Assessing seawater quality with a variable fuzzy recognition model

With the rapid development of the marine economy industry, human exploitation of marine resources is increasing, which is contributing to the growing trend of eutrophication and frequent occurrence of red tide. Accordingly, investigations of seawater quality have attracted a great deal of attention. This study was conducted to construct a seawater environmental quality assessment model based on the variable fuzzy recognition model. The uncertainty and ambiguity of the seawater quality assessment were then considered, combining the monitoring values of evaluation indicators with the standard values of seawater quality. Laizhou Bay was subsequently selected for a case study. In this study, the correct variable model for different parameters was obtained according to the linear and nonlinear features of evaluation objects. Application of the variable fuzzy recognition model for Laizhou Bay, water quality evaluation and comparison with performance obtained using other approaches revealed that the generated model is more reliable than traditional methods, can more reasonably determine the water quality of various samples, and is more suitable for evaluation of a multi-index, multi-level, nonlinear marine environment system; accordingly, the generated model will be an effective tool for seawater quality evaluation.     

Measurement of trace nitrate concentrations in seawater by ion chromatography with valve switching

An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity （R〉0,99） in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability （RSD〈5%, n=6）. The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater.     

Marine bacterium strain screening and pyrethroid insecticide-degrading efficiency analysis

A pyrethroid insecticide-degrading bacterium, strain HS-24, was isolated from an offshore seawater environment. The strain, which can degrade cypermethrin(CYP) and deltamethrin(DEL), was identified as Methylophaga sp. The optimal culture and degradation conditions for CYP and DEL by strain HS-24 is pH 7 at 28°C. Under optimum culture conditions, strain HS-24 exhibited a broad degradation concentration range of 100, 200, 400, 600, and 800 mg/L for CYP and DEL. The metabolic intermediates were analyzed by NMR, which provided strong evidence that CYP and DEL removal occurred mainly because of a biological process. The toxicity of the degradation products of strain HS-24 was studied simultaneously by measuring the light output of the luminescence bacterium. This demonstrated that the biodegradation ability of strain HS-24 significantly decreased the toxicity of CYP- and DEL-contaminated aquaculture seawater. Finally, the findings of this paper indicate that strain HS-24 is thus revealed as a biological agent for the remediation of marine aquatic environments.     

基于PCA和LOGIT模型的网络入侵检测方法

针对高维度网络数据进行多类攻击行为检测的需求,提出一种基于PCA和Logit模型的网络入侵检测方法,通过PCA对网络数据降维、简化数据集和多项式Logit模型实现对不同攻击行为的识别并判别其类型。实验结果表明,方法在网络入侵识别上具有较理想的效果。     

基于指标规范值的海水水质评价的SVR模型

为了建立具有普适通用的海水水质评价的支持向量机模型,在设置各指标参照值和指标规范变换式,并对指标进行规范变换的基础上,应用免疫进化优化算法,建立基于指标规范值的海水水质评价的回归支持向量机模型。将优化好的模型用于珠江口海水水质的评价,其评价结果与BP神经网络的评价结果基本一致,从而表明基于指标规范值的支持向量机模型用于海水水质评价是可行的,且该模型较传统的支持向量机评价模型具有较好的普适性和通用性。     

Research on the critical conditions for clay particle release during saline aquifer freshening process

Water sensitivity phenomenon occurs during saline aquifer freshening process in seawater intrusion area, and clay particles released in the phenomenon can damage the infiltration capacity of the aquifer. In order to find out the factors and mechanisms for clay particle release, laboratory column infiltration experiments simulating saline aquifer freshening process were designed to measure the critical conditions(critical flow velocity, critical salt concentration and critical ionic strength) and force analysis for clay particle according to DLVO electric double layer theory was employed to illustrate the mechanisms for particle release. The research results showed that critical flow velocity for clay particle release is influenced by salt concentration of injecting solution. When salt concentration of injecting solution is very high, clay particles are not released, indicating that there does not exist a critical flow velocity in this situation. As salt concentration of injecting solution decreases, particles start to be released. The critical salt concentration for clay particle release is 0.052 mol L-1 in our work, which was determined by a constant-flux experiment for stepwise displacement of high concentration Na Cl solution. The critical ionic strength for clay particle release decreases as Ca2+ molar content percentage of the mixed solution of Na Cl and Ca Cl2 increases following the first-order exponential decay equation y = 0.0391e-0.266 x + 0.0015.     

Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.     

基于非均匀水体对比度传输方程的海水透明度计算试验

针对均匀水体假设的海水透明度经验计算公式不具有普适性的缺点,将海水在垂直方向上分为若干光学性质相近的均匀层,推导出非均匀水体中目标对比度传输方程,在此基础上,建立了海水透明度的计算模型。利用BROKE_WEST_ACS实测的海水固有光学性质数据和透明度盘观测数据,对计算模型进行了数值试验和效果分析。结果表明:模型计算值与透明度盘实测值平均相对误差为9.1%;该模型既克服了透明度盘测量易受天气状况和人眼差异影响较大的缺点,又突破了均匀水体透明度计算方法的局限性。     

长江口北支异常强盐水入侵观测与分析

长江口北支由于径流分流比很小,盐水入侵较强,特别是枯季大潮期盐水甚至倒灌进入南支,影响上海市和江苏省的水源地水质。为了进一步研究北支盐水入侵的规律及影响因素,2014年1月1-9日在北支进行了大小潮同步水文观测。本次观测到了北支异常强盐水入侵:小潮期发生强盐水入侵,且强度大于大潮期。小潮期强盐水入侵导致中下游河段被高浓度盐水控制,盐度从下游B01到中游B02几乎没有变化,且盐度的涨落潮变化几乎消失。分析认为,小潮观测期间长江入河口流量较小、河口潮差不是太小,加上强偏北风,三者的叠加是导致强盐水入侵的主要原因。     

甘肃北山勒巴泉南一带新元古代变质侵入岩的地质地球化学特征及成因探讨

在甘肃北山勒巴泉一带赋存一套变质侵入岩。岩性主要为闪长质片麻岩、石英闪长质片麻岩、英云闪长质片麻岩、花岗闪长质片麻岩及二长花岗质片麻岩。Rb-Sr全岩等时线定年获得似斑状中细粒花岗闪长质片麻岩年龄值727±50Ma,锆石Pb-Pb定年获得中细粒花岗闪长质片麻岩年龄值766±49Ma,结合其与围岩的接触关系及强变形变质特征,形成时代为南华纪中晚期。其岩石地球化学特点为:岩石A12O3CaO+Na2O+K2O,A/CNK=1.30~1.38,属过铝质类型;σ=2.08~3.78,NK/A=0.32~0.61,属钙碱性系列。在微量元素组成上,富集LREE和大离子亲石元素(LILE),而亏损HREE、高场强元素(Nb、Ta、Yb),Eu异常具弱—明显Eu负异常—弱的Eu正异常(δEu=0.24~1.20)。这些花岗岩类总体具有俯冲的构造背景,岩浆的产生可能与北山地区在新元古代末古陆壳裂解作用有关。