NaCl 溶液闪蒸效率特性数值研究

盐水闪蒸技术广泛应用于海水淡化及海洋温差能发电,含盐质量分数、给盐液温度和闪蒸压力对闪蒸汽化率和热效率有很大影响。在质量分数为3.5%～20%、给盐液温度为30～95℃和闪蒸压力为1～30 kPa的范围内,对NaCl溶液闪蒸汽化率和热效率等闪蒸效率特性进行了定量计算研究,研究得到了盐水含盐质量分数、给盐液温度和闪蒸压力对闪蒸汽化率以及热效率影响的规律。结果表明,降低含盐质量分数,提高给盐液温度,降低闪蒸压力可提高闪蒸汽化率与热效率;含盐质量分数越高,造成的热损失越大,而提高给盐液温度会增大热损失。     

New interpretation of the Franciscan mélange at San Simeon coast,California: tectonic intrusion into an accretionary prism

Many concepts and interpretations on the formation of the Franciscan mélange have been proposed on the basis of exposures at San Simeon, California. In this paper, we show the distribution of chaotic rocks, their internal structures and textures, and the interrelationship between the chaotic rocks and the surrounding sandstones (turbidites). Mélange components, particularly blueschists, oceanic rocks, including greenstone, pillow lava, bedded chert, limestone, sandstone, and conglomerate, have all been brecciated by retrograde deformation. The Cambria Slab, long interpreted as a trench slope basin, is also strongly deformed by fluidization, brecciation, isoclinal folding, and thrusting, leading us to a new interpretation that turbiditic rocks (including the Cambria Slab) represent trench deposits rather than slope basin sediments. These rocks form an accretionary prism above mélanges that were diapirically emplaced into these rocks first along sinistral-thrust faults, and then along dextral-normal faults. Riedel shear systems are observed in several orders of scale in both stages. Although the exhumation of the blueschist blocks is still controversial, the common extensional fractures and brecciation in most of the blocks in the mélanges and further mixture of various lithologies into one block with mélange muddy matrix indicate that once deeply buried blocks were exhumed from considerable depths to the accretionary prism body, before being diapirically intruded with their host mélange along thrust and normal faults, during which retrograde deformation occurred together with retrograde metamorphism. Recent similar examples of high-pressure rock exhumation have been documented along the Sofugan Tectonic Line in the Izu forearc areas, in the Mineoka belt in the Boso Peninsula, and as part of accretionary prism development in the Nankai and Sagami troughs of Japan. These modern analogues provide actively forming examples of the lithological and deformational features that characterize the Franciscan mélange processes.     

台湾屏东县东港溪拦溪对其周边地下水水质及水产养殖的影响

为了解设于屏东县新园乡界河以东港溪上的拦河堰对当地地下水的影响进行一系列研究.首先对台湾西南沿海的屏东县新园乡1989年10月东港溪拦溪建堰前后地下水水质及等水位线数据进行了分析,同时逐月收集东港溪拦溪堰周边的佳冬乡养殖池所用的井水、池水、浮游生物、日本鳗鲡(Anguilla japonica)及虾等数据,进行分析与比较.此外,用以上2个乡的地下水进行了鳗鲡幼苗水族箱养殖试验,并检验分析试验后的鳗鱼.各项分析结果表明,拦溪堰的兴建使新园乡的地下水水位降低,附近污染河川的水渗入了地下,对养殖生物的健康产生不同程度的影响.因此建议,在旱季应减少对东港溪拦溪堰水的抽取量;台湾西部尤其是新园乡的水产养殖活动应予以减少.     

海水海砂混凝土双K断裂参数的确定

采用尺寸为515 mm×100 mm×100 mm初始缝高比从0.1变化至0.8的三点弯曲梁试件,利用试验测得起裂荷载Pini、最大荷载Pmax及对应的裂缝口张开位移CMODc等参数,研究了缝高比a0/h对海水海砂混凝土双K断裂参数的影响。并以相同配合比的淡水河砂梁作为对照组,进一步研究了海砂海水混凝土双K断裂参数与普通混凝土之间的关系。结果发现海水海砂混凝土断裂参数在a0/h=0.25～0.7范围内时可以认为是一常数;海水海砂混凝土梁断裂参数比相同配合比情况下的淡水河砂梁大且对边界影响更加敏感。     

基于ETOPO1数据的全球及重点海域水深统计与分析

由于不同的水深探测手段及海深反演方法适用于不同深度的海域,且全球海域水深分布不均,因此在探测及反演海深之前,需对目标海域的水深分布有一定认识。本文采用ETOPO1模型对全球及部分海域进行统计分析,结果表明,全球及大西洋、印度洋、太平洋区域的水深大多处于3 000—10 000 m,其中3 000—5 000 m水深海域占比较大,因此,在这些海域主要采用重力数据结合船测数据进行反演,同时应注意避开海岸带、岛屿较多、海脊存在的区域;对于水深小于1 000 m的海域,可以根据外部环境,采用多波束船测、水深遥感、机载激光测深等方式进行探测。通过分析及统计全球和重点海域的水深可以为海深探测及海底地形反演方法的选取提供参考。     

西秦岭熊山沟岩体地球化学及构造环境分析

在区域地质调查及综合研究的基础上,对位于西秦岭天水东南部地区的原百花岩体进行了详细的岩石学、岩石地球化学、岩体接触关系、同位素年龄研究,从中解体出熊山沟岩体,并初步了解了该岩体的岩浆活动规律。熊山沟岩体早期岩石类型为斜长花岗岩,岩石化学成分K2O含量较低,K2O∕Na2O比值为0.33～0.42;晚期岩石类型为二长花岗岩,岩石相对富集K2O,K2O∕Na2O比值为1.01～1.43,岩石属拉斑-钙碱性系列;微量元素富集Th、Hf、Nb、Zr等元素;稀土元素以富集轻稀土,无铕负异常或铕负异常不明显为主要特征;氧同位素值较低（δ^18O为＋3.32‰）,岩石具Ⅰ型花岗岩的特征,岩浆来源于下地壳物质,形成于大陆弧构造环境。     

辽宁五龙地区中生代火成岩成因及其找矿意义

辽宁五龙金矿是辽东地区大型岩浆热液型矿床之一,成矿作用主要与中生代火成岩有关,为了进一步理清五龙地区中生代火成岩成因,本文对五龙金矿区大量花岗斑岩脉、闪长岩脉、三股流岩体和其中的各类脉岩进行了单颗粒锆石LA-ICPMS U-Pb测年和岩石主、微量元素地球化学研究。结果表明,五龙地区岩浆岩形成时代主要有晚侏罗世和早白垩世,矿区内近南北向展布的花岗斑岩脉形成于晚侏罗世（154.3±0.9~155.6±1.1 Ma）,指示矿区在晚侏罗世受到区域最大主应力方向为近南北向;三股流岩体成岩最新年龄（116.8±0.8~117.3±0.7 Ma）基本位于前人报道的年龄范围（111~129 Ma）;地球化学数据表明各类岩浆岩属于高钾钙碱性—钾玄岩系列,具有相同源区特征,形成于活动大陆边缘俯冲伸展环境下的弧岩浆,并且具有壳幔混合及进一步演化特征;结合不同深度标高成矿元素丰度特征,指示闪长岩与成矿作用密切相关,并且越往深部成矿潜力越大,对该地区找矿预测具有重要指导意义。     

北京房山岩体形成过程中的岩浆混合作用证据

北京房山侵入岩体主要由石英二长闪长岩单元和三种不同结构的花岗闪长岩单元组成,岩体中广泛分布的镁铁质微粒包体、富集暗色矿物的线状条带以及各岩相单元的非渐变接触关系等宏观特征,指示岩体的形成与岩浆混合作用有密切联系。122个斜长石成分剖面电子探针分析表明,它们众数成分为 An=29的更长石。但是,其成分变化范围极宽(An=14～56),晶体内不同部位的成分有很大差别,出现正常环带的 An 值较低(14～42),内环带的 An 值较高(24～56)的特殊情况,指示斜长石结晶环境的改变,暗示具有富钙基性岩浆的加入。从岩体边部到中心,斜长石 An 牌号逐渐降低,但相邻岩相单元之间有较大的重叠,表明不同岩石单元中的斜长石成分主要受控于岩浆成分的变化,与分离结晶作用无关。斜长石的韵律性环带、特别是内环带的发育则是岩浆混合作用机制的有力证据。基性岩浆的反复注入不仅改变寄主岩浆的成分,而且也控制了它的温度、定位机制和岩石的结构特征。因此,房山岩体的形成过程还包含了镁铁质岩浆多次注入的历史,并且从外到里基性岩浆的作用逐渐减弱。     

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.     

太行山南段符山高镁闪长岩的成因 —— 拆沉陆壳物质熔融的熔体与地幔橄榄岩反应的结果

本文对太行山南段符山高镁闪长岩进行了年代学与地球化学研究,结合其中地幔橄榄岩包体的研究,对符山高镁闪长岩的成因和中生代岩石圈地幔的性质进行了探讨.研究表明,符山闪长岩体是由一套含橄榄石角闪闪长岩-角闪闪长岩-闪长岩构成.含橄榄岩包体的寄主岩--角闪闪长岩中的锆石可划分为两种:一是代表寄主岩浆结晶的锆石:内部结构均匀、呈条带状吸收、自形-半自形晶形,具有较高的Th/U比值(1.10～4.08),其206Pb/238U年龄介于123～128Ma之间,12个点的加权平均值为125±1Ma,这表明岩体的形成时代为早白垩世;二是捕获或继承锆石:具有核边结构、吸收程度不均匀、呈浑圆状和自形-半自形两种,它们的Th/U比值介于0.32～2.03之间,构成了3组207Pb/206Pb加权平均年龄:2503±11Ma、2181±26Ma和1778±36Ma.该类岩石的SiO2和MgO含量分别介于56.69%～59.21%和3.60%～6.33%之间;且以高:Mg#(0.51～0.64)、富Na(Na2O/K2O大于1)、高Cr(93.1×10-6～420×10-6)、Ni(35.1×10-6～137×10-6)为特征.该类岩石强烈富集轻稀土元素和大离子亲石元素、明显亏损高场强元素,(87Sr/86Sr)I、εNd(t)值和(206Pb/204Pb)I分别变化于0.70581～0.70641、-8.30～-16.56和17.052～17.512之间.综合上述特征,同时结合地幔橄榄岩包体的特征和古元古代捕获锆石的大量存在,认为符山高镁闪长岩的原始岩浆起源于拆沉陆壳物质的部分熔融,其后经历了与地幔橄榄岩的反应过程.