关于间接测定碘的分析方法研究

用硝基苯萃取[Cd（Phen）3]^2＋I2^-离子对,再用盐酸反萃取,利用氢化物发生-原子荧光光谱法测定镉的含量,从而间接测定碘。实验在pH=5．2的NaAc-HAc缓冲体系下进行,优化了还原剂KBH;中邻菲罗啉的浓度,镉溶液用量,萃取剂硝基苯的用量,反萃取盐酸的酸度,并制备碘的标准曲线,其线性相关系数R2≥0．9942,线性范围0～10ng／mL,精密度为8．5％,检出限0．80ng／mL,利用标准曲线测出水样中碘的浓度为17．78ng／mL,结果令人满意。实验表明,开发原子荧光光谱间接分析方法,使其能够准确测量更多种类的元素,有着十分积极的意义,同时也能够促进该方法得到更广范的应用。     

郑州市大雾气候特点及一次个例分析

为了了解近20 a郑州市大雾的时空变化特征,根据1980-2005年郑州市大雾观测记录,统计分析了这一时期郑州市大雾的变化特点及产生大雾时的气象要素特征;并利用河南省地面和探空观测资料以及NCEP1°×1°再分析资料,从要素场、大气稳定度等方面,对2007年12月25-27日郑州市大雾形成原因进行了分析.结果表明:郑州市年雾日数呈下降趋势,每月都可以出现大雾,但12月最多,6月最少.降水后较大的相对湿度、稳定的大气层结以及近地层较小风速等是大雾形成的必要条件.     

衡阳南岳区农村居民点用地合理布局分析

城镇化水平的快速推进和社会主义新农村建设的开展给建设用地供给和耕地保护形成了巨大的压力。农 村居民点用地普遍散乱、粗放的现象为挖掘现有建设用地潜力,少占耕地提供了可能。以衡阳南岳区为例,应用GIS 空间分析与景观指数分析等方法,在分析社会经济、自然地理和生产环境三方面的主要因素对南岳区农村居民点 用地布局的影响后,提出引导南岳区农村居民点合理布局的对策与建议。     

湖南省城市化与经济发展关系的计量分析

运用现代计量经济学的计量分析方法对湖南省城市化与经济发展的相互关系与相互作用进行了探讨。结果表明,城市化与经济发展二者之间存在协整关系即长期均衡关系,但短期失衡,其波动有近35％得到调整;经济发展对城市化的冲击强烈,其解释水平高达到82％;城市化对经济发展冲击微弱,其解释水平仅达到5．4％;经济发展来自自身的冲击较大,而城市化来自本身冲击较小,但有增强趋势。经济发展与城市化二者之间的这种关系作用应引起关注。     

冬春季切变类冰雹发生条件的对比分析

本文以 1996年 12月 31日和 1981年 5月 1日为例 ,对冬、春季节发生在江苏的较大范围的切变类冰雹天气过程作了对比分析。结果指出 ,无论冬季或春季当高原东部有深槽东移 ,冷暖空气在江淮地区交汇 ,地面抬升系统为暖切 ,并有大气层结不稳定 (Δθse( 50 0 - 850 ) <0℃ =中心和较强的风向和风速垂直切变、85 0hPa西南急流轴、85 0hPa最大水汽通量轴线、5 0 0和 85 0hPa正涡度中心等相配置时 ,就可能导致江苏地区较大范围强对流天气的发生。     

Vertical structures of PM10 and PM 2.5 and their dynamical character in low atmosphere in Beijing urban areas

The vertical structures and their dynamical character of PM2.5 and PM10 over Beijing urban areas are revealed using the 1 min mean continuous mass concentration data of PM2.5 and PM10 at 8, 100, and 320 m heights of the meteorological observation tower of 325 m at Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP CAS tower hereafter) on 10―26 August, 2003, as well as the daily mean mass concentration data of PM2.5 and PM10 and the continuous data of CO and NO2 at 8, 100 (low layer), 200 (middle layer), and 320 m (high layer) heights, in combination with the same period meteorological field observation data of the meteorological tower. The vertical distributions of aerosols observed on IAP CAS tower in Beijing can be roughly divided into two patterns: gradually and rapidly decreasing patterns, I.e. The vertical distribution of aerosols in calm weather or on pollution day belongs to the gradually decreasing pattern, while one on clean day or weak cold air day belongs to the rapidly decreasing pattern. The vertical distributive characters of aerosols were closely related with the dynamical/thermal structure and turbulence character of the atmosphere boundary layer. On the clean day, the low layer PM2.5 and PM10 concentrations were close to those at 8 m height, while the concentrations rapidly decreased at the high layer, and their values were only one half of those at 8 m, especially, the concentration of PM2.5 dropped even more. On the clean day, there existed stronger turbulence below 150 m, aerosols were well mixed, but blocked by the more stronger inversion layer aloft, and meanwhile, at various heights, especially in the high layer, the horizontal wind speed was larger, resulting in the rapid decrease of aerosol concentration, I.e. Resulting in the obvious vertical difference of aerosol concentrations between the low and high layers. On the pollution day, the concentrations of PM2.5 and PM10 at the low, middle, and high layers dropped successively by, on average, about 10% for each layer in comparison with those at 8 m height. On pollution days, in company with the low wind speed, there existed two shallow inversion layers in the boundary layer, but aerosols might be, to some extent, mixed below the inversion layer, therefore, on the pollution day the concentrations of PM2.5 and PM10 dropped with height slowly; and the observational results also show that the concentrations at 320 m height were obviously high under SW and SE winds, but at other heights, the concentrations were not correlated with wind directions. The computational results of footprint analysis suggest that this was due to the fact that the 320 m height was impacted by the pollutants transfer of southerly flow from the southern peripheral heavier polluted areas, such as Baoding, and Shijiazhuang of Hebei Province, Tianjin, and Shandong Province, etc., while the low layer was only affected by Beijing's local pollution source. The computational results of power spectra and periods preliminarily reveal that under the condition of calm weather, the periods of PM10 concentration at various heights of the tower were on the order of minutes, while in cases of larger wind speed, the concentrations of PM2.5 and PM10 at 320 m height not only had the short periods of minute-order, but also the longer periods of hour order. Consistent with the conclusion previously drawn by Ding et al., that air pollutants at different heights and at different sites in Beijing had the character of "in-phase" variation, was also observed for the diurnal variation and mean diurnal variation of PM2.5 and PM10 at various heights of the tower in this experiment, again confirming the "in-phase" temporal/spatial distributive character of air pollutants in the urban canopy of Beijing. The gentle double-peak character of the mean diurnal variation of PM2.5 and PM10 was closely related with the evident/similar diurnal variation of turbulent momentum fluxes, sensible heat fluxes, and turbulent kinetic energy at various heights in the urban canopy. Besides, under the condition of calm weather, the concentration of PM2.5 and PM10 declined with height slowly, it was 90% of 8 m concentration at the low layer, a little lesser than 90% at the middle layer, and 80% at the high layer, respectively. Under the condition of weak cold air weather, the concentration remarkably dropped with height, it was 70% of 8 m concentration at the low layer, and 20%―30% at the middle and high layers, especially the concentration of PM2.5 was even lower.     

黄土高原半干旱区非均一下垫面粗糙度分析

利用2007年4月17日-2008年4月16日兰州大学半干旱气候与环境观测站边界层气象塔的风速、 风向、 温度、 气压、 湿度等观测资料, 采用经典的廓线法和风速、 风向标准差法, 分别计算了中性大气层结下观测站下垫面粗糙度长度, 并得到了具有黄土高原地理特征的地表粗糙度及其时空变化特征。计算结果表明, 季节变化对粗糙度的影响幅度可达0.159 m, 空间非均一性对粗糙度的影响幅度可达0.155 m。测站附近粗糙度春季为0.017 m, 夏季为0.062 m, 秋季为0.065 m, 冬季为0.018 m。测站西北方向上游粗糙度春季为0.17 m, 夏季为0.22 m, 秋季为0.34 m, 冬季为0.05 m。测站东南方向上游粗糙度春季为0.11 m, 夏季为0.17 m, 秋季为0.19 m, 冬季为0.05 m。该站下垫面粗糙度计算宜选用风速为6±1.5 m·s-1, 风向变化30°范围内的数据。     

Uncertainty analysis of CO_2 flux components in subtropical evergreen coniferous plantation

We present an uncertainty analysis of ecological process parameters and CO2 flux components (Reco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance meas-urements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different ...     

豫北一次区域性大暴雨的数值模拟分析

利用NECP 1°×1°6 h再分析资料和WRF中尺度数值模式对2006年7月2-3日豫北区域性大暴雨过程进行数值模拟,并用模拟结果对该过程作中尺度分析.结果表明:暴雨中尺度系统发展和维持期间,基本上是强涡度区对应强辐合区,使得垂直对流运动发生发展,为强降水发生和持续提供了动力条件;θse值大小和实况降水强弱演变对应关系很好,θse值越大,实况降水越强,反之,实况降水越弱;豫北地区出现强降水时,水汽通量中心位于豫南且分布在西南急流轴上,豫中南部始终维持一条明显的水汽输送带,水汽被源源不断地输送到豫北地区;豫北地区处于明显的水汽辐合区,强辐合区有一自西向东的移动过程,与实况强降水过程演变趋势一致;大暴雨区域上空从低层到对流层顶层垂直螺旋度均为正值,且强降水时段与螺旋度最强时段对应关系很好,降水峰值与正螺旋度中心出现时间吻合.     

华南区域季节性降水的差异分析

运用EOF方法研究华南区域降水时空分布特征,结果表明：（1）华南地区各季节降水在年际和年代际的时间变化上有区域一致性,但有季节性差异,其中春季和秋季在20世纪80年代后降水明显减少,旱年增多;而夏季90年代后降水明显增加,涝年增多;冬季变化则不明显。（2）华南地区各季节降水在空间分布上也有差异,其中春季降水呈现东多西少的分布特征,大值中心位于广西东北部、广东中部及西南沿海。夏季和秋季降水相似,呈南多北少的分布特征,大值中心位于广西沿海和广东西南沿海。冬季降水呈东北多西南少的分布特征,大值中心位于粤北。