东北地区五大连池湖相沉积物正构烷烃和单体碳同位素特征及其古植被意义

对中国东北地区小兴安岭与松嫩平原过渡带五大连池青石钻孔湖相沉积物进行了有机地球化学分析,检测出丰富的正构烷烃生物标志化合物.本文主要讨论了正构烷烃的分布及其单体碳同位素组成特征.正构烷烃具有前峰型和双峰型两种分布特征,表明其有机质为混合来源,包括低等菌藻类生物和陆生高等植物输入.正构烷烃的分布特征表明,自35.2ka B.P.以来,nC27/nC31和ACL指标共同记录了东北地区小兴安岭与松嫩平原过渡带的植被以草本为主.对C27、C29和C31长链正构烷烃进行了单体碳同位素测定,并利用二元模式估算了C3和C4植物相对生物量,结果表明,自35.2ka B.P.以来,研究区的植被以C3植物为主.期间在典型冷暖气候事件中,受温度变化的影响,C3/C4植物的相对生物量有明显的变化,在全新世大暖期(6.0ka B.P.),受温度升高影响,C3植物的生物量显著减少,C4植物的生物量则明显增加;而在两次典型冷气候事件(中全新世降温事件8.2ka B.P.和新仙女木事件12.9ka B.P.)时期,受温度降低影响,C3植物的生物量有增加的趋势,C4植物的生物量则相对呈减少的趋势;在末次冰盛期21.0ka B.P.时,受明显低温特征的影响,C3植物生物量高达80.0％,这可能是当时低温的气候特征抑制了C4植物的生长.研究结果对探索我国东北地区C3/C4植物分布格局,并为评估未来气候演化对该地区植被格局和农业生产的影响提供科学依据.     

可可西里盆地东部五道梁群热水湖相成因新认识

五道梁地区位于青藏高原北部可可西里盆地东部,其中新世发育一系列古湖泊,保存有大套碳酸盐沉积。本文通过对五道梁北山含叠层石剖面和南部剖面进行矿物学、元素地球化学研究,发现叠层石剖面主要矿物为方解石和少量石英,而南侧剖面则含有铁白云石、方解石、石英和钠长石。铁白云石和钠长石次生加大边的发现说明该区曾受热水活动的影响。元素分析结果也显示As、Sb、Ba、Fe等热水沉积标志元素含量较高,且Ni/Co、Mn/Sr、V/Cr、V/Sc等比值也较高;加之稀土元素配分模式和碳氧同位素特征均表明该地区为热水湖相沉积。另外叠层藻的出现也反映当时湖水温度至少为20~30℃。综合各种分析结果说明五道梁群为热水湖相成因,该区中新世发育有大量火山岩,因此可作为下一步寻找火山沉积型硼矿床重要线索。     

Distribution and partitioning of major and trace elements in pyrite-bearing sediments of a Mediterranean coastal lagoon

The formation of iron sulphide minerals exerts significant control on the behaviour of trace elements in sediments. In this study, three short sediment cores, retrieved from the remote Antinioti lagoon (N. Kerkyra Island, NW Greece), are investigated concerning the solid phase composition, distribution, and partitioning of major (Al, Fe) and trace elements (Cd, Cu, Mn, Pb, and Zn). According to ²¹⁰Pb, the sediments sampled correspond to depositions of the last 120 years. The high amounts of organic carbon (4.1–27.5%) result in the formation of Fe sulphides, predominantly pyrite, already at the surface sediment layers. Pyrite morphologies include monocrystals, polyframboids, and complex FeS–FeS₂ aggregates. According to synchrotron-generated micro X-ray fluorescence and X-ray absorption near-edge structure spectra, authigenically formed, Mn-containing, Fe(III) oxyhydroxides (goethite type) co-exist with pyrite in the sediments studied. Microscopic techniques evidence the formation of galena, sphalerite and CuS, whereas sequential extractions show that carbonates are important hosts for Mn, Cd, and Zn. However, significant percentages of non-lattice held elements are bound to Fe/Mn oxyhydroxides that resist reductive dissolution (on average 60% of Pb, 46% of Cd, 43% of Zn and 9% of Cu). The partitioning pattern changes drastically in the deeper part of the core that is influenced by freshwater inputs. In these sediments, the post-depositional pyritization mechanism, illustrated by overgrowths of Fe monosulphides on pre-existing pyrite grains, results in relatively high degree of pyritization that reaches 49% for Cd, 66% for Cu, 32% for Zn and 7% for Pb.     

CONSIDERATION OF HYDRODYNAMIC CHARACTERISTICS,SEDIMENTS & ENVIRONMENTAL PROBLEMS OF MUDDY COAST IN THE CONSTRUCTION OF LIANYUNGANG HARBOUR

After nearly 20 years of construction,we have successfully solved a series of hydrologic sedimentaryand environment problems encountered during the construction of the big deep water harbour inLianyungang which can now accommodate ships of 50000 tonnage.With the economic development,the channel of 50000 tonnage will be built soon, and of 100000 tonnage is under planning. Theconstruction of the international container shipping hub at the harbour is being accelerated in anticipationof the opening of the second Eurasian land bridge.The future development of the harbour will givegreat impetus to the local economy of Lianyungang City and make it an international city.     

Coring tips

This commentary is intended as a practical guide for the non-motorized use of piston corers to obtain undisturbed sections of lake sediments. Good recovery is essential for accurate reconstruction of environmental and limnological history. Emphasis is placed on the square-rod piston corer, which is widely used for acquisition of sediment cores in meter-long sections from lakes as much as 30 m deep. Coring platforms for open water can be easily prepared on pairs of boats or canoes or (in water depth up to 15 m) even a single small rubber raft, but firm anchoring is essenial to maintain the vertical position of the casing and to assure re-entry into a single hole. Incomplete recovery on individual drives is not a result of sediment compaction but rather the build-up of friction on the tube interior, by which the core forms a plug that prevents further recovery.Short cores of soft sediment for the study of recent changes in lakes are also best acquired with a piston corer, for a gravity corer without a piston may be subject to the same type of plug formation. In cases in which the structure of the sediment must be preserved (e.g. annual laminations), freezing the sediment in place with a dry-ice solution is the best procedure.     

Beach sediment temperature variations through depth and time

Data obtained from a site at mean tide level on Belfast Lough, Northern Ireland, show temperature fluctuations on various timescales. Hourly means differ markedly from month to month but are similar for different depths during the same month. The short-term temperature fluctuations recorded at the surface are largely dissipated at a sediment depth of 20 cm with the proportion of total flux occurring at any depth remaining similar irrespective of the absolute temperature range. It is suggested that temperature flux ratios may provide an objective in situ assessment of beach exposure and/or water flow through sediments. A plea for a standardized methodology is made.     

DISTRIBUTIONS OF TOTAL, INORGANIC AND ORGANIC PHOSPHORUS IN THE SEDIMENTS NEAR THE HUANGHE RIVER ESTUARY

For some hundred surface sediment samples from five cores taken in two cruises near the Huanghe River Estuary, total phosphorus (TP (.inorganic phosphorus (IP (and organic phosphorus (OP)were determined.On the average, 527×10-6, 455×10~6 and 72×10-6 were found for TP,IP and OP for the surface sediments taken in the two cruises. The distribution of OP and IP was controlled by the sample particle size: OP content increased with the decreasing of the sample particle size, while the maximal value of IP was found in the silt fraction due to the existence of apatite in our samples. Vertical distributions reflected well the channel change of the Huanghe River. Results from the multiple regressions between the three forms of phosphorus and the percentages of different particle size agreed well with the analytical data.     

A Late Weichselian stable isotope stratigraphy compared with biostratigraphical data: A case study from southern Sweden

Late Weichselian lake sediments from a site in southern Sweden, were analysed for stable carbon and oxygen isotopes, as well as plant macrofossils and insect remains. By comparison of independent data sets, general climatic changes were demonstrated. Lithological, chemical and stable isotope data reveal two significant climatic oscillations at ca. 12 200–12 000 and ca. 11 000–10 200 yr BP respectively. Continental climatic conditions, indicated by evaporative enrichment of ¹⁸O in lake marl, characterise parts of the early lake history, including the Older Dryas Stadial. Distinct variations of δ¹³C in organic material is discussed in terms of climatically induced changes in lake-water chemistry. Different types of photosynthetic assimilation of dissolved inorganic carbon is proposed as a contributing factor influencing lake marl δ¹³C. The universal application of a positive correlation between lake marl δ¹⁸O and mean annual air temperature is questioned. Quantifications of mean summer and winter temperatures based on beetle analysis show a climatic optimum around 12 000 yr BP, a marked cooling around 11 000 yr BP and a strong amelioration at ca. 10 200 yr BP. These climatic events were accompanied by distinct changes in aquatic vegetation. Plant macrofossil and insect analyses indicate an open vegetation during the entire period studied. Biostratigraphical data reflecting local limnic and terrestrial vegetation and regional climate facilitate the interpretation of stable isotope data.     

Infilling of the Younger Kathmandu–Banepa intermontane lake basin during the Late Quaternary (Lesser Himalaya,Nepal): a sedimentological study

The Kathmandu and Banepa Basins, Central Nepal, are located in a large syncline of the Lesser Himalayas. The Older Kathmandu Lake evolved during the Pliocene and early Pleistocene; the Younger Kathmandu Lake, which is the focus of this study, is infilled with late Quaternary sediments. Three formations, arranged in stratigraphical order, the Kalimati, Gokarna and Thoka Formations formed during the infilling stage of this lacustrine basin. Structural and textural sedimentological analyses, a chemical survey across the basin and mineralogical investigations of fine‐grained sediments form the basis of this palaeogeographical study. The basin under investigation was covered by a perennial freshwater lake before 30 000 yr BP. The lake was infilled with alluvial and fluvial sediments delivered mainly from the mountains north of the basin. A fairly low gradient was favourable for the formation of diatomaceous earths, carbonaceous mudstones and siltstones, which were laid down in the centre of the lake and in small ponds. Towards the basin edge, lacustrine sediments gave way to deltaic deposits spread across the delta plain. Crevasse splays and anastomosing rivers mainly delivered suspended load for the widespread siltstones and mudstones. The proximal parts of the alluvial–fluvial sedimentary wedge contain debris flows that interfinger with fine‐grained floodplain deposits. Three highstands of the water‐level (>30 000 yr BP, 28 000–19 000 yr BP, 11 000–4000 yr BP (?)) have been recognised in the sedimentary record of the younger Kathmandu Lake in the Late Quaternary. Second‐order water‐level fluctuations are assumed to be triggered by local processes (damming by tectonically induced landslides). First‐order water‐level fluctuations are the result of climatic changes. Copyright © 2003 John Wiley & Sons, Ltd.