红枫湖夏季分层期间pCO2分布规律的研究

在夏季分层期间对红枫湖南、北湖湖心的水样进行分层采集,同时测定了分层水样的温度、pH、HCO₃-浓度、溶解氧(DO)、叶绿素a(Chl-a)及铵根离子(NH₄+)、硝酸根离子(NO₃-)、磷酸根离子(PO₄3-)的浓度,水体中CO₂的分压(pCO₂)由化学平衡及亨利定律求得。研究结果表明:光合作用、有机质降解及水体热分层是影响红枫湖夏季pCO₂分布的主要因素。其中,温水层CO₂欠饱和是光合作用吸收CO₂引起的,温跃层中pCO₂的急剧增加是光合产物降解产生CO₂引起的。静水层沉积物附近pCO₂最高并且还有持续增加的趋势,说明沉积物中有机质降解是静水层中CO₂增加的主要原因,夏季湖底水温较高加快了沉积物中有机质的降解。分层现象使pCO₂在水体中的分布差别明显,并且使静水层中CO₂得到积累。此外,夏季红枫湖水体中pCO₂的变化与NH₄+、PO₄3-的变化密不可分,表现为温水层中光合作用消耗NH₄+、PO₄3-,有机质降解过程伴随NH₄+、PO₄3-的释放。     

太湖入湖河道沉积物中生物利用磷和营养水平分析

为了解太湖入湖河道的营养状况,研究了太湖西部河流沉积物生物利用磷的组成与分布。研究结果显示,北部沉积物中营养元素较高,南部较低;沉积物中生物利用磷的含量次序为藻类可利用磷(AAP)>NaHCO3提取磷(OLP)>水溶性磷(WSP)>易解吸磷(RDP),其中AAP是重要的生物利用磷,AAP的比例越高,富营养化程度越高。AAP与营养元素的相关性在不同区域河道有所不同,北部河道与总氮(TN)、总磷(TP)相关性较好,中部和南部河道与沉积物有机质总量(TOM)相关性较好。沉积物的生物利用磷受不同污染源影响较大。对比河道沉积物与湖泊沉积物的特征,发现湖泊沉积物中生物利用磷(BAP)/总磷(TP)、藻类可利用磷(AAP)/总磷(TP)都高于河道沉积物,表明湖泊沉积物中的磷更容易被植物吸收。     

Pelagic records from the Equatorial Ninetyeast Ridge and significant environmental events during the past 3.5 Ma

This paper presents pelagic records of planktic foraminifera, as well as data of stable isotope stratigraphy and carbonate stratigraphy since 3.5 Ma B.P. from site ODP758 in the Ninetyeast Ridge of the Indian Ocean. Based on these data, manifestations and related mechanisms of major tectonic and environmental events such as the rapid uplift of the Himalaya Mountains, “middle Pleistocene climatic transition” and “mid-Brunhes dissolution event” in the region are discussed. According to the analysis and comparison of various indices and changes in terms of foraminifera assemblage, paleotemperature, paleosalinity and themocline from site ODP758, the authors deduce that the paleoclimatic changes might correlate with the mid-Pleistocene transition at 1.4–1.7 Ma B.P. The changes of CaCO₃, mass accumulation rates (MAR) of CaCO₃ and non- CaCO₃ MAR indicate that the loaded terrigenous sediments increased at 1.7 Ma, which is in agreement with the uplift history of the Qinghai-Tibet plateau as shown by the available data. The last two changes coincide with the uplift of the Qinghai-Tibet plateau, hence they are called “Qinghai-Tibet movement” (1.7 Ma), and the “Kunlun-Yellow River movement” (1.2–0.6 Ma). The changes of the CaCO₃ content, coarse fraction (> 150 μm) content and planktonic foraminifera biostratigraphy show that strong dissolution of abyssal CaCO₃ occurred in the study region during 0.5–0.4 Ma. The event was consistent with the “mid-Brunhes dissolution event” in the sedimentary records of the Atlantic Ocean, Pacific Ocean, Indian Ocean and Nansha sea area of the South China Sea. __________ Translated from Geological Bulletin of China, 2007, 26(12): 1627–1632 [译自: 地质通报]     

Towards a nonperturbation transport theory in hetereogeneous aquifers

A large body of existing theories of flow and contaminant transport in aquifers ignore the presence of recharge, eliminate the boundary conditions, neglect transient conditions in groundwater flow, conceive hydraulic gradients as linear, and require parameter variability to be stationary and Gaussian. The most outstanding and difficult to justify assumption is the subjective small size of the stochastic terms (i.e., small perturbation methods), which usually is forced by considering the logarithm of the hydraulic conductivity. Several problems in flow and contaminant subsurface hydrology, such as the enhanced dispersion parameters with plume size or time after injection, remain to be observed in the light of a stochastic theory that allows a more realistic consideration of physical and hydrologic properties. In this article, an attempt is made to reformulate a contaminant transport equation (the variable dispersion equation, VDE) with transport parameters in terms of regional hydrologic and aquifer hydraulic properties, such as recharge rate, spatially random transmissivity, hydraulic gradient, aquifer thickness, and soil porosity. Subsequently, a general analytic procedure, the method of decomposition, is used to derive a solution to the VDE. This procedure does not require small perturbation, logarithmic transformations, or specific probability law assumptions. Comparison tests with existing theoretical and field results are given. The tests illustrate the enhanced dispersion and shifting concentration effects produced by the variable dispersion equation. Finally a generalization of the method to nonstationary dispersion in three-dimensional domains is proposed.     

Laboratory simulation of geogas microbubble flow

Preliminary laboratory tests provided first data on the behavior of gas microbubbles through porous media in the framework of the geogas theory. Under experimented conditions with laboratory equipment arranged for pressure controlled gas-tracer injection and sampling, gas microbubbles moved up to ten times faster than singlephase flow in dry media under the same injection pressure. Microbubbles were determined to be very sensitive to changes in injection pressure and their terminal velocity seems to be described with good approximation by the Stokes formula. The capability of microbubbles to pick up and transport upward for short distances solid ultra-small particles (metallic and radionuclide compounds) has been proved. Results are consistent with a time-dependent process linked to the transport properties of microbubbles (e.g., flotation), such as that reported by some authors.     

Trace metals in suspended particulate matter and in sediment trap material from a permanently anoxic fjord — Framvaren, South Norway

Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.     

ELECTROCHEMICAL MEASUREMENT OF STEEL CORROSION IN SEABOTTOM SEDIMENT WITH “MD” METHOD

The tbough one year cormsion potential and polarisation resistanoc for 3 kinds of stals in seabottomedment of Liaodong Bay were measured with the “MD” method.The measurements wiIl have some thoretical and pndital talues. The thooretical valoc lies in thatthe reoorded changing process of the practital corrosion case can be basis for indoor discussion andeectrochemical on the corrosion practical value lies in that the obtained datu canbe basis for designing and controlling elatrochemical protation syttems. In fact, it is very difficult tomeasure in situ the cornosion parnders of steeIs in sea sediment.     

About the specification of erosion flux for soft stratified cohesive sediments

The present paper deals with the specification of bed erosion flux that accounts for the effects of sediment-induced stratification in the water column. Owing to difficulties in measuring the bed shear stress _b and the erosive shear strength _s, we suggest a series of methods that combine laboratory and numerical experiments. A simplified turbulent transport model that includes these effects helps to quantify _b and _s. Focusing on soft stratified beds, the present study considers erosion rate formulas of the form =_f exp {[T_b-T_s]} where is a model constant (=1 for Gularte's (1978) formula and =1/2 for Parchure's (1984) formula). First, the bed erosive strength profile _s(Z) is adjusted by forcing the turbulent transport model with measured erosion rates. Second, three procedures are suggested to determine the erosion rate formula coefficients _f and : a global procedure and two different layer-by-layer procedures. Each procedure is applied to an erosion experiment conducted in a rotating annular flume by Villaret and Paulic (1986). The use of the layer-by-layer procedure based on a least squares fitting technique provides a closer fit than the global procedure. The present study points out the complementarity of experimental and numerical approaches and also suggests possible improvements in laboratory test procedures.     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.