油页岩灰渣提取氧化铝制备铝酸盐发光材料

利用干馏后的油页岩灰渣,湿法提取氧化铝作为发光材料基质,经采用高温固相法合成 CaAl2O4 : Eu3 + ,R + ( R = Li,Na,K,Rb) 荧光粉。最佳合成条件为: 烧结温度1 200 ℃,烧结时间3 h,助熔剂加入量3 wt%,激活离子配比3 mol%; 实验发现辅助激活离子为Li + 时,CaAl2O4 : Eu3 + , Li + 的发光强度最强。样品荧光光谱分析结果表明,发射光谱在615 nm 处出现强谱峰,归属为Eu3 + 的5D0→7F2 跃迁辐射。     

青海地区盐渍土分布规律及其独特工程特性探讨

针对青海一些地区盐渍土当硫酸钠含量小于1%时也会产生盐胀,而超氯盐渍土却不会产生溶陷的事实,进行了较为深入细致的论证和研究。以数据、事实为依据,得出了与现行理论及规范有较大出入的论断。     

我国海水贝类养殖低碳效应评价

食物生产系统的碳排放占人类活动碳排放总量的 30%, 碳汇渔业是一种重要的面向人类社会高质量食物蛋白质供给 的低碳发展路径。本文基于常见的 11 种养殖贝类的固碳系数和蛋白质含量特性研究,系统评估了我国2019 年养殖牡蛎 、蛤 类、扇贝、贻贝和蚶类等在养殖周期内碳捕集特性以及对低碳发展的贡献。研究表明： (1) 11 种养殖贝类之间贝壳和软体 组织含碳量的差异并不明显,但干重比和出肉率差异显著。因此,贝类固碳量核算不能忽视种类差异。 (2)所选 11 种贝类 软体组织皆属于高蛋白食品,虾夷扇贝软体组织 (干重) 的蛋白质含量最高。针对单位质量贝类养殖,长牡蛎的碳封存贡献 度最大,而华贵栉孔扇贝提供的蛋白质最多,两者都是碳汇渔业的优势种。(3) 据估算,我国2019 年海水养殖贝类中牡蛎、蛤 类 、扇贝和蚶类总共吸收固定了约 117.98 万吨 C02,提供了 40.65 万吨蛋白质 。这些蛋白质相比于牛肉源蛋白质可减少 4 048.74 万吨 C02 当量的排放量。由于贝类固碳强度大,探索低碳可持续的贝类养殖是绿色渔业经济的重要引擎, 也是建立可持续高质量“蓝色粮仓”和生物固碳的重要路径, 将在我国低碳产业发展中发挥重要作用。     

2022年冬奥会对张家口城市旅游地形象的影响研究——基于UGC文本分析

重大节事活动对旅游地形象的影响具有时序动态特征,分析其内在机理有利于促进目的地营销和竞争力提升。本文采用Python数据挖掘技术和自然语言处理技术（NLP）,爬取国内知名旅游门户网站的旅游评论,从“认知-情感-整体”3个维度构建分析框架,探究2022年冬奥会申办期、筹备期、预热举办期的张家口城市旅游地形象的时序变化特征,解析特殊时期冬奥会对城市旅游地形象的潜在影响和作用机制。结果表明：(1)张家口市的城市旅游地形象构成要素日趋多元化,冬奥会的作用效果由弱变强。张家口市的冰雪旅游形象关键度不断提升,经历了由模糊向具象转变的细化过程,情感形象产生积极变化;(2)冬奥会对张家口城市旅游地形象产生了渐进式影响效应,通过旅游体验的建构作用、投射形象的引致作用和品牌感知的晕轮作用发挥效果。冬奥会推动张家口市的产品业态创新、基础设施升级及服务水平提升,通过改善游客体验对城市旅游地形象产生积极影响。研究结果对东道主城市的旅游营销和规划具有一定指导意义。     

Spatiotemporal variations of water use efficiency and its driving factors in Inner Mongolia from 2001 to 2020

Water use efficiency (WUE) is an important variable to explore coupled relationships in carbon and water cycles. In this study, we first compared the spatial variations of annual gross primary productivity (GPP) and evapotranspiration (ET) using four GPP and ET products. Second, we selected the products closest to the flux towers data to estimate WUE. Finally, we quantitatively analyzed the impact of climate change and soil water content on WUE. The results showed that: (1) Four GPP and ET products provided good performance, with GOSIF-GPP and FLDAS-ET exhibiting a higher correlation and the smallest errors with the flux tower data. (2) The spatial pattern of WUE is consistent with that of GPP and ET, gradually decreasing from the northeast to the southwest. Higher WUE values appeared in the northeast forest ecosystem, and lower WUE values occurred in the western Gobi Desert, with a value of 0.28 gC m^?2 mm^?1. The GPP and ET products showed an increasing trend, while WUE showed a decreasing trend (55.15%) from 2001 to 2020. (3) The spatial relationship between WUE and driving factors reveal the variations in WUE of Inner Mongolia are mainly affected by soil moisture between 0 and 10 cm (SM0-10cm), vapor pressure deficit (VPD), and precipitation, respectively. (4) In arid regions, VPD and precipitation exhibit a major influence on WUE. An increase in VPD and precipitation has a negative and positive effect on WUE, with threshold values of approximately 0.36 kPa and 426 mm, respectively. (5) In humid regions, SM0-10cm, VPD, SM10-40cm, and SM40-100cm exert a significant impact on WUE, especially SM0-10cm, and weakens with increasing soil depths, these differences may be related to physiological structure and living characteristics of vegetation types in different climate regimes. Our results emphasize the importance of VPD and soil moisture in regional variability in WUE.     

Temporal stability of apparent soil electrical conductivity measured by electromagnetic induction techniques

Assessing and managing the spatial variability of hydropedological properties are important in environmental,agricultural,and geological sciences.The spatial variability of soil apparent electrical conductivity（ECa） measured by electromagnetic induction（EMI） techniques has been widely used to infer the spatial variability of hydrological and pedological properties.In this study,temporal stability analysis was conducted for measuring repeatedly soil ECa in an agricultural landscape in 2008.Such temporal stability was statistically compared with the soil moisture,terrain indices（slope,topographic wetness index（TWI）,and profile curvature）,and soil properties（particle size distribution,depth to bedrock,Mn mottle content,and soil type）.Locations with great and temporally unstable soil ECa were also associated with great and unstable soil moisture,respectively.Soil ECa were greater and more unstable in the areas with great TWI（TWI 〉 8）,gentle and concave slope（slope 〈 3%; profile curvature 〉 0.2）.Soil ECa exponentially increased with depth to bedrock,and soil profile silt and Mn mottle contents（R2= 0.57）,quadratically（R2 = 0.47）,and linearly（R 2 = 0.47）,respectively.Soil ECa was greater and more unstable in Gleysol and Nitosol soils,which were distributed in areas with low elevation（〈 380 m）,thick soil solum（〉 3 m）,and fluctuated water table（shallow in winter and spring but deep in summer and fall）.In contrast,Acrisol,Luvisol,and Cambisol soils,which are distributed in the upper slope areas,had lower and more stable soil ECa.Through these observations,we concluded that the temporal stability of soil ECa can be used to interpret the spatial and temporal variability of these hydropedological properties.     

舰船气泡尾流分布的BPBE表征方法研究

基于气泡群平衡方程(BPBE),提出一种用于更系统表征舰船气泡尾流变化特征的数值模型。模型的创新处在于既能反映气体传质因素的影响,又考虑了尾流中实际存在的气泡聚并现象,且具有简单易行,运算效率高的特点。分析结果表明:聚并在近尾流区作用强烈,传质在远程尾流区作用明显;聚并对BND的分布变化影响不大,对气含量的发展变化则发挥着主要作用;尺寸为70~80 um的气泡BND最大,尺寸为200 um的气泡气含量最大。     

Influencing factors of gas content evaluation for shale gas： a case study of Lower Paleozoic Wuling fold belt in Upper Yangtze Basin

Factors of shale gas accumulation can be divided into the external and internal factors, according to accumulation mechanism and characteristics of shale gas. The internal factors mainly refer to parameters of organic geochemistry, mineral components and physical parameters. Six factors were presented in this study, i. e. organic matter, maturity, quartz, carbonate, clay mineral and pore. The external factors mainly refer to geologic environment of shale gas reservoir, including four factors： temperature, pressure, depth and thickness. Based on the experiment results of 26 samples of drilling cores from Wuling fold belt in Lower Paleozoic Silurian of the Upper Yangtze Basin, combined with the integrated analysis of geology, logging and test, the correlation of the gas content of shale gas to the above-mentioned ten factors was concluded. Six important evaluation indicators were preliminarily established in the gas-bearing core area of marine shale in the Upper Yangtze Basin.     

Last glacial emplacement of methane-derived authigenic carbonates in the Sea of Japan constrained by diatom assemblage,carbon-14, and carbonate content

We studied diatom assemblages and CaCO₃ contents of methane-derived authigenic carbonates from the eastern margin of the Sea of Japan and assessed the formation time of these samples. Radioactive ¹⁴C date was determined in selected samples to obtain the maximum age of the time. The results of our study suggest mass formation of carbonate nodules in a glacial period within ∼40 ky, consistent with a published U/Th dating result of carbonate nodules in the study area. Diatom assemblages and contents in the carbonate nodules (abundance of ∼10⁶/g, dominance of neritic-littoral species, warm/cold water species ratio lower than ∼25) differ from the near-seafloor sediments in the study area, which have characteristics of Holocene sediments in the Sea of Japan, and suggest cementation of glacial sediments. Laminated sediments in some nodule samples are glacial sediments because laminations are records of a low sea level period in the semi-enclosed ocean. Similarity of diatom assemblages and contents in all carbonate samples is another evidence of glacial sediments in nodules. Glacial sediments with oceanic cold water species as low as Holocene sediments restricts the sediment age to before 20 cal. ky BP. Carbonate contents higher than 78 wt% suggest the cementation of poorly compacted sediments near the seafloor, and the date of carbonate cementation is, therefore, close to that of the cemented sediments. Most carbonate nodule samples in this study were formed in a glacial period and detection of ¹⁴C restricts this period to within ∼40 ky.     

一种统计技术结合动力释用的沿海海雾预报方法

提出了一种利用历史相似个例查询技术,结合WRF模式输出释用的Gultepe沿海大雾业务预报方法。该方法可以较好的计算近地面大气中的液态水含量(LWC)和云滴粒子数密度(Nd)参数。利用该方法对2011—2013年的3—6月的历史沿海海雾个例进行试报,结果表明,恰当的结合统计方法和动力模式可以一定程度上克服目前数值模式不成熟的缺陷,从而提高WRF模式在大雾业务预报方面的释用水平。