Measurements of the concentrations of carbonyl sulfide (COS) in the marine atmosphere were made over a period of two years in the southern Indian Ocean (Amsterdam Island, 37°50 S–77°31 E; March 1987–February 1988 and April 1989–February 1990). The mean atmospheric COS concentration for the whole period was 475±48 pptv (n=544). Atmospheric COS concentrations show no significant seasonal variation with a summer to winter ratio of 1.05. Taking into account the observed variability of the atmospheric COS concentration (10%), a value of 1.4 yr is estimated as a lower limit for the atmospheric COS lifetime. A comparison of the COS data at Amsterdam Island with those obtained in the Southern Hemisphere in the past 12 yr does not reveal any significant trend in the tropospheric background COS mixing ratio. 相似文献
In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized
zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change
from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly
perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope
system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of
2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave.
−7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local
contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the
Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef
has generally higher plagioclase and pyroxene δ18O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic
evidence for sub-solidus interaction with fluids, and the Δplagioclase–pyroxene values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope
system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative
δD values suggest a greater involvement of meteoric water. Consistently higher values of Δplagioclase–pyroxene in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO2-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction
is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale.
The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination
played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO2 produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation. 相似文献
We designed a new seismic source model for Italy to be used as an input for country-wide probabilistic seismic hazard assessment (PSHA) in the frame of the compilation of a new national reference map.
We started off by reviewing existing models available for Italy and for other European countries, then discussed the main open issues in the current practice of seismogenic zoning.
The new model, termed ZS9, is largely based on data collected in the past 10 years, including historical earthquakes and instrumental seismicity, active faults and their seismogenic potential, and seismotectonic evidence from recent earthquakes. This information allowed us to propose new interpretations for poorly understood areas where the new data are in conflict with assumptions made in designing the previous and widely used model ZS4.
ZS9 is made out of 36 zones where earthquakes with Mw > = 5 are expected. It also assumes that earthquakes with Mw up to 5 may occur anywhere outside the seismogenic zones, although the associated probability is rather low. Special care was taken to ensure that each zone sampled a large enough number of earthquakes so that we could compute reliable earthquake production rates.
Although it was drawn following criteria that are standard practice in PSHA, ZS9 is also innovative in that every zone is characterised also by its mean seismogenic depth (the depth of the crustal volume that will presumably release future earthquakes) and predominant focal mechanism (their most likely rupture mechanism). These properties were determined using instrumental data, and only in a limited number of cases we resorted to geologic constraints and expert judgment to cope with lack of data or conflicting indications. These attributes allow ZS9 to be used with more accurate regionalized depth-dependent attenuation relations, and are ultimately expected to increase significantly the reliability of seismic hazard estimates. 相似文献
Identifying a good site for groundwater exploration in hard rock terrain is a challenging task. In hard rocks, groundwater
occurs in secondary porosity developed due to weathering, fracturing, faulting, etc., which is highly variable within short
distance and contributing to near-surface inhomogeneity. In such situations topographic, hydrogeological and geomorphological
features provide useful clues for the selection of suitable sites.
Initially, based on satellite imagery, topographical, geomorphological and hydrogeological features, an area of about 149
km2 was demarcated as a promising zone for groundwater exploration in the hard rock tract of Seethanagaram Mandal, Vizianagaram
District, Andhra Pradesh, India. A total of 50 Vertical Electrical Soundings (VES) were carried out using Wenner electrode
configuration. An interactive interpretation of the VES data sharpened the information inferred from geomorphological and
hydrogeological reconnaissance. Ten sites were recommended for drilling. Drilling with Down-The-Hole Hammer (DTH) was carried
out at the recommended sites down to 50 to 70 m depths. The interpreted VES results matched well with the drilled bore well
lithologs. The yields of bore wells vary from 900 to 9000 liters per hour (lph). 相似文献