地层中的硅岩: 研究进展及展望*

硅岩是由自生石英形成的化学沉积岩,通常以层状或非层状(结核状、条带状)独自出现、与其他岩性互层出现及赋存于其他岩性地层中。硅岩不仅记录了大量盆地古地理、古海洋、古气候的地质信息,而且对于岩石大地构造学研究具有重要意义。前人对硅岩的研究取得了丰富的成果,近年来关于硅岩的新观点为硅岩的研究提供了新的思考途径和研究线索。通过调研近年来关于硅岩的岩石学特征、地球化学特征及沉积环境的研究,分析总结了不同地质历史时期、不同沉积环境、不同产状硅岩的形成模式、成因类型以及判别方式,认为硅岩的沉积不是单一因素控制的结果,而是地质构造活动强度、生物类型及活动性、沉积古环境的综合结果。常规地球化学元素结合岩石组构与微区分析、包裹体分析、新同位素(Rb-Sr和Sm-Nd)分析,以及新的地球化学判定标准(Ge/Si)是硅岩研究的必备手段和方法。     

碳酸盐岩早期差异成储路径及其对储集性能的影响:以滨里海盆地N油田石炭系KT-Ⅰ与KT-Ⅱ层系为例*

以滨里海盆地N油田石炭系KT-Ⅰ与KT-Ⅱ层系碳酸盐岩储集层为例,综合岩心、薄片、扫描电镜、高压压汞、常规物性分析以及各类测试资料,对碳酸盐岩储集层特征以及早期成储路径展开系统研究,并进一步探讨成储路径与储集层孔喉结构和质量的关系。结果表明,KT-Ⅰ层系以云岩类储集层为主,颗粒灰岩次之,其中云岩类储集层以晶间(溶)孔、小型溶洞为主,孔喉连通性好,为高孔—高渗的孔洞型储集层, 而颗粒灰岩类储集层以粒内溶孔、铸模孔及生物体腔孔发育为特征,孔喉连通性差,属中孔—低渗的孔隙型储集层。KT-Ⅱ层系以粒间(溶)孔和生物体腔孔发育的颗粒灰岩为特征,为中高孔—高渗的孔隙型储集层。进一步分析表明,KT-Ⅰ层系云岩与灰岩储集层单旋回厚度小,皆受高频海平面升降变化驱动的早成岩期岩溶的控制, 而KT-Ⅱ层系单旋回厚度大,颗粒滩未经历早期岩溶的改造。 3类储集层的成储路径分别为: (1)KT-Ⅰ云岩类储集层,准同生期白云石化作用导致矿物相转变并使得部分矿物更易遭受溶蚀→早成岩期岩溶作用控制储集层的形成→云岩抗压溶岩石骨架有利于储集层的保护; (2)KT-Ⅰ颗粒灰岩储集层,早成岩期岩溶作用优化储集层→初期压实控制胶结流体通道进而控制胶结作用—粒间孔与粒内孔差异胶结控制储集层的保护; (3)KT-Ⅱ颗粒灰岩储集层,原始沉积环境控制储集层的形成→初期压实与早期胶结作用控制储集层的保护。成储路径差异控制了不同的孔渗特征与孔喉结构,而孔喉结构进一步控制了早期岩溶型云岩、早期岩溶型颗粒灰岩、原生孔保存型颗粒灰岩3种储集层的质量。研究结果将为具类似特征的碳酸盐岩储集层成因分析提供参考,也因发现了云岩较灰岩更易早期溶蚀的现象而具有较为重要的岩溶地质学意义。     

Geochronology and geochemistry of lithium-rich tuffs in the Sichuan basin,western Yangtze: Implication for the magmatic origin and final closure of eastern Paleo-Tethys

The felsic volcanogenic tuffs named “green-bean rocks” (GBRs), characterized by a green or yellowish green color, are widely distributed in the western Yangtze platform and have a high lithium content (286–957 ppm). This paper studies the ages, origin and tectonic setting of the GBRs in the Sichuan basin on the western margin of the Yangtze platform through the whole-rock geochemistry and zircon trace elements by using U–Pb dating and Hf–O isotopes. The GBR samples from the Quxian and Beibei sections yielded zircon U–Pb ages of 245.5 ± 1.8 Ma and 244.8 ± 2.2 Ma. These samples can be used as the isochronous stratigraphic marker of the Early–Middle Triassic boundary (EMTB) for regional correlation. The whole-rock and zircon geochemistry, and zircon Hf–O isotopes exhibited S-type geochemical affinities with high positive δ¹⁸O values (9.28‰–11.98‰), low negative ε_Hf(t) values (?13.87 to ? 6.79), and T_DM² ages of 2150–1703 Ma, indicating that the lithium-rich GBRs were generated by the remelting of the pre-existing ancient Paleoproterozoic layer without mantle source contamination in the arc-related/orogenic tectonic setting. The results of this study demonstrate that the lithium-rich GBRs in the western Yangtze platform were derived from arc volcanic eruptions along the Sanjiang orogen, triggered by the closure of the eastern Paleo-Tethys Ocean and the syn-collision between the continental Indochina and Yangtze blocks at ca. 247 Ma. This was marked by a major shift from I-type magmas with intermediate ε_Hf(t) values to S-type magmas with low negative ε_Hf(t) values. Collectively, our results provide new insights into the origin of the GBRs and decodes the closure of the eastern Paleo-Tethys.     

Mineralization of the Liwu large-scale stratiform copper deposits in Sichuan Province,China: Constraints from fluid inclusions

The Liwu stratiform copper deposit is located in the northwestern Jianglang dome, western China. Current studies mainly focus on the genetic type and mineralization of this deposit. Detailed fluid inclusion characteristics of metallogenic period quartz veins were studied to reveal the ore-forming fluid features. Laser Raman analysis indicates that the ore-forming fluids is a H₂O-NaCl-CH₄ (-CO₂) system. Fluid inclusions microthermometry shows a homogenization temperature of 181–375°C and a salinity of 5.26%–16.99% for the disseminated-banded Cu-Zn mineralization; but a homogenization temperature of 142–343°C and a salinity of 5.41%–21.19% for the massive-veined Cu-Zn mineralization. These features suggest a medium-high temperature and a medium salinity for the ore-forming fluids. H-O isotopic data indicates that the ore-forming fluids were mainly from the metamorphic and magmatic water, plus minor formation water. And sulfur isotopic data indicates that sulfur was mainly derived from the formation and magmatic rocks. Metallogenesis of the disseminated-banded mineralization was mainly correlated with fluid mixing and water-rock reaction; whereas that of the massive-veined mineralization was mainly correlated with fluid boiling. The genetic type of the deposit is a medium-high temperature hydrothermal deposit related to magmatism and controlled by shear zones. This study is beneficial to understand the stratiform copper deposit.©2023 China Geology Editorial Office.     

黔西北大方地区龙潭组海陆过渡相烃源岩特征及评价

黔西北大方地区龙潭组以泥页岩、煤层与砂岩交替互层发育为特点,具有典型的海陆过渡相特征。文章在剖面实测和样品采集的基础上,结合全岩和黏土矿物XRD分析、总有机碳(TOC)含量测定、岩石热解、干酪根显微组分及镜质体反射率(R_O)等分析,对研究区龙潭组烃源岩发育特征进行了研究和评价。结果表明: ① 龙潭组矿物以黏土矿物为主,具有较强的吸附能力,但黏土矿物含量与石英含量呈明显的负相关关系(R>0.8),尤其是泥页岩中70%以上的黏土含量以及较低的脆性指数增加了压裂开发的难度。 ② 龙潭组有机质丰度受岩性变化控制明显。煤层具有最高的TOC含量(平均值42.9%)和生烃潜量(平均值为2.68 mg/g),显示强大的煤层气生烃潜力;泥页岩生烃潜量均小于2 mg/g,但约有80%样品的TOC含量超过2%,页岩气资源潜力不及煤层气;粉砂岩生烃潜力最差,生烃潜量平均值为0.13 mg/g,TOC含量为1.4%~5.6%,显示一定的致密气潜力。 ③ 龙潭组有机显微组以壳质组和镜质组占主导,干酪根以Ⅲ型为主,Ⅱ₂型为辅,热演化程度高,处于高-过成熟的生干气阶段。 ④ 煤层更为发育的龙潭组中段是大方地区煤层气、页岩气和致密砂岩气联合勘探的有利层段。     

持续开挖效应下结构面剪切力学性质与能量特征研究

基于地下岩体工程开挖扰动的实际情况,开展考虑持续开挖效应,充分反映岩体结构面应力调整过程的结构面剪切试验更具理论意义和工程应用价值。采用人工劈裂方法制备岩体结构面,开展了常规应力路径和持续开挖效应下的结构面剪切试验,系统研究了两种条件下结构面剪切力学性质、声发射特征和能量的演化规律。研究结果表明：开挖扰动荷载强度越大,结构面发生剪切破坏时的剪应力降整体上越大,但持续开挖效应下的剪应力降最大值仅为常规应力路径下剪应力降的48.57%;考虑持续开挖效应的结构面剪切过程中声发射活动主要集中于结构面受剪破坏和剪应力降产生时,且声发射活动强度与开挖扰动强度正相关,声发射振铃计数变化率极值明显小于常规应力路径下的相应值;持续开挖效应下试样裂纹发育密集度、结构面磨损区域及破坏程度均随开挖扰动强度增加而增加,但试样裂纹发育的密集程度和结构面破坏程度相对常规应力路径下的情况轻;考虑持续开挖效应的结构面发生剪切破坏时弹性应变能随扰动荷载增大而增大,均低于常规应力路径条件下的弹性应变能值,持续开挖效应降低了结构面剪切破坏的强度,但更易引发结构面发生剪切破坏。     

基于裂隙扩展的多级岩质边坡开挖卸荷破坏路径分析

开挖卸荷作用下裂隙岩体边坡的破坏模式与路径分析是边坡工程灾害研究的热点之一,准确识别边坡的潜在破裂路径对工程安全施工和支护优化设计具有重要意义。依据断裂扩展分析方法,将裂隙扩展判别的理论方法开发并应用于数值模拟分析中,通过裂隙尖端应力强度因子计算、裂隙扩展模式识别、裂隙起裂角演算、裂隙扩展交汇等技术实现了岩体中断续裂隙的起裂、扩展与贯通演化过程的快速模拟;以某高速公路沿线裂隙岩体路堑边坡为对象,采用提出的模拟方法分析了多级开挖卸荷作用下坡体裂隙的扩展机制与边坡的破坏路径。结果表明：裂隙岩体边坡从上至下多级开挖过程中,坡肩裂隙首先起裂,并通过拉张型扩展逐渐发展为优势裂隙;随着边坡下挖,优势裂隙沿坡面向下逐步发生拉张/剪切混合型扩展并与既有裂隙交汇,在边坡中上部形成阶梯状扩展破坏路径;裂隙扩展至边坡下部及坡脚后扩展模式由拉张/剪切混合型转化为剪切型,并最终以弧形剪切面从坡脚出露。研究揭示了裂隙岩体边坡多级开挖卸荷作用下上部阶梯状拉张/剪切混合型破裂-下部弧形剪切型破裂的复合破坏模式,可为边坡工程支护设计和施工稳定性控制提供新思路。     

Petroleum in the Jurassic Reservoirs within the Eastern Fukang Sub-depression, Junggar Basin, NW China: Correlation and Source Rock

The origin and source of the petroleum in the Jurassic reservoirs within the eastern Fukang sub-depression were geochemically investigated. They show thermal maturities matching the peak generation stage, while the condensates are at the early stage of intense cracking. Oils and condensates may have experienced mild evaporative fractionation, while mixing of severely biodegraded with non-biodegraded oils has occurred. Using biomarkers and isotopes, petroleums were classified into Group I, II and III genetic groups, with Group III further divided into IIIa and IIIb subgroups. Group I petroleum displays heavy carbon isotopes, a strong predominance of pristine over phytane, high C19 and C20 tricyclic and C24 tetracyclic terpanes, low gammacerane, and dominant C29 steranes, while Group II shows light carbon isotopes, a predominance of phytane over pristine, high C21 and C23 tricyclic with low C24 tetracyclic terpanes, high gammacerane and dominant C27 steranes. Group IIIa petroleum shows mixing compositions of Group I and II, while Group IIIb displays similar compositions to Group I, but with significantly higher Ts, C29Ts and C30 diahopane proportions. Oil-source rock correlation suggests Group I and II petroleums originate from Jurassic and Permian source rocks, respectively, while Group IIIa are mixtures sourced from these rocks and IIIb are mixtures from Jurassic and Triassic source rocks.     

A Numerical Simulation Study of Temperature and Pressure Effects on the Breakthrough Pressure of CO2 in Unsaturated Low-permeability Rock Core

Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock, and it also plays important roles in safety and capacity of CO2 geological storage. Based on the published experimental results, we present numerical simulations on CO2 breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions (which can keep CO2 in gaseous, liquid and supercritical states) and thus, a numerical method which can be used to accurately predict CO2 breakthrough pressure on rock-core scale is proposed. The simulation results show that CO2 breakthrough pressure and breakthrough time are exponential correlated with P-T conditions. Meanwhile, pressure has stronger effects on experimental results than that of temperature. Moreover, we performed sensitivity studies on the pore distribution index λ (0.6, 0.7, 0.8, and 0.9) in van Genuchten-Muale model. Results show that with the increase of λ, CO2 breakthrough pressure and breakthrough time both show decreasing trends. In other words, the larger the value of λ is, the better the permeability of the caprock is, and the worse the CO2 sealing capacity is. The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.     

青藏高原古近系牛堡组三段天文周期旋回分析及古湖平面演化研究：以尼玛盆地尼1井为例

青藏高原中部尼玛盆地是一个形成于班公湖-怒江缝合带之上的新生代陆相裂谷盆地。交通不便和勘探程度较低等因素导致其高精度沉积旋回特征和地层学一直鲜有研究。尼1井是盆地内第一口地质探井,通过对该井古近系牛堡组三段的自然伽马测井曲线进行频谱分析,证实了天文轨道周期对盆地内湖相地层的沉积具有显著影响。滤波分析显示牛堡组三段保存了41个短偏心率(～100 kyr)周期,76个斜率(～54 kyr)周期和178个岁差(～23 kyr)周期,平均沉积速率为92.03m/Ma,沉积时限～4.1 Myr。此外,结合Fischer图解与总有机碳含量的变化趋势,确定牛堡组三段湖平面经历了1次长周期的升-降变化过程。综合分析,认为尼玛盆地优质烃源岩的形成主要受天文旋回周期影响下的湖平面变化所控制。