Rare earth element characteristics of the carboniferous Huanglong Formation dolomites in eastern Sichuan Basin,southwest China: Implications for origins of dolomitizing and diagenetic fluids

Marine dolostones of Carboniferous Huanglong Formation constitute major gas reservoir rocks in eastern Sichuan Basin. However, the investigation with respect to sources of dolomitizing and diagenetic fluids is relatively underexplored. The current study attempts to investigate the REE characteristics of dolomites using seawater normalization standard, and therefore discusses the origins of dolomitizing and diagenetic fluids, on the basis of continuous 47.33-m-long core samples from the second member of Huanglong Formation (C₂h₂) in eastern Sichuan Basin. Low Th, Sc, and Hf concentrations (0.791 × 10⁻⁶, 4.751 × 10⁻⁶, and 0.214 × 10⁻⁶, respectively), random correlation between total REE concentration (ΣREE) and Fe or Mn abundance, and seawater-like Y/Ho ratios (mean value of 45.612) indicate that the carbonate samples are valid for REE analysis. Based on petrographic characteristics, four dolomite types are identified, including micritic-sized dolomite (type Dol-1), fine-to medium-sized dolomite (type Dol-2), medium-to coarse-sized dolomite (type Dol-3), and coarse-to giant-sized saddle dolomite (type Dol-4). Dol-1 dolomites, characterized by positive Ce anomaly (mean value of 6.398), light REE (LREE) enrichment, and heavy REE (HREE) depletion with mean LREE/HREE ratio of 12.657, show micritic calcite-like REE patterns, indicating seawater origin of their dolomitizing fluids. Dol-1 dolomites were formed in sabkha environment whereas the dolomitizing fluids originated from evaporative brine water due to their micritic crystal sizes and tight lithology. Dol-2 dolomites, particularly subtype Dol-2a barely developing vuggy porosity, also show micritic calcite-like REE patterns, suggesting their dolomitizing fluids were seawater or seawater-derived fluids. This inference is confirmed by low Fe and Mn concentrations, which range from 651 μg/g to 1018 μg/g (mean value of 863 μg/g) and 65 μg/g to 167 μg/g (mean value of 105 μg/g), respectively, whereas homogenization temperatures (T_h, mean value of 103 °C) indicate that Dol-2 dolomites were formed under burial environment. Dol-3 dolomites, in form of cements of Dol-2 dolomites, show similar REE patterns to their host minerals (i.e., Dol-2 dolomites), indicating their parent source was possibly derived from Dol-2 dolomites. Dol-3 dolomites have high Fe and Mn concentrations with mean values of 3346 μg/g (ranging from 2897 μg/g to 3856 μg/g) and 236 μg/g (ranging from 178 μg/g to 287 μg/g), respectively, indicating the involvement of meteoric water. Meanwhile, it confirms that the dissolution in Dol-2 dolomites was caused by meteoric water leaching. Positive Eu anomalies (mean value of 1.406) in Dol-4 dolomites, coupled with high homogenization temperatures (mean value of 314 °C), suggest that Dol-4 dolomites precipitated from hydrothermal fluids. High Fe and Mn concentrations (mean values of 2521 μg/g and 193 μg/g, respectively) in Dol-4 dolomites likely results from interactions of hydrothermal fluids with deep burial clastic rocks.     

Robust leader-follower formation tracking control of multiple underactuated surface vessels

This paper is concerned with the formation control problem of multiple underactuated surface vessels moving in a leader-follower formation.The formation is achieved by the follower to track a virtual target defined relative to the leader.A robust adaptive target tracking law is proposed by using neural network and backstepping techniques.The advantage of the proposed control scheme is that the uncertain nonlinear dynamics caused by Coriolis/centripetal forces,nonlinear damping,unmodeled hydrodynamics and disturbances from the environment can be compensated by on line learning.Based on Lyapunov analysis,the proposed controller guarantees the tracking errors converge to a small neighborhood of the origin.Simulation results demonstrate the effectiveness of the control strategy.     

Sunrise Hill unconformity: A newly discovered regional hiatus between Archaean granites and greenstones in the northeastern Pilbara Craton

Contacts between Archaean granites and greenstones in the northeastern part of the Pilbara Craton have been described as intrusive and tectonic. New field observations in the Shay Gap region demonstrate that greenstones of the Gorge Creek Group unconformably overlie the Muccan and Warrawagine batholiths. Regionally, the unconformity is marked by a persistent but relatively thin basal clastic sequence, locally with a granite boulder conglomerate, overlain by ore‐bearing banded iron‐formation, fine‐grained clastic rocks and chert. The granite basement is dated at 3443 ± 6 Ma. The precise age of the hiatus is unknown but its maximum effect might have been the removal of a substantial thickness of Early to Middle Archaean strata.     

Lattice dynamical system modelling of molecular clouds

Because a comprehensive microscopic treatment of interstellar molecular clouds is out of reach, an alternative approach is proposed in which most of the crucial ingredients of the problem are considered, but at some 'minimal' level of modelling. This leads to the elaboration of a lattice dynamical system , i.e. a time-dependent, spatially extended, deterministic system of macroscopic cells coupled through radiative transfer. Each cell is characterized by a small set of variables and supports a caricatural chemistry possessing the essential dynamical features of more realistic reaction schemes.   This approach naturally precludes quantitative results, but allows heretofore unavailable insights into some of the basic mechanisms at play. We focus on the response of the transfer process and the chemistry to a frozen 'turbulent' velocity field. It is shown that the system settles generically into a state where the effective coupling between cells is neither local nor global, and for which no single length-scale exists.   The spectral lines reconstructed from the spatiotemporal evolution of our model may, depending on the velocity field, exhibit profiles ranging from Gaussian to bimodal with strong realization effects. In the bimodal case, the model intrinsically displays an energy cascade transport mechanism to the cells that cool most efficiently: the feedback of chemistry on radiative transfer cannot be neglected.   Finally, extensions of this work are discussed and future developments are outlined.     

Studies of ultracompact H ii regions — II. High-resolution radio continuum and methanol maser survey

High spatial resolution radio continuum and 6.67-GHz methanol spectral line data are presented for methanol masers previously detected by Walsh et al. (1997). Methanol maser and/or radio continuum emission is found in 364 cases towards IRAS -selected regions. For those sources with methanol maser emission, relative positions have been obtained to an accuracy of typically 0.05 arcsec, with absolute positions accurate to around 1 arcsec. Maps of selected sources are provided. The intensity of the maser emission does not seem to depend on the presence of a continuum source. The coincidence of water and methanol maser positions in some regions suggests there is overlap in the requirements for methanol and water maser emission to be observable. However, there is a striking difference between the general proximity of methanol and water masers to both cometary and irregularly shaped ultracompact (UC) H  ii regions, indicating that, in other cases, there must be differing environments conducive to stimulating their emission. We show that the methanol maser is most likely present before an observable UC H  ii region is formed around a massive star and is quickly destroyed as the UC H  ii region evolves. There are 36 out of 97 maser sites that are linearly extended. The hypothesis that the maser emission is found in a circumstellar disc is not inconsistent with these 36 maser sites, but is unlikely. It cannot, however, account for all other maser sites. An alternative model which uses shocks to create the masing spots can more readily reproduce the maser spot distributions.     

甘肃花草滩煤矿区沉积相演化与内部构造的地质意义探讨

花草滩煤矿区地处北祁连褶皱带中段北侧,酒东盆地东端。古生界和中生界地层在区内发育较完整,其中石炭系太原组为含煤地层。经二、三维地震勘探、钻探等工作证实矿床总体上受单斜构造控制。石炭纪中期盆地呈逐渐上升趋势,沉积相演化经历了由海相逐渐过渡到海陆交汇相,再到陆相沉积的阶段。F5和F8断层具顺层断裂特征,破坏煤层的连续性,在一定程度上控制了瓦斯突出区的分带,可作为煤矿瓦斯含量高低的分界标志。     

陕西凤县八方山-二里河（铜）铅锌矿床地质特征及成矿模式

在综合分析凤-太矿集区成矿构造特征的基础上，依据以往总结的凤．太矿田铅锌、金矿聚矿构造模式，通过对八方山-二里河铅锌矿床地质特征的分析，总结了找矿标志，初步认为八方山-二里河（铜）铅锌矿床的成矿模式为：“前泥盆纪海底热水喷流沉积一印支-燕山期构造改造型”铅锌矿床。认为成矿物质来源于基底，后期的构造-岩浆改造使基底成矿元素活化，沿同生断裂迁移、改造，最后在泥盆系中形成的扩容性构造部位富集成矿。提出了下一步扩大找矿的方向和建议。     

Galaxy formation and evolution – I. The Padua tree-sph code (pd-sph)

In this paper we report on pd-sph , the new tree-sph code developed in Padua. The main features of the code are described and the results of a new and independent series of 1D and 3D tests are shown. The paper is mainly dedicated to the presentation of the code and to the critical discussion of its performance. In particular, great attention is devoted to the convergency analysis. The code is highly adaptive in space and time by means of individual smoothing lengths and individual time-steps. At present it contains both dark and baryonic matter, this latter in the form of gas and stars, cooling, thermal conduction, star formation, feedback from Type I and II supernovae, stellar winds, and ultraviolet flux from massive stars, and finally chemical enrichment. New cooling rates that depend on the metal abundance of the interstellar medium are employed, and the differences with respect to the standard ones are outlined. Finally, we show the simulation of the dynamical and chemical evolution of a disc-like galaxy with and without feedback. The code is suitably designed to study in a global fashion the problem of formation and evolution of elliptical galaxies, and in particular to feed a spectrophotometric code from which the integrated spectra, magnitudes and colours (together with their spatial gradients) can be derived.