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Galdemard P. Lagage P. O. Dubreuil D. Jouan R. Masse P. Pantin E. Bockelée-Morvan D. 《Earth, Moon, and Planets》1997,78(1-3):271-277
Comet C/1995 O1 (Hale-Bopp) was observed with camiras, the Saclay mid-infrared camera, mounted on the Nordic Optical Telescope
(Roque de los Muchachos, La Palma), from April 14th to April 25th, 1997. This observing run was part of the European campaign
devoted to Hale-Bopp observations from the Canary Islands (PI R. West). camiras spectro-imaging capabilities, achieved with
a Circular Variable Filter (of spectral resolution R ≈ 50), were used to obtain spectra of the comet in the N atmospheric
window (8–13 μm) over a large field of view (52″ × 78″), at a spatial resolution of ∼1 arcsec. Data were also collected at
shorter wavelengths (in the L and M bands). The silicate dust feature around 10 μm is clearly apparent in the data. The shape
of the feature varies continuously according to the position in the field. A dust model developed at Saclay in the framework
of β-Pictoris dust disk studies was used to interpret the observations. The presence of both olivine and pyroxene with a high
degree of crystallinity is needed to account for the observations. A change in the size distribution of the grains allows
to reproduce the spatial change of the silicate feature according to the position in the field.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
33.
Studies of modern cyanobacterial mats and biofilms show that they can precipitate minerals as a consequence of metabolic and degradational activities paired with ambient hydrochemical conditions. This study looked at modern microbial mats forming giant, tower‐like, groundwater‐fed, calcareous microbialites in the world's largest, highly alkaline lake; Van Gölü (Lake Van), East Turkey. Results show that microbial systems play a role not only in carbonate precipitation but also in the formation of siliceous mineral phases. Transmitted light microscopy, scanning electron microscopy and spectral observations revealed that, within the extracellular polymeric substances excreted by the mats abundant minute aragonite grains precipitated first in vivo. These minute grains were quickly succeeded and/or supplemented in the dead biomass of the cyanobacterial mat by authigenic Al–Mg–Fe siliceous phases. Silicon dioxide is available in large concentrations in the highly alkaline water of Lake Van. Divalent cations (Ca and Mg) are delivered to the microbialites mostly by groundwater springs. The precipitation of the fine‐grained siliceous phases is probably mediated by bacteria degrading the cyanobacterial biomass and complexing the excessive cations with their extracellular polymeric envelopes. The bacteria serve as nucleation centres for the subsequent precipitation of siliceous mineral phases. Generally, the biphasic (calcareous and siliceous) mineralization – characterizing Lake Van microbialites – is controlled by their interior highly dynamic hydrogeochemical situation. There, the dramatically different alkaline lake water and the Ca–Mg‐charged groundwater mix at various rates. The early diagenetic replacement of the in vivo aragonite by authigenic siliceous phases significantly increases the fossilization potential of the mat‐forming cyanobacteria. Lake Van and its giant microbialite tufa towers act as a model explaining the transformation of early diagenetic mineral phases observed in many modern and ancient carbonate marine deposits, particularly those influenced by diffusion of silica‐enriched and metal‐enriched pore waters from below the water–sediment interface. 相似文献
34.
Investigating the immobilization of CO2, previous basalt-water-CO2 interaction studies revealed the formation of carbonates over a short period, but with the extensive formation of secondary silicates (SS). The mechanisms involved in these processes remain unresolved, so the present study was undertaken to understand secondary mineral formation mechanisms. XRPD and Rietveld refinement data for neo-formed minerals show a drastic decrease in the Ca-O bond length, with the calcite structure degenerating after 80 h (hours). However, SEM images and EDS data revealed that a longer interaction time resulted in the formation of chlorite and smectite, adjacent to basalt grains which prevent basalt-water-CO2 interaction to form carbonates, thus restricting carbonate formation. As a result of this, the CO2 mineralization rate is initially high (till 80 h), but it later reduces drastically. It is evident that, for such temperature-controlled transformations, low temperature is conducive to minimizing SS surface coating at the time of mineral carbonation. 相似文献
35.
应用五氟化溴法(BrF5)测定硅酸盐及氧化物矿物的氧同位素组成,试剂纯化、样品预处理、环境湿度、反应器洁净程度以及实验质量控制是影响该法准确度的主要因素。为确定BrF5法最佳实验条件,提高分析精度,本文以国家标准物质为参考,对硅酸盐及氧化物矿物在不同焙烧温度下的氧同位素组成进行分析,并对实验环境湿度和反应器洁净程度对分析数据质量的影响进行了系统研究。实验确定了焙烧温度设置为650~750℃,可去除硅酸盐全岩样品中的炭质成分,避免了温度因素引起的同位素分馏;将实验环境相对湿度降低至50%RH,并在0. 5min内完成样品装填,可解决由于水汽造成δ18O值明显偏低的突出问题;对于新使用的反应器,或反应器在使用中有黄色物质脱落、内壁受到污染,及时进行氟化处理和清洗,可避免因氧气产率降低所引起的氧同位素分馏;反应器交替进行样品和标准物质CO2试样的制备,可对样品同位素数据的可靠性进行监测。对国家标准GBW04409的氧同位素组成进行测试,δ18O测试结果与推荐值一致,分析精度优于0. 1‰。以上途径有效控制了氧同位素分馏,提高了BrF5氧同位素分析方法的适用性。 相似文献
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In order to gain insight into the correlations between 29Si, 17O and 1H NMR properties (chemical shift and quadrupolar coupling parameters) and local structures in silicates, ab initio self-consistent
field Hartree-Fock molecular orbital calculations have been carried out on silicate clusters of various polymerizations and
intertetrahedral (Si-O-Si) angles. These include Si(OH)4 monomers (isolated as well as interacting), Si2O(OH)6 dimers (C2 symmetry) with the Si-O-Si angle fixed at 5° intervals from 120° to 180°, Si3O2(OH)8 linear trimers (C2 symmetry) with varying Si-O-Si angles, Si3O3(OH)6 three-membered rings (D3 and C1 symmetries), Si4O4(OH)8 four-membered ring (C4 symmetry) and Si8O12(OH)8 octamer (D4 symmetry). The calculated 29Si, 17O and 1H isotropic chemical shifts (δi
Si, δi
O and δi
H) for these clusters are all close to experimental NMR data for similar local structures in crystalline silicates. The calculated
17O quadrupolar coupling constants (QCC) of the bridging oxygens (Si-O-Si) are also in good agreement with experimental data. The calculated 17O QCC of silanols (Si-O-H) are much larger than those of the bridging oxygens, but unfortunately there are no experimental data
for similar groups in well-characterized crystalline phases for comparison. There is a good correlation between δi
Si and the mean Si-O-Si angle for both Q
1 and Q
2, where Q
n
denotes Si with n other tetrahedral Si next-nearest neighbors. Both the δ
i
O and the 17O electric field gradient asymmetry parameter, η of the bridging oxygens have been found to depend strongly on the O site
symmetry, in addition to the Si-O-Si angle. On the other hand, the 17O QCC seems to be influenced little by structural parameters other than the Si-O-Si angle, and is thus expected to be the most
reliable 17O NMR parameter that can be used to decipher Si-O-Si angle distribution information. Both the 17O QCC and the 2H QCC of silanols decrease with decreasing length of hydrogen bond to a second O atom (Si-O-H···O), and the δ
i
H increase with the same parameter.
Received: 18 July 1997 / Revised, accepted: 23 February 1998 相似文献
39.
Sŀawomir Maj 《Pure and Applied Geophysics》1978,116(6):1225-1230
Summary The relationship between the phonon conductivity at room temperature (K
N
) and the seismic parameter () for silicate minerals is suggested. The considerations are based on the Debye model of thermal energy transport phenomena in solids and on the seismic equation of state for silicates and oxides given byAnderson (1967). The semiempirical relationship is the formK
N
= 0.430.82 where is in km2/s2 andK
N
in mcal/cm s K, and the empirical relationship isK
N
=(0.528±0.006) –(8.18±2.11). The laboratory data on thermal and elastic properties for several silicates were taken fromHorai andSimmons (1970). 相似文献
40.
Trace-element distributions in silicates during prograde metamorphic reactions: implications for monazite formation 总被引:1,自引:0,他引:1
To assess the petrogenetic relationship between monazite and major silicates during prograde metamorphism, REE were measured across coexisting zoned silicates in garnet through kyanite‐grade pelitic schists from the Great Smoky Mountains, western Blue Ridge terrane, southern Appalachians, to establish REE concentrations and distributions before and after the monazite‐in isograd, and to identify the role major silicates play in the formation of monazite. Results indicate significant scavenging of light rare‐earth elements (LREE) from silicates during the monazite‐in isograd reaction; however, the absolute concentration of LREE hosted in the silicates was insufficient to produce monazite in the quantity observed in these schists. Monazite must have formed mainly from either the dissolution of allanite or some other source of concentrated LREE (possibly adsorbed onto grain boundaries), even though direct evidence for allanite is lacking in a majority of the samples. Laser‐ablation ICP‐MS analyses and theoretical thermodynamic calculations show that monazite may have formed as a result of contributions from both allanite and major silicates. Allanite breakdown initially formed monazite, and monazite production drew LREE liberated from allanite, major silicates and possibly from crystal boundaries. In many rocks the reaction was further promoted by the staurolite‐in reaction, allowing for rapid, isogradic monazite growth. 相似文献