幔源CO_2释出机理、脱气模式及成藏机制研究进展

针对幔源CO2如何从地幔岩浆中脱出并进入沉积地层中形成CO2气藏聚集这一关键问题,总结了国内外研究进展和前缘方向。研究表明,地幔深部的碱性玄武岩浆和碱性岩浆才是深部流体和CO2等挥发份大量赋存、渗滤和释出的场所。浅成侵入岩、次火山岩和火山通道等是CO2释放和聚集的有利位置,岩浆期后和岩浆衰弱期的热液活动阶段是CO2大量释放和聚集的有利时期。幔源CO2进入沉积盆地中具有3种脱气模式,即沿岩石圈断裂直接脱气模式、热流底辟体脱气模式和壳内岩浆房-基底断裂组合脱气模式。CO2的固有物化性质决定其运移相态多样,具有运移和聚集过程同步的特征。只有在满足大量的化学消耗及地层水或原油的溶解和耗散之后才能形成CO2有效聚集。幔源CO2成藏和分布主要受岩浆气源体和气源断裂体系的控制。今后,在超临界CO2及其对油气运移聚集的作用、CO2与深大断裂及火山岩的关系、CO2脱气运移机制、CO与常规烃类油气的耦合差异成藏机制等方面仍需要进一步的研究和探索。     

山西天池煤矿构造特征及其形成机制

基于天池煤矿地质勘探资料,结合区域构造背景研究了矿井地质构造特征及形成机制。天池煤矿构造属简单构造,地层总体呈走向北东、倾向北西的单斜构造,矿井内褶皱发育程度较低,断层以正断层为主,其次为低角度逆掩断层。陷落柱分布较为杂乱,成群出现,常见于褶皱轴部。自三叠纪末期开始一直受到区域构造活动的控制作用,印支期受SN向的挤压,形成了一些近EW向的构造;燕山期经历两期NWW--SEE向挤压使井田内地层及煤层主体呈NE走向;喜山早期的NE—SW向挤压,导致NE向断层的性质发生转变;上新世开始表现为区域上的伸展作用。     

(ϖμ/ϖT) P of the lower mantle

We estimate (/T) _P of the lower mantle at seismic frequencies using two distinct approaches by combining ambient laboratory measurements on lower mantle minerals with seismic data. In the first approach, an upper bound is estimated for |(/T) _P | by comparing the shear modulus () profile of PREM with laboratory room-temperature data of extrapolated to high pressures. The second approach employs a seismic tomography constraint ( lnV _S / lnV _P ) _P =1.8–2, which directly relates (/T) _P with (K _S /T) _P . An average (K _S /T) _P can be obtained by comparing the well-established room-temperature compression data for lower mantle minerals with theK _S profile of PREM along several possible adiabats. Both (K _S /T) and (/T) depend on silicon content [or (Mg+Fe)/Sil of the model. For various compositions, the two approaches predict rather distinct (/T) _P vs. (K _S /T) _P curves, which intersect at a composition similar to pyrolite with (/T) _P =–0.02 to –0.035 and (K _S /T) _P =–0.015 to –0.020 GPa/K. The pure perovskite model, on the other hand, yields grossly inconsistent results using the two approaches. We conclude that both vertical and lateral variations in seismic velocities are consistent with variation due to pressure, temperature, and phase transformations of a uniform composition. Additional physical properties of a pyrolite lower mantle are further predicted. Lateral temperature variations are predicted to be about 100–250 K, and the ratio of ( lnp/ lnV _S ) _P around 0.13 and 0.26. All of these parameters increase slightly with depth if the ratio of ( lnV _S / lnV _P ) _P remains constant throughout the lower mantle. These predicted values are in excellent agreement with geodynamic analyses, in which the ratios ( ln / lnV _S ) _P and ( / lnV _S ) _P are free parameters arbitrarily adjusted to fit the tomography and geoid data.     

Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.     

暖切变型江淮梅雨锋结构及其形成和维持机制

对在1991年7月上旬特别稳定的梅雨形势下持续10天的特大暴雨期作了合成和典型过程研究,并进一步探讨了暖切变型江淮梅雨锋天气系统模型。它在自由大气层表现为结构竖立的相当正压切变线和一种不同于经典地转动量近似的带状准二维运动场。边界层的浅层锋生倾斜环流以及偏于切变线轴以南的Ekman抽吸与自由大气层中基本上由积云对流加热驱动的竖直环流相互依存和耦合,造成持续的大暴雨。这种系统的初生和中断后复苏的机制可能是由斜压性极弱的副热带高空东移的短波扰动在低层“湿度锋”带紧南侧触发导致的一种带状CISK。     

The emplacement of intermediate volume ignimbrites: A case study from Roccamonfina Volcano,Southern Italy

A model is presented for the emplacement of intermediate volume ignimbrites based on a study of two 6 km³ volume ignimbrites on Roccamonfina Volcano, Italy. The model considers that the flows were slow moving, and quickly deflated from turbulent to non-turbulent conditions. Yield strength and density increased whereas fluidisation decreased with time and runout of the pyroclastic flows. In proximal locations, on the caldera rim, heterogeneous exposures including discontinuous lithic breccias, stratified and cross-stratified units interbedded with massive ignimbrite suggest deposition from turbulent flows. In medial locations thick, massive ignimbrite occurs associated with three types of co-ignimbrite lithic breccia which we interpret as being emplaced by non-turbulent flows. Multiple grading of different breccia/lithic concentration types within single flow units indicates that internal shear occurred producing overriding or overlapping of the rear of the flow onto the slower-moving front part. This overriding of different parts of non-turbulent pyroclastic flows could be caused by at least two different mechanisms: (1) changes in flow regime, such as hydraulic jumps that may occur at breaks in slope; and (2) periods of increased discharge rate, possibly associated with caldera collapse, producing fresh pulses of lithic-rich material that sheared onto the slower-moving part of the flow in front.We propose that ground surge deposits enriched in pumice compared with their associated ignimbrite probably formed by a flow separation mechanism from the top and front of the pyroclastic flow. These turbulent clouds moved ahead of the non-turbulent lower part of the flow to form stratified pumice-rich deposits. In distal regions well-developed coarse, often clast-supported, pumice concentrations zones and coarse intra-flow-unit lithic concentrations occur within the massive ignimbrite. We suggest that the flows were non-turbulent, possessed a relatively high yield strength and may have moved by plug flow prior to emplacement.     

Effects of ageing and overconsolidation on the elastic stiffness of a remoulded clay

Summary Results of resonant column tests were used to determine values of low amplitude shear modulus (G ₀) of a remoulded kaolinite clay for different durations of ageing and for different values of consolidation stress (₀) and overconsolidation ratio (OCR). It was found that after completion of primary consolidation the values of G ₀ increased linearly with the logarithm of time and after a week of confinement the value of normalized rate of secondary increase of shear modulus (N _G ) could be reliably estimated. Values of N _G were found to derease linearly with the logarithm of OCR and with the logarithm of ageing duration. This similarity of behaviour provided a basis for establishing an equivalency between age and equivalent overconsolidation ratio (OCR)_eq. The effects of ₀ and OCR on the value of G ₀ were also established in a functional form that indicated a stronger influence compared to that predicted by the Hardin Equation.     

基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制

目的：基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制。方法：应用TCMSP和UniProt数据库平台查询青蛇方组方的有效活性成分及靶基因,与疾病靶基因取交集后构建蛋白质-蛋白质相互作用(PPI)网络;应用DAVID数据库,对潜在核心作用靶点基因进行基因本体（GO）功能、京都基因与基因组百科全书（KEGG）通路富集分析。利用分子对接原理论证青蛇方生物活性成分与核心靶点的分子结合能力。结果：筛选出青蛇方有效成分63种,作用靶点99个;主要有β-谷甾醇、2,4,7-三羟基-9,10-二氢菲、靛蓝素、豆甾醇、色氨酸等关键成分;转录因子AP-1（JUN）、肿瘤坏死因子（TNF）、原癌基因（RELA）、干扰素γ（IFNG）、转化生长因子-β1（TGF-β1）等核心基因。关键信号通路有癌症信号通路、恰加斯病通路、弓形体病通路、脂质和动脉粥样硬化通路等,分子对接结果显示活性成分与核心靶点基因结合能力较强。结论：青蛇方外用可以通过多种活性成分、多种通路有效抑制免疫炎症反应,促进免疫系统正常运行,从而达到治疗湿疹的目的。     

北京云蒙山地区花岗岩穹隆及伸展构造的探讨

北京云蒙山花岗岩为一中生代侵入的花岗岩穹隆,花岗岩穹隆的叶理普遍发育,叶理轨迹基本平行于穹隆的外部边界,并显示出从核部到边部逐渐增强,东南侧明显强于西北侧的特点。变形构造研究显示,花岗岩穹隆的边部及围岩中普遍存在不同层次及不同运动方向的伸展构造。东南侧以具河防口－水峪伸展型韧性剪切带为特征,剪切运动标志显示为从ＮＷ－ＳＥ的正剪切运动,有限应变分析估算其剪切位移量在１０ｋｍ以上,剪切带上部被河防口正