对二郎坪群火神庙组物质组成的质疑与再认识

经研究证明，前人建立的二郎坪群火神庙组确有少量的亚碱性双峰式火山岩。这些火山岩零星地分布在几个地区，走向不连续，出露宽度一般为数百米。构成该组主体的是一条规模宏伟的侵入岩带，其岩石组合为辉长岩－闪长岩－石英闪长岩－斜长花岗岩－花岗岩，总体上表现为正序岩浆演化序列。这些侵入岩普遍经历了三个阶段的变形变质作用，即第一阶段为韧性变形；第二阶段为静态重结晶；第三阶段为带状褶劈理，表现了复杂而漫长的构造演化史。     

Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.     

高挂山—牛头寨地区小型环形影象构造分析及其找矿意义

高挂山—牛头寨地区,通过大比例尺航片解译,发现6个大小不等的小型环形影象信息。这些环形影象与岩浆活动、已知矿床、矿化点、重砂异常、物化探异常等的分布有着内在的联系。为预测找矿远景区和找隐伏矿床提供了影象依据。     

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.     

细基江篱繁枝变种在不同水层中的栽培试验

本文报道了为改变我国华南沿海目前在半咸淡水塘中进行地播式裁培细基江篱繁枝变种单产低的状况而进行的不同水层夹苗栽培和施肥增产试验,证明了越靠近水面江篱藻体生长越快,越接近底部藻钵生长越差,提出如果在水塘中单纯裁培江篱则水塘深度应保持20～30厘米,如果水深超过1米以上,则应采用浮筏式夹苗栽培,并在水中混养鱼虾等。浸泡施肥试验证明,在短短的40天裁培过程施肥藻体比不施肥藻体增产23％,说明了施肥的重要性。     

Optimal and sustainable extraction of groundwater in coastal aquifers

Four examples are investigated for the optimal and sustainable extraction of groundwater from a coastal aquifer under the threat of seawater intrusion. The objectives and constraints of these management scenarios include maximizing the total volume of water pumped, maximizing the profit of selling water, minimizing the operational and water treatment costs, minimizing the salt concentration of the pumped water, and controlling the drawdown limits. The physical model is based on the density-dependent advective-dispersive solute transport model. Genetic algorithm is used as the optimization tool. The models are tested on a hypothetical confined aquifer with four pumping wells located at various depths. These solutions establish the feasibility of simulating various management scenarios under complex three-dimensional flow and transport processes in coastal aquifers for the optimal and sustainable use of groundwater.     

Geometry and growth of sill complexes: insights using 3D seismic from the North Rockall Trough

Doleritic sill complexes, which are an important component of volcanic continental margins, can be imaged using 3D seismic reflection data. This allows unprecedented access to the complete 3D geometry of the bodies and an opportunity to test classic sill emplacement models. The doleritic sills associated with basaltic volcanism in the North Rockall Trough occur in two forms. Radially symmetrical sill complexes consist of a saucer-like inner sill at the base with an arcuate inclined sheet connecting it to a gently inclined, commonly ragged, outer rim. Bilaterally symmetrical sill complexes are sourced by magma diverted from a magma conduit feeding an overlying volcano. With an elongate, concave upwards, trough-like geometry bilaterally symmetrical sills climb away from the magma source from which they originate. Both sill complex types can appear as isolated bodies but commonly occur in close proximity and consequently merge, producing hybrid sill complexes. Radial sill complexes consist of a series of radiating primary flow units. With dimensions up to 3 km, each primary flow unit rises from the inner saucer and is fed by primary magma tube. Primary flow units contain secondary flow units with dimensions up to 2 km, each being fed by a secondary magma tube branching from the primary magma tube. Secondary flow units in turn are composed of 100-m scale tertiary flow units. A similar branching hierarchy of flow units can also be seen in bilaterally symmetrical sill complexes, with their internal architecture resembling an enlarged version of a primary flow unit from a radial sill complex. This branching flow pattern, as well as the interaction between flow units of varying orders, provides new insights into the origin of the structures commonly seen within sill complexes and the hybrid sill bodies produced by their merger. The data demonstrate that each radially symmetrical sill complex is independently fed from a source located beneath the centre of the inner saucer, grows by climbing from the centre outwards and that peripheral dyking from the upper surface is a common feature. These features suggest a laccolith emplacement style involving peripheral fracturing and dyking during inner saucer growth and thickening. The branching hierarchy of flow units within bilaterally symmetrical sill complexes is broadly similar to that of primary flow units within a radially symmetrical sill complex, suggesting that the general features of the laccolith emplacement model also apply.Editorial responsibility: J. Stix     

Petrology and structure of the Palaeoproterozoic (1.9 Ga) Rytky nickel sulphide deposit,Central Finland: a comparison with the Kotalahti nickel deposit

The Palaeoproterozoic (1.9 Ga) Rytky and Kotalahti mafic-ultramafic intrusions are located in the contact zone between the Archaean craton and Proterozoic supracrustal rocks. During the second deformation event (D₂) the surrounding country rocks were subjected to intensive metamorphism and deformation associated with the Svecofennian orogeny; the Archaean/Proterozoic boundary controlled both D₂ thrusting and magma ascent. Emplacement of the Rytky and Kotalahti intrusions took place at the culmination of D₂, as shown by the gneiss inclusions with S₂ schistosity within the intrusions. Overthrusting continued after emplacement, with detached fragments of the bodies incorporated into the Archaean gneisses. During the third deformation event (D₃) the originally subhorizontal intrusions were rotated into a subvertical position, so that they now have their stratigraphic top towards the west. The Rytky intrusion is composed mainly of medium- and coarse-grained lherzolite, websterite and gabbronorite. The nickel deposit with pentlandite as the main nickel mineral is associated with the lherzolite and websterite. The coarse-grained lherzolite, websterite and melagabbro represent the first rocks to form, and they contain the nickel sulphide mineralisation. Country rock contamination, as indicated by high TiO₂, P₂O₅, Rb, Zr and light rare earth element contents (LREE), is most pronounced in the marginal part of the intrusion, which was the first to form. The variation in olivine composition (Fo 78.6-84.77 mole %; Ni 630–2386 ppm) and the metal ratio of the sulphide (Ni/Co 19.3 – 50.3) along with the internal stratigraphy of the intrusion indicate an in-situ process of sulphide ore formation.Editorial handling: P. LightfootAn erratum to this article can be found at     

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater

In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode.     

Observations and modelling of the travel time delay and leading negative phase of the 16 September 2015 Illapel,Chile tsunami

The systematic discrepancies in both tsunami arrival time and leading negative phase (LNP) were identified for the recent transoceanic tsunami on 16 September 2015 in Illapel, Chile by examining the wave characteristics from the tsunami records at 21 Deep-ocean Assessment and Reporting of Tsunami (DART) sites and 29 coastal tide gauge stations. The results revealed systematic travel time delay of as much as 22 min (approximately 1.7％ of the total travel time) relative to the simulated long waves from the 2015 Chilean tsunami. The delay discrepancy was found to increase with travel time. It was difficult to identify the LNP from the near-shore observation system due to the strong background noise, but the initial negative phase feature became more obvious as the tsunami propagated away from the source area in the deep ocean. We determined that the LNP for the Chilean tsunami had an average duration of 33 min, which was close to the dominant period of the tsunami source. Most of the amplitude ratios to the first elevation phase were approximately 40％, with the largest equivalent to the first positive phase amplitude. We performed numerical analyses by applying the corrected long wave model, which accounted for the effects of seawater density stratification due to compressibility, self-attraction and loading (SAL) of the earth, and wave dispersion compared with observed tsunami waveforms. We attempted to accurately calculate the arrival time and LNP, and to understand how much of a role the physical mechanism played in the discrepancies for the moderate transoceanic tsunami event. The mainly focus of the study is to quantitatively evaluate the contribution of each secondary physical effect to the systematic discrepancies using the corrected shallow water model. Taking all of these effects into consideration, our results demonstrated good agreement between the observed and simulated waveforms. We can conclude that the corrected shallow water model can reduce the tsunami propagation speed and reproduce the LNP, which is observed for tsunamis that have propagated over long distances frequently. The travel time delay between the observed and corrected simulated waveforms is reduced to <8 min and the amplitude discrepancy between them was also markedly diminished. The incorporated effects amounted to approximately 78％ of the travel time delay correction, with seawater density stratification, SAL, and Boussinesq dispersion contributing approximately 39％, 21％, and 18％, respectively. The simulated results showed that the elastic loading and Boussinesq dispersion not only affected travel time but also changed the simulated waveforms for this event. In contrast, the seawater stratification only reduced the tsunami speed, whereas the earth's elasticity loading was responsible for LNP due to the depression of the seafloor surrounding additional tsunami loading at far-field stations. This study revealed that the traditional shallow water model has inherent defects in estimating tsunami arrival, and the leading negative phase of a tsunami is a typical recognizable feature of a moderately strong transoceanic tsunami. These results also support previous theory and can help to explain the observed discrepancies.