滇东-黔西地区晚二叠世煤岩及煤层气储层物性分析

本文以丰富的地质资料对滇东－黔西地区晚二叠世煤岩分布的割理（裂隙）,吸附、孔隙溶积、镜质组含量、含气性、灰分产率等进行了较为系统的研究,初步建立了煤炭与煤层气储层物性的关系,提出了镜质组含量的煤炭类型有较好的煤层气储集物性条件。     

Dual models of pore spaces

We present a model for pore spaces that consists of two parts related by duality: (1) a decomposition of an open polyhedral pore space into open contractible pore bodies separated by relatively open interfaces and (2) a pore network that is homotopy equivalent to the pore space. The dual model is unique and free of parameters, but it relies on regularity conditions for the pore space. We show how to approximate any pore space by the interior of a polyhedral complex such that the regularity conditions are fulfilled. Thus, we are able to calculate the dual model from synthetic porous media and images of real porous media. The pore bodies are unions of relatively open Delaunay cells with respect to the corners of the pore boundary, and the pore network consists of certain at most two-dimensional (2D) Voronoi cells with respect to the corners of the pore boundary. The pore network describes the neighborhood relations between the pore bodies. In particular, any relatively open 2D Delaunay face f separating two pore bodies has a unique (relatively open) dual network edge. In our model, f is a pore throat only if it is hit by its dual network edge. Thus, as opposed to widespread intuition, any pore throat is convex, and adjacent pore bodies are not necessarily separated by pore throats. Due to the duality between the pore network and the decomposition of the pore space into pore bodies it is straightforward to store the geometrical properties of the pore bodies [pore throats] as attributes of the dual network vertices [edges]. Such an attributed network is used to perform 2D drainage simulations. The results agree very well with those from a pore-morphology based modeling approach performed directly on the digital image of a porous medium. Contractibility of the pore bodies and homotopy equivalence of the pore space and the pore network is proven using discrete Morse theory and the nerve theorem from combinatorial topology.     

Use of high spectral resolution remote sensing to determine leaf palatability of eucalypt trees for folivorous marsupials

In this study we assess the feasibility of remotely measuring canopy biochemistry, and thus the potential for conducting large-scale mapping of habitat quality. A number of studies have found nutrient composition of eucalypt foliage to be a major determinant of the distribution of folivorous marsupials. More recently it has been demonstrated that a specific group of secondary plant chemicals, the diformylphloroglucinols (DFPs), are the most important feeding deterrents, and are thus vital determinants of habitat quality. We report on the use of laboratory spectroscopy to attempt to identify one such DFP, sideroxylonal-A, in the foliage of Eucalyptus melliodora, one of the few eucalypt species browsed by folivorous marsupials. Reflectance spectra were obtained for freeze-dried, ground leaves using near infrared spectroscopy (NIRS) and for both oven-dried and fresh whole leaves using a laboratory-based (FieldSpec) spectroradiometer. Modified partial least squares (MPLS) regression was used to develop calibration equations for sideroxylonal-A concentration based on the reflectance spectra transformed as both the first and second difference of absorbance (Log 1/R). The predictive ability of the calibration equations was assessed using the standard error of calibration statistic (SECV). Coefficients of determination (r²) were highest for the ground leaf spectra (0.98), followed by the fresh leaf and dry leaf spectra (0.94 and 0.87, respectively). When applied to independent validation sub-sets, sideroxylonal-A was most accurately predicted from the ground leaf spectra (r² = 0.94), followed by the dry leaf and fresh leaf spectra (0.72 and 0.53, respectively). Two spectral regions, centred on 674 nm and 1394 nm, were found to be highly correlated with sideroxylonal-A concentration for each of the three spectral data sets studied. Results from this study suggest that calibration equations derived from modified partial least squares regression may be used to predict sideroxylonal-A concentration, and hence leaf palatability, of Eucalyptus melliodora trees, thereby indicating that the remote estimation of habitat quality of eucalypt forests for marsupial folivores is feasible.     

A model of the early evolution of karst aquifers in limestone in the dimensions of length and depth

A new model of the early evolution of limestone karst aquifers in the dimensions of length and depth is presented. In its initial state the aquifer consists of a rock massive with evenly spaced fractures of about 50 μm aperture widths with an hydraulic conductivity of 10⁻⁷ ms⁻¹. In addition to this a coarser network of prominent fractures with aperture widths of several 100 μm is also present. Boundary conditions of constant recharge 450 mm/year, or constant head from the input of allogenic streams are imposed. First the position of the water table in the aquifer is calculated, then dissolutional widening during a time step in all the fractures below the water table is found by use of the well-known nonlinear dissolution kinetics of limestone. This is iterated and the position of the water table as well as the fracture widths are found as a function of time. In the case of constant recharge to a karst plateau, the water table in any case drops to base level and conduits there propagate from the spring headwards. If constant head conditions are valid the position of the water table remains almost stable and conduits propagate along the water table from the input towards the spring. There is competition between conduit evolution along prominent fractures and along tight fissures close to the water table. In any case under constant head conditions one of these pathways wins, and early karst evolution is terminated by a breakthrough event with an explosive increase of the flow through the aquifer until constant head conditions break down. Depending on the boundary conditions of constant head or constant recharge or a combination of both it is possible to describe models of cave genesis, which have been derived from field evidence, such as the water table models of Swinnerton and Rhoades as well as the four-state model by Ford and Ewers (Can. J. Earth Sci., 15 (1978) 1783).     

东营凹陷下第三系深部碎屑岩储层次生孔隙垂向分布及成因分析

东营凹陷下第三系埋深大于 30 0 0 m的深部碎屑岩储层普遍发育 2～ 4个次生孔隙带 ,Φ=10 %～ 30 % ,K=0 .1× 10 - 3μm2～ 30× 10 - 3μm2 ,为中孔低渗低孔低渗油气储层。综合有机质热演化过程、成岩作用和构造断裂等分析 ,认为东营凹陷埋深大于 30 0 0m碎屑岩地层中 ,第一、二个次生孔隙带埋深在 30 0 0 m～ 390 0 m之间 ,其形成主要与有机质成熟过程释放有机酸对长石等颗粒的溶解有密切关系 ,在深大断裂附近储层同时受到大气淡水的影响 ,而深陷带包裹于暗色泥岩中的浊积砂岩的次生孔隙发育情况还与泥质岩异常压力带有关 ;第三个次生孔隙带埋深一般为 390 0 m～ 430 0 m,主要成因于粘土矿物转化造成的还原环境 ,同时受到硫酸盐热化学氧化还原反应的影响。这三个次生孔隙发育带对储集油气有效。第四个孔隙发育带埋深在 470 0 m以下 ,主要是构造成因的微裂缝 ,较难成为有效的油气储层。     

pH值对长石溶解度及次生孔隙发育的影响

本文从长石溶解反应的机理及各离子形态在溶液中分布的热力学角度出发 ,论述了pH值对三个长石端员及高岭石在流体中溶解度的影响。在此基础上 ,进一步探讨了流体酸碱度对长石向高岭石转化和次生孔隙发育程度的制约 ,并提出了衡量次生孔隙发育程度的参数———转化系数D。     

梅雨锋生次级环流对暴雨的作用

本文采用了MM4中尺度数值模式对1991年7月5日08时至6日20时发生在江淮流域的梅雨锋暴雨过程进行了模拟。在模拟较理想的基础上，利用模式输出的高分辨率的动力协调资料，就暴雨过程中锋生次级环流各强迫项对暴雨的作用进行了诊断研究。结果表明：锋生次级环流对暴雨形成具有重要的作用，但在暴雨过程不同时期各项的作用差异很大。     

Differential diatom dissolution in Late Quaternary sediments from Lake Manyara,Tanzania: an experimental approach

Diatom dissolution in saline lakes represents an important obstacle to the quantitative reconstruction of water chemistry and climate from lake sediment archives. This problem is here approached experimentally by artificially dissolving diatom-bearing core sediment from Lake Manyara, Tanzania. Manyara holds one of the longest continuous palaeolimnological records from tropical Africa although its interpretation is based on a fragmentary diatom record due to frustule dissolution. These experiments have revealed clear changes in assemblage composition as dissolution operated differentially with respect to diatom taxa. Differential dissolution has considerable impact on the water chemistry estimates derived from transfer functions. Taphonomy, rather than environmental change, may have been responsible for minor fluctuations in the diatom assemblages from Manyara, although major palaeohydrological changes during the Late Pleistocene and Early Holocene can be identified. Particularly well represented by MANE-87 is a period of intermediate lake level between 27 500 and 23 000 ¹⁴C yr BP which has regional palaeohydrological significance.