湿地土壤和沉积物异化铁还原过程研究进展

异化铁还原是湿地土壤和沉积物中重要的生物地球化学过程,也是有机质矿化的主要途径之一。湿地干湿交替等过程会使土壤的氧化还原状态发生改变,影响铁元素及与其相关的元素的迁移和转化。总结了湿地土壤和沉积物中异化铁还原过程及其与碳、磷、硫等元素在生物地球化学循环关键过程中的相互作用,阐述了湿地土壤和沉积物中异化铁还原过程对微量金属元素迁移和转化的影响,分析了影响湿地土壤和沉积物异化铁还原过程的主要环境因子。未来相关研究应集中于湿地土壤和沉积物中异化铁还原微生物分析和纯化、不同有机质形式对异化铁还原过程的影响以及异化铁还原对土壤有机质矿化的贡献。     

Monitoring and modelling of hydrological processes in the semiarid region of Brazil: The Cariri experimental basins

Catchments have highly variable yields of runoff and soil erosion. The size, land use and the surface cover play a significant role and influence the catchment response and parameter values of simulation models. Two experimental basins—the Cariri basins—were equipped in a semi-arid region of Brazil, for obtaining runoff and sediment yield at different catchment scales, as well as, to evaluate the influence of the land use and surface cover. In the first basin, located in the municipality of Sumé, the field studies were carried out at two different scales: four micro-catchments with an area of around 0.5 ha and nine standard Wischmeier-type erosion plots of 100 m². The experimental units had varied vegetation and management. They were subjected only to natural rainfall events, and were monitored from 1982 to 1991. The total runoff and total sediment yield were determined for each of the events. The installations in the second basin, in the municipality of São João do Cariri, from 1999, include two erosion plots, three micro-catchments, and two sub-catchments of a small basin. These basins are still being monitored for runoff and sediment production. Among the micro-catchments two are nested to detect any scale effect at the micro-catchment level. Nearly 600 events of precipitation, that produced runoff in at least one of the experimental units, have been registered. These data have been used to evaluate the influence of various factors, including cultivation practices and to calibrate hydrological models for plots and micro-catchments. Parameters have been tested by means of cross validations among micro-catchments and sub-catchments. The data sets are made available to all the catchment hydrology researchers and others at https://doi.org/10.5281/zenodo.4690886 .     

Evaluation of a simple,inexpensive, in situ sampler for measuring time‐weighted average concentrations of suspended sediment in rivers and streams

The accurate measurement of suspended sediment (<200 μm) in aquatic environments is essential to understand and effectively manage changes to sediment, nutrient, and contaminant concentrations on both temporal and spatial scales. Commonly used sampling techniques for suspended sediment either lack the ability to accurately measure sediment concentration (e.g., passive sediment samplers) or are too expensive to deploy in sufficient number to provide landscape‐scale information (e.g., automated discrete samplers). Here, we evaluate a time‐integrated suspended sediment sampling technique, the pumped active suspended sediment (PASS) sampler, which collects a sample that can be used for the accurate measurement of time‐weighted average (TWA) suspended sediment concentration and sediment particle size distribution. The sampler was evaluated against an established passive time‐integrated suspended sediment sampling technique (i.e., Phillips sampler) and the standard discrete sampling method (i.e., manual discrete sampling). The PASS sampler collected a sample representative of TWA suspended sediment concentration and particle size distribution of a control sediment under laboratory conditions. Field application of the PASS sampler showed that it collected a representative TWA suspended sediment concentration and particle size distribution during high flow events in an urban stream. The particle size distribution of sediment collected by the PASS and Phillips samplers were comparable and the TWA suspended sediment concentration of the samples collected using the PASS and discrete sampling techniques agreed well, differing by only 4% and 6% for two different high flow events. We should note that the current configuration of the PASS sampler does not provide a flow‐weighted measurement and, therefore, is not suitable for the determination of sediment loads. The PASS sampler is a simple, inexpensive, and robust in situ sampling technique for the accurate measurement of TWA suspended sediment concentration and particle size distribution.     

Changes in run‐off and sediment load in the three parts of the Yellow River basin,in response to climate change and human activities

Hydrological regimes in the Yellow River have changed significantly because of climate change and intensive human interventions. These changes present severe challenges to water resource utilization and ecological development. Variation of run‐off, suspended sediment load (SSL), and eight precipitation indices (P1: 0–12 mm·day^?1, P12: 12–25 mm·day^?1, P25: 25–50 mm·day^?1, P50: P ≥ 50 mm·day^?1 and corresponding rainfall day: Pd1, Pd12, Pd25, Pd50 day year^?1) in three critical parts of the Yellow River basin (source region: SRYRB, upper reaches: URYRB, middle reaches: MRYRB) were investigated for the period from 1960 to 2015. The results show that run‐off and SSL significantly decreased (P < 0.01) in the URYRB and the MRYRB, whereas their decline in the SRYRB was insignificant (P > 0.05). Moreover, run‐off in the URYRB had one change point in 1987, and SSL in the URYRB as well as run‐off and SSL in the MRYRB had two change points (in the 1970s and the 1990s). Over the same period, only Pd1 and Pd12 in the SRYRB showed significant increasing trends, and an abrupt change appeared in 1981. The optimal precipitation indices for assessing the effects of precipitation on run‐off and SSL in the URYRB and MRYRB were Pd50 and P12, respectively. A double‐mass curve analysis showed that precipitation and human activities contributed to approximately 20% and 80% of the reduction in run‐off, respectively, for both the SRYRB and the MRYRB. However, the contribution rate of precipitation and human activities on SSL reduction was approximately 40% and 60% in the URYRB and 5% and 95% in the MRYRB, respectively. Human activities, primarily soil and water conservation measures and water extraction (diversion), were the main factors (>50%) that reduced the run‐off. However, the dominant driving factors for SSL reduction were soil and water conservation measures and reservoir interception, for which the contribution rate was higher than 70% in the MRYRB. This work strengthens the understanding of hydrological responses to precipitation change and provides a useful reference for regional water resource utilization.     

Estimating bed material fluxes upstream and downstream of a controlled large bifurcation - the Mississippi-Atchafalaya River diversion

Bed material transport at river bifurcations is crucial for channel stability and downstream geomorphic dynamics. However, measurements of bed material transport at bifurcations of large alluvial rivers are difficult to make, and standard estimates based on the assumption of proportional partitioning of flow and bedload transport at bifurcations may be erroneous. In this study, we employed a combined approach based on observed topographic change (erosion/deposition) and bed material transport predicted from a one-dimensional model to investigate bed material fluxes near the engineering-controlled Mississippi-Atchafalaya River diversion, which is of great importance to sediment distribution and delivery to Louisiana's coast. Yang's (1973) sediment transport equation was utilized to estimate daily bed material loads upstream, downstream, and through the diversion during 2004–2013. Bathymetric changes in these channels were assessed with single beam data collected in 2004 and 2013. Results show that over the study period, 24% of the Mississippi River flow was diverted into the Atchafalaya River, while the rest remained in the mainstem Mississippi. Upstream of the diversion, the bed material yield was predicted to be 201 million metric tons (MT), of which approximately 35 MT (i.e., 17%) passed through the bifurcation channel to the Atchafalaya River. The findings from this study reveal that in the mainstem Mississippi, the percentage of bed material diversion (83%) is larger than the percentage of flow diversion (76%); Conversely, the diversion channel receives a disproportionate amount of flow (24%) relative to bed material supply (17%). Consequently, severe bed scouring occurred in the controlled Outflow Channel to the Atchafalaya River, while riverbed aggradation progressed in the mainstem Mississippi downstream of the diversion structures, implying reduced flow capacity and potential risk of a high backwater during megafloods. The study demonstrates that Yang's sediment transport equation provides plausible results of bed material fluxes for a highly complicated large river diversion, and that integration of the sediment transport equation with observed morphological changes in riverbed is a valuable approach to investigate sediment dynamics at controlled river bifurcations.     

Characterization of suspended sediment in Meltwater from Glaciers of Garhwal Himalaya

Glacierised basins are significant sources of sediments generated by glacial retreat. Estimation of suspended sediment transfer from glacierised basins is very important in reservoir planning for hydropower projects in Himalaya. The present study indicates that storage and release of sediment in proglacial streams may categorise the pattern of suspended sediment transfer from these basins. Assessment of suspended sediment concentration (SSC), suspended sediment load (SSL) and yield has been undertaken for Dunagiri Glacier basin located in Garhwal Himalaya (30^o33'20”N, 79^o53'36”E), and its results are compared with the Gangotri and Dokriani glaciers sharing close proximity. Out of the total drainage basin area, about 14.3 % of the area is glacierised. Data were collected for five ablation seasons (1984–1989, barring 1986). The mean daily SSCs for July, August and September were 333.9, 286.0 and 147.15 mg/l, respectively, indicating highest concentration of mean daily suspended sediment in July followed by August. SSL trends were estimated to be 93.0, 57.0 and 21.3 tonnes. About 59% of the total SSL of the melt period was transported during the months of August and September. Sediment yield for the study basin was computed to be 296.3 t km^?2 yr ^?1. It is observed that the cumulative proportion of SSC precedes the discharge throughout the melt season except in the year 1987. Release of SSL in terms of total load is less in the early part of melt season than in the later stage as compared to that of discharge. Diurnal variations in SSC reach their maximum at 2400 h, and therefore, SSC was found to be high during night (2000–0400 h). There was a good relationship between SSC and SSL with discharge for the ablation seasons (1988 and 1989). Mean monthly SSC and mean monthly SSL provide a good exponentional relationship with mean monthly temperature. Copyright © 2012 John Wiley & Sons, Ltd.     

Energy flux partitioning and evapotranspiration in a sub‐alpine spruce forest ecosystem

In this study, we examined the year 2011 characteristics of energy flux partitioning and evapotranspiration of a sub‐alpine spruce forest underlain by permafrost on the Qinghai–Tibet Plateau (QPT). Energy balance closure on a half‐hourly basis was H + λE = 0.81 × (R_n ? G ? S) + 3.48 (W m^?2) (r² = 0.83, n = 14938), where H, λE, R_n, G and S are the sensible heat, latent heat, net radiation, soil heat and air‐column heat storage fluxes, respectively. Maximum H was higher than maximum λE, and H dominated the energy budget at midday during the whole year, even in summer time. However, the rainfall events significantly affected energy flux partitioning and evapotranspiration. The mean value of evaporative fraction (Λ = λE/(λE + H)) during the growth period on zero precipitation days and non‐zero precipitation days was 0.40 and 0.61, respectively. The mean daily evapotranspiration of this sub‐alpine forest during summer time was 2.56 mm day^?1. The annual evapotranspiration and sublimation was 417 ± 8 mm year^?1, which was very similar to the annual precipitation of 428 mm. Sublimation accounted for 7.1% (30 ± 2 mm year^?1) of annual evapotranspiration and sublimation, indicating that the sublimation is not negligible in the annual water balance in sub‐alpine forests on the QPT. The low values of the Priestley–Taylor coefficient (α) and the very low value of the decoupling coefficient (Ω) during most of the growing season suggested low soil water content and conservative water loss in this sub‐alpine forest. Copyright © 2013 John Wiley & Sons, Ltd.     

Using LM‐OSL of quartz to distinguish sediments derived from surface‐soil and channel erosion

This study describes the use of linearly modulated optically stimulated luminescence (LM‐OSL) to distinguish surface‐soil derived sediments from those derived from channel bank erosion. LM‐OSL signals from quartz extracted from 15 surface‐soil and five channel bank samples were analysed and compared to signals from samples collected from two downstream river sites. Discriminant analysis showed that the detrapping probabilities of fast, first slow and second slow components of the LM‐OSL signal can be used to differentiate between the samples collected from the channel bank and surface‐soil sources. We show that for each of these source end members these components are all normally distributed. These distributions are then used to estimate the relative contribution of surface‐soil derived and channel bank derived sediment to the river bed sediments. The results indicate that channel bank derived sediments dominate the sediment sources at both sites, with 90.1 ± 3% and 91.9 ± 1.9% contributions. These results are in agreement with a previous study which used measurements of ¹³⁷Cs and ²¹⁰Pb_ex fallout radionuclides to estimate the relative contribution from these two sources. This result shows that LM‐OSL may be a useful method, at least in the studied catchment, to estimate the relative contribution of surface soil and channel erosion to river sediments. However, further research in different settings is required to test the difference of OSL signals in distinguishing these sediment sources. And if generally acceptable, this technique may provide an alternative to the use of fallout radionuclides for source tracing. Copyright © 2015 John Wiley & Sons, Ltd.     

A method for evaluating the longitudinal functional connectivity of a river–lake–marsh system and its application in China

The longitudinal functional connectivity of a river–lake–marsh system (RLMS) refers to the actual water-mediated transport of material from upstream to downstream areas along a spatial gradient and is fundamental to understand hydrological and biogeochemical cycles. However, due to a lack of consensus on appropriate data and methods, the quantification of connectivity is still a challenge, especially at the catchment scale. We developed a new method to evaluate longitudinal functional connectivity based on fluxes of materials (water, sediment, and chemicals) along a RLMS. The calculation of fluxes is based on the longitudinal pattern of terrain gradient, which influences transport efficiency, and on contributions from hillslopes, which set the initial spatial template of material loading to the RLMS. We evaluate the contributions from hillslopes to RLMS based on a new modified version of the index of sediment connectivity (IC) proposed by Borselli et al. (2008) and revised by Chartin et al. (2017).We applied this method to the Baiyangdian Basin covering an area of 3.4 × 10⁴ km² in China and quantified longitudinal functional connectivity during normal, wet, and dry periods(April, July and December) in year 2016. We found that areas with good structural connectivity exhibited poor functional connectivity during the normal and dry periods. Modelling testing with discharge data from hydrological stations and measured chemicals from Baiyangdian Lake was satisfactory in test periods. We conclude that public data and Digital Elevation Model-derived information can be used to reliably map the longitudinal functional connectivity of RLMSs. The proposed method provides a useful tool for monitoring and restoring the longitudinal functional connectivity of RLMSs and our results indicate that efforts aimed at restoring functional connectivity in RLMSs should take into account landscape patterns that can greatly influence fluxes in the watershed.     

Hydraulics of overland flow influenced by litter incorporation under extreme rainfall

Water erosion on hillslopes is a worldwide environmental problem, which is a rainfall‐induced process, especially extreme rainfall. The great intensity of extreme rainfall strongly enhances the power of overland flow to detach soil and transport sediment. Plant litter is one of the most important constituents of ecosystems that often covers the soil surface and can be incorporated into topsoil. However, little attention has been paid to its effect on flow hydraulics owing to the veiled nature. This study aimed to examine the effects of incorporated litter on the hydraulic properties under extreme rainfall condition. To reach this goal, six litter rates of 0, 0.05, 0.10, 0.20, 0.35, and 0.50 kg m^?2 and four litter types collected from deciduous trees, coniferous trees, shrubs, and herbs were incorporated into topsoil. Then, simulated rainfall experiments were performed on five slope gradients (5°, 10°, 15°, 20°, and 25°) with an extreme rainfall intensity of 80 mm h^?1. The results showed that Froude number and flow velocity of the overland flow decreased, whereas flow resistance increased exponentially with litter incorporation rate. Litter type had an influence on flow hydraulics, which can mainly be attributed to the variations in surface coverage of the exposed litter and the litter morphology. Flow velocity and Darcy–Weisbach coefficient increased markedly with slope gradient. However, the variation of slope gradient did not modify the relationships between flow hydraulics and incorporated litter rate. The random roughness, resulting from heterogeneous erosion due to the uneven protection of surface exposed litter, increased linearly with litter incorporated rate. As rainfall proceeded, flow hydraulics varied with incorporated litter rate and slope gradient complicatedly due to the increases in flow rate and coverage of the exposed litter and the modification of soil surface roughness.