云南程海近500年来湖泊初始生产力的演化

程海为富营养化封闭湖泊，通过对程海CH01乳沉积物色素分析，定性恢复了近500a来程海湖泊初始生产力演化过程，结果表明，近500a来程海湖泊初始生产力总体上呈现由低到高的上升趋势，其中1700AD前后，1790AD前后是湖泊初始生产力出现变化的界限，另外，色素含量变化揭示研究时期内存在1750AD前后，1930AD前后二次明显暖波动。     

海洋表层沉积物中金属镉的来源解析

利用2015年8月份对长江口及其邻近海域表层沉积物的监测数据,基于主成分分析/绝对主成分分数(PCA/APCS)受体模型定量解析了重金属元素镉(Cd)的可能来源,并结合地统计学插值了Cd的源贡献量的空间分布状况,结果表明沉积物中镉污染主要存在3个可能来源,源头及贡献率分别为工业污染(18.8%)、陆地径流输入(66.0%)、生物活动等自然因素(13.6%),并且各个源头贡献量具有不同的空间分布状况,其中工业污染的高值区主要集中在靠近陆地区域,陆地径流输入的分布呈现由近岸向外海逐减降低的特征,生物活动等自然因素的高值区主要集中在远离陆地的外海区域。     

不同类型沉积物磁化率的比较研究和初步解释

沉积物的磁化率分析以被广泛应用在第四纪古气候研究中,不同类型沉积物磁化率的解释可能存在明显的差异.本文选择了黄土、冲积物、湖积物、风沙堆积和南方红土等五种不同类型的沉积物,进行了磁化率的测试,粒度和孢粉分析,试图通过对沉积物磁化率和相关古环境指标的研究,对不同类型沉积物的磁化率予以对比并进行初步解释.研究结果表明,黄土和湖泊沉积中磁化率的变化主要受气候变化的影响,是指示古气候的重要指标;河流沉积物和风沙沉积物的磁化率主要受粒度的影响;影响南方红土磁化率的因素十分复杂,其磁化率的解释比较困难有待进一步的研究.这一研究表明,鉴于不同沉积物磁化率的影响因素存在明显的不同,因此在运用磁化率进行古环境解释时须持慎重态度.     

Terrestrial discharge influences microbioerosion and microbioeroder community structure in coral reefs

Microbioerosion rates and microbioeroder community structure were studied in four Kenyan protected coral-reef lagoons using shell fragments of Tridacna giant clams to determine their response to the influence of terrestrial run-off. Fourteen different microbioeroder traces from seven cyanobacteria, three green algae and four fungi species were identified. The river discharge-impacted reef and ‘pristine’ reef showed similar composition but higher microbioeroder abundance and total cyanobacteria- and chlorophyte-bioeroded areas when compared with the other study reefs. Cyanobacteria dominated during the north-east monsoon (NEM) relative to the south-east monsoon (SEM) season, with algae and cyanobacteria being major microbioeroders in the river-impacted and pristine reefs. The rate of microbioerosion varied between 4.3 g CaCO3 m^?2 y^?1 (SEM) and 134.7 g CaCO₃ m^?2 y^?1 (NEM), and was highest in the river-impacted reef (127.6 g CaCO₃ m^?2 y^?1), which was almost double that in the pristine reef (69.5 g CaCO₃ m^?2 y^?1) and the mangrove-fringed reef (56.2 g CaCO₃ m^?2 y^?1). The microbioerosion rates measured in this study may not be high enough to cause concern with regard to the health and net carbonate production of Kenya’s coral reefs. Nevertheless, predicted increases in the frequency and severity of stresses related to global climate change (e.g. increased sea surface temperature, acidification), as well as interactions with local disturbances and their influence on bioerosion, may be increasingly important in the future.     

不同海域沉积物对尿素吸附的实验模拟研究

本文对采自渤海、黄海和东海3个典型海域的沉积物进行了尿素吸附/解吸的实验室模拟研究,用Freundlich吸附模型和Henry吸附模型分析了不同沉积物对尿素吸附的热力学特性,并研究了温度、沉积物粒径、有机质含量等因素对尿素在沉积物表面吸附的影响。结果表明,沉积物对尿素的吸附/解吸过程总体呈现3个阶段:快速吸附阶段（0~5 h）—慢速吸附阶段（5~12 h）—平衡阶段（12 h之后）。当水体中的尿素浓度较低时,沉积物解吸释放尿素,随着上覆水中尿素浓度逐渐增加,沉积物对上覆水中的尿素产生吸附行为,各海区沉积物对尿素的吸附能力由强至弱依次为渤海、东海、黄海,这可能与沉积物的类型有关。Freundlich方程和Henry方程均可模拟沉积物对尿素的吸附,温度、粒径以及沉积物中有机质含量等因素均对尿素在沉积物上的吸附产生影响,随着温度升高,尿素在沉积物上的吸附量变小,沉积物粒径越小,有机质含量越高,吸附尿素的能力越强,因此,揭示尿素在沉积物表面的环境行为时,必须考虑以上因素的影响。     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

东太平洋海隆13°N表层含金属沉积物物质组成与元素赋存状态

为了解不同类型含金属沉积物在物质组成和元素赋存状态的差异,对东太平洋海隆13°N洋中脊两侧表层含金属沉积物(站号:E271和E53)进行了矿物学、地球化学分析,顺序提取实验,并与前人对轴部表层沉积物(站号:17A-EPR-TVG1)的研究结果作了对比分析。研究结果表明, E271和E53是远端含金属沉积物,由非浮力热液羽状流中颗粒物沉降所形成的;17A-EPR-TVG1沉积物是近喷口含金属沉积物,由黑烟囱或者热液硫化物丘状体崩塌、堆积,或者由热液羽状流中Fe-Mn氧化物和硫化物快速沉淀而形成的,近喷口沉积物比远端沉积物更富集Fe、Cu和Zn等元素。元素在两种含金属沉积物中的赋存状态基本相同,除了Fe,Cu,Zn,Mo和稀土元素(REE)等元素在远端沉积物中主要存在于Fe-Mn氧化物相,在近喷口沉积物中主要在残留相中。远端沉积物中REE页岩标准化配分模式与海水相似,表明REE主要来自海水,而近喷口沉积物中REE配分模式与热液流体相似,说明REE以高温热液流体来源为主。相关研究结果加深了对热液沉积作用研究的认识。     

海底底质声学原位测量电路控制系统研究

介绍了一种液压驱动贯入式海底沉积声学原位测量系统的电路控制单元的研究实现过程,以及该控制单元在南海北部海底沉积声学调查中的应用。该电路控制单元以Cortex-A8处理器为核心,集成大容量FLASH存储器,与单片机接口控制板进行串口通讯,实现对声学发射采集单元和机械液压贯入单元的可视化控制和监测。基于该电路控制单元,海底底质声学原位测量系统兼具自容式和在线式两种工作模式,可自容记录或实时采集声学原位测量单元在海底的工作状态数据、海底沉积物声速和声衰减系数等声学特性数据。该声学原位测量系统的实验室联调及南海海试结果表明,使用该电路控制单元对海底底质声学测量过程的监测与控制是有效的,对精确获取海底底质的原位声学特性有重要作用,可以促进海底底质声学原位测量系统的产品化。     

内湾沉积物生物硅化学测定法的实验条件探讨

对国内外已经建立的几种生物硅的测定方法进行简要的评述,并详细地对内湾沉积物中生物硅化学提取法的条件选取进行实验探讨,对低生物硅含量的内湾沉积物测定提出了较优的条件。