temperature and 11% in annual precipitation on the national scale. Future climatic change will reduce the temporal and spatial differences of climatic factors.