湖泊疏浚堆场淤泥污染及潜在生态风险评价

疏浚淤泥内通常含有不同类型的有毒有害物质,在堆场直接堆放过程中可能会对周围环境产生有害影响.本文针对太湖及巢湖相应疏浚堆场内淤泥进行研究,探讨淤泥中重金属、多环芳烃以及多氯联苯等污染物含量及潜在生态风险;根据重金属的风险指数法和持久性有机污染物的风险商法,对各污染物的潜在生态风险进行定量分析.研究结果表明,太湖白旄堆场以及孔湾堆场淤泥内重金属及多环芳烃含量较小,潜在生态风险较低;巢湖南庄堆场淤泥内各类有害物质含量较大,种类较多,对于周围环境具有较高的潜在生态威胁.多氯联苯则在各个疏浚堆场淤泥中具有很高的积累量,潜在生态风险较高,应引起管理者的重视.     

太湖梅梁湾水土界面反硝化和厌氧氨氧化

运用无扰动芯样实验室内流动培养、稳定同位素示踪、同位紊气态产物测定及同位素配对技术,对太湖梅梁湾北部到南部的4个梯度样点的水土界面反硝化和厌氧氨氧化速率进行研究.结果表明,梅梁湾内及湾外开敞湖区4个样点的水土界面反硝化脱氮速率为(46.36±13.26)-(16.34±22,74)μmol/(m~2·h),厌氧氨氧化脱氮速率为(7.50±2.21)-(2.05±2.90)～mol/(m~2.b).梅梁湾北部河口区水土界面总脱氮能力明显高于梅梁湾南部及开敞湖区.通过对脱氮过程的进一步研究发现.北部脱氮过程主要以上覆水硝酸盐为底物的非耦合反硝化过程(D_w)为优势过程,而梅梁湾外开敞湖区则以沉积物硝化过程耦合控制的反硝化(D_n)为主.影响D_n、D_w在反硝化中比重的主要因素是沉积物溶氧侵蚀深度和上覆水NO_3~-.浓度的差异;梅梁湾厌氧氨氧化脱氮比例占总脱氮比例为12%-14%,湾外开敞湖区则占11%,影响其比例差异的主要因子是反硝化强度的大小及其反硝化中间产物--亚硝酸盐含量的差异.     

Adsorption of cobalt by using inorganic components of sediment samples from water bodies

The adsorption of cobalt ions was evaluated using sediment samples from water bodies to investigate the adsorption properties of sediment and the behavior of these natural materials in the presence of nuclear and industrial waste.The two sediments(S1 and S2)were treated to eliminate humic and fulvic acids and then they were characterized by several techniques.The minerals found in both the sediments(X-ray diffraction)were quartz and albite;plus,goethite and muscovite in S1,and kaolinite and montmorillonite in S2.Point of zero charge(PZC)of S1 and S2 was 6.00 and 5.22,respectively.The specific area of S1(63.3 m²/g)is higher than S2(1.5 m²/g).Adsorption kinetics data for S1 and S2 were best fitted to the pseudo second-order model.The removal efficiency of S1 for cobalt was 96%with an adsorption capacity(qe)of 0.93 mg/g,and for S2 was 45%with a qeof 0.40 mg/g.The experimental data of the adsorption isotherms were adjusted to Langmuir and Freundlich models for S1 and S2,respectively.The thermodynamic parameters(enthalpy,entropy,and Gibb’s free energy)indicated that the adsorption processes were endothermic,spontaneous,and chemisorption mechanism.The results show that the adsorption capacities of the sediments depend on their composition.These water sediments have important adsorption properties for cobalt,and they can be used in the treatment of nuclear and industrial aqueous wastes.     

水牛蹄型深海集矿机履齿设计及牵引性能研究

作为深海采矿系统的重要组成部分,深海集矿机的技术研究和开发一直是许多国家的难题。为了提高深海集矿机在稀软沉积物上的牵引性能,基于水牛蹄的曲面结构特征和特殊几何结构,设计了一款仿水牛蹄蹄型履齿。以该款履齿的结构参数为研究对象,通过对朗肯被动土压力理论的优化,得到了仿水牛蹄蹄型履齿的牵引力解析解,建立了对应的履齿仿生参数对履齿牵引力的影响公式。结合正交试验方法进行了不同形式履齿在沉积物上运动的单、多履齿剪切试验,将仿水牛蹄蹄型履齿与直型履齿、仿水牛蹄轮廓履齿（另一种仿生履齿）进行对比试验,并通过模型车试验验证了该款履齿的可行性。结果表明：3种履齿中,仿水牛蹄蹄型履齿提供的最大牵引力最高。研究可为进一步优化仿水牛蹄蹄型履齿结构参数和提高深海稀软底质机械的牵引性能提供参考依据。     

长江下游南漪湖沉积记录的全新世以来温度变化

了解全新世的温度变化能为理解目前日益突出的全球变暖、评估未来全球气候变化给出重要的参考。在这项研究中,基于长江下游南漪湖沉积岩芯深度为0~450cm中161个样品的brGDGTs代用指标,对过去12.0ka的大气温度进行重建,以进一步深化对全新世温度变化的理解。发现湖泊周边土壤与湖泊沉积物brGDGTs分子组成存在显著差异：土壤以brGDGTs-Ⅰ系列为主,占到总比重的80%以上,计算得的MBT'_5ME平均值为0.81;湖泊表层和柱状沉积物的brGDGTs分子组成更相似,其brGDGT-Ⅰ和brGDGT-Ⅱ分别为43%、48%和62%、35%,对应的MBT'_5ME平均值分别为0.44和0.62,因此认为湖泊沉积物brGDGTs主要为自生来源,进而选用基于MBT'_5ME的湖泊温度经验计算式进行古温度的重建。重建的南漪湖年均大气温度自12.0 ka B.P.以来变化范围为13.8~22.4℃,根据变化趋势,可以分为4个阶段：①阶段,早全新世（约12.0~8.2 ka B.P.）,温度变化范围为15.1~20.6℃,属低温阶段;②阶段,中全新世（约8.2~6.0 ka B.P.）,温度为16.8~20.0℃,为稳定高温阶段;③阶段,中晚全新世（约6.0~3.0 ka B.P.）,温度为13.8~19.4℃,快速降温阶段;④阶段,晚全新世（约3.0 ka B.P.以来）,温度在17.4~22.4℃,快速升温阶段。通过对比其他古气候记录,可以得到以下结论：长江下游地区在约12.0~8.2 ka B.P.时期温度变化主要受高纬度冰川残留的影响,为低温时期;在约8.2~6.0 ka B.P.时期的温度变化主要受到较强的太阳辐射量控制,属稳定高温期,对应全新世大暖期;约6.0 ka B.P.后,温度受到6.0~3.0 ka B.P.中低纬度冷事件以及上升温室气体辐射强迫共同影响,呈现先降后升的"V"型变化趋势。本研究表明长江下游地区自12.0 ka B.P.以来温度变化主要受全球温度变化控制,自晚全新世以来温室气体辐射强迫是影响其温度变化的主要因素。

     

黄土沉积物原生组分磁化率与风力的物质分选

本研究选取我国西北地区典型荒漠表土和黄土-古土壤序列样品为研究对象,探讨黄土沉积物及其潜在物源区表土的原生磁性矿物浓度在不同粒级间的变化规律、黄土剖面中粒度与磁化率的关系,以验证中国黄土沉积物中磁性组分在搬运过程中是否存在分选作用及其变化规律。来自西北地区表土的地质证据表明,磁性组分主要集中于>63 μm和31~63 μm粒径组分,并以后者的含量最高;与之相对应,黄土沉积中原生磁性组分主要集中于31~63 μm粒径组分,但>63 μm粒径组分不再是主要载磁组分,其磁性显著低于31~63 μm粒径组分。同时,多个剖面的证据表明黄土沉积的原生磁化率与31~63 μm粒径组分的含量是同相位变化的,进一步支持沉积物中原生组分的磁化率受到风动力的分选作用影响。需要强调的是,沉积物原生磁化率的主要载磁粒径组分为31~63 μm的颗粒物,而并非最粗粒组分。本研究结果暗示,相较于沉积物的全样粒度,干旱半干旱地区风成沉积的磁化率在指示古风场强度方面具有潜力。

     

天然气水合物储层岩心保压转移与测试进展

掌握天然气水合物储层基础物性演化特征对提升天然气水合物资源勘查与试采综合实力具有重要意义。目前,天然气水合物储层基础物性模拟实验和测试仍然以人工制备的天然气水合物岩心样品为主,导致测试结果和模拟实验认识与天然气水合物资源勘查试采工程需求仍有一定的差距,亟需原位准原位物性测试数据进行对比校正。天然气水合物储层保压取心及其后续岩心保压转移与测试是积累准原位物性测试数据的有力手段。聚焦天然气水合物储层保压取心之后的岩心保压转移与测试,全面综述了国内外现有的天然气水合物储层岩心保压转移与测试系统的优缺点,深入分析了天然气水合物储层岩心保压转移与测试获得的基础性认识;综述国内天然气水合物储层保压取心系统研发现状,梳理与之配套的岩心保压转移与测试系统研发现状及其面临的挑战;针对面临的挑战,为发展中国海域天然气水合物储层保压转移与测试技术装备研发自主能力提出了建议。     

天山北麓细土平原区冻结期包气带水分运移及其生态环境效应分析

依据昌吉均衡试验场负压计和地渗仪观测资料,用土壤水能量的观点,分析研究了天山北麓细土平原区冻结期包气带水分运移的规律及其与潜水的转移关系,并在此基础上,探讨了冻结期包气带水分运移的生态环境效应.     

Sediment transfer in an extremely low-gradient,low-relief and highly buffered system: Darwin Harbour catchment,northern Australia

Abstract

Sediment yields from and sediment transfer within catchments of very low relief and gradient, which make up about 50% of Earth’s surface, are poorly documented and their internal sediment dynamics are poorly known. Sediment sources, their proportionate contributions to valley floors and sediment yield, and storage are estimated using fallout radionuclides ²¹⁰Pb_(ex) and ¹³⁷Cs in the catchments that drain into Darwin Harbour, northern Australia, an example of this understudied catchment type that appears to be globally at the extreme end of this category of catchments. Unchannelled grassy valley floors (dambos, or seasonal wetlands) trap ～90% of the sediment delivered from hillslopes by sheet and rill erosion. Further down valley, small channels transport ～10% of the sediment that escapes from the dambos, and the remaining sediment comes from erosion of the channels. In this case, the fractional sediment storage is very high as a result of the existence of dambos, a landform that depends for its existence on low gradients.     

Development and Extension of An Aggregated Scale Model: Part 1 – Background to ASMITA

Whilst much attention has been given to models that describe wave, tide and sediment transport processes in sufficient detail to determine the local changes in bed level over a relatively detailed representation of the bathymetry, far less attention has been given to models that consider the problem at a much larger scale (e.g. that of geomorphological elements such as a tidal flat and tidal channel). Such aggregated or lumped models tend not to represent the processes in detail but rather capture the behaviour at the scale of interest. One such model developed using the concept of an equilibrium concentration is the Aggregated Scale Morphological Interaction between Tidal basin and Adjacent coast (ASMITA). In this paper we provide some new insights into the concepts of equilibrium, and horizontal and vertical exchange that are key components of this modelling approach. In a companion paper, we summarise a range of developments that have been undertaken to extend the original model concept, to illustrate the flexibility and power of the conceptual framework. However, adding detail progressively moves the model in the direction of the more detailed process-based models and we give some consideration to the boundary between the two.