Microelectrona cladara gen.et sp.nov.:A New Protodikraneurini from the Eocene Baltic Amber(Hemiptera:Cicadomorpha:Cicadellidae:Typhlocybinae)

<正>A new genus Microelectrona gen.nov.and species Microelectrona cladara sp.nov.of the extinct tribe Protodikraneurini of the leafhoppers(Cicadeilidae:Typhlocybinae) from the Eocene Baltic amber is described. The piece of amber containing leafhopper inclusion is broken,unveiling some of the morphological structures,and enabling their studies using scanning electron microscopy.     

Exsolution of dolomite and application of calcite–dolomite solvus geothermometry in high‐grade marbles: an example from Skallevikshalsen,East Antarctica

Calcite–dolomite solvus geothermometry is a versatile method for the estimation of metamorphic temperature because of its simplicity. However, in medium‐ to high‐grade metamorphic rocks the accuracy of estimating temperature by the integration of unmixed dolomite and calcite is hampered by the heterogeneous distribution of unmixed dolomite, difficulties in distinguishing between preexisting and exsolved dolomite and demarcating grain boundaries. In this study, it is shown that calcite–dolomite solvus thermometry can be applied to calcite inclusions in forsterite and spinel for the estimation of peak metamorphic temperature in granulite facies marbles from Skallevikshalsen, East Antarctica. The marbles are comprised of a granoblastic mineral assemblage of calcite + dolomite + forsterite + diopside + spinel + phlogopite ± apatite, characteristic of granulite facies metamorphic conditions. Forsterite, spinel and apatite frequently contain ‘negative crystal’ inclusions of carbonates that display homogeneously distributed dolomite lamellae. On the basis of narrow ranges of temperature (850–870 °C) recorded from carbonate inclusions compared with the range from matrix carbonate it is regarded that the inclusion carbonates represent a closed system. Furthermore, this estimate is consistent with dolomite–graphite carbon isotope geothermometry, and is considered to be the best estimate of peak metamorphic temperature for this region. Matrix calcite records different stages of retrograde metamorphism and re‐equilibration of calcite that continued until Mg diffusion ceased at ～460 °C. Electron backscattered diffraction (EBSD) results together with morphological features of unmixed coarse tabular dolomite suggest anisotropic diffusion and mineral growth are influenced by crystallographic orientation. Identification of sub‐grain boundaries and formation of fine‐grained unmixing in calcite rims suggest the presence of grain boundary fluids in the late retrograde stages of metamorphic evolution. These results, thus, demonstrate the usefulness of carbonate inclusion geothermometry in estimating the peak metamorphic temperatures of high‐grade terranes and the application of EBSD in understanding the unmixing behaviour of minerals with solid solutions.     

A new 3D laser-scanning and GPS combined measurement system

Terrestrial laser scanning (TLS) is widely used because of its ability to quickly acquire high-density and high-precision 3D image and topographic data. However, it can only acquire independent coordinate system points, which restricts its application in large-scale deformation monitoring. In this study, we constructed a measurement system to acquire global coordinate point cloud data by combining TLS and GPS (Global Positioning System). The coordinate values of retro-reflective targets could be acquired in different coordinate systems, the GPS coordinate and the TLS station coordinate, synchronously. Our experiments showed that, after registration with the homonymy points acquired by 30-min short-baseline differential GPS using the ICP algorithm, the positional accuracy of the TLS retro-reflective target center in the global coordinate was better than 10 mm. This high precision meets, for instance, the requirements of coal mining subsidence monitoring. We used our new combined measurement system to acquire and process the point cloud data of a frame structure. The measurements demonstrated the practicability and robustness of the new measurement system.     

黑河中游农村居民节水意识对节水行为的影响路径——基于结构方程模型与计划行为理论的研究

提高居民节水意识有助于推动居民节水行为,但由于意识难以客观测量,意识对行为的影响机理难以刻画,定量评估其影响路径的研究仍有待加强。基于计划行为理论,构建节水意识对节水行为的影响机制并设定相应的观测指标,设计问卷调查了黑河流域中游地区张掖市526户农村居民家庭,运用结构方程模型定量分析其影响路径。结果显示,节水态度、节水预期、行为控制、主观规范对节水行为的标准化路径系数分别为0.003、0.122、0.140、0.161,其中属于行为控制的自身经验与节水障碍预期、属于主观规范的管理部门信任度与邻里感知均对节水行为有显著的正向影响。虽然节水态度维度中,对水资源价值、保护环境和节约用水的因子载荷分别达到0.74、0.67、0.70,表明农村居民对水资源的生态、社会价值认同度很高,但向节水行为的转化过程中仍受经济效益预期的支配。提出了通过奖惩正式制度与邻里乡约非正式制度结合,以及高效节水产业政策引导,促进居民节水意识向节水行为的高效转化。     

腐植酸改性强化磁铁矿吸附水体中铅镉的实验研究

磁铁矿是一种绿色廉价的矿物材料,对水体中重金属离子具有良好的吸附性,但吸附容量低,选择性差,易团聚,通过改性可以克服该缺点并提高其吸附性能。本文以腐植酸为改性剂,采用常温水相反应制备了腐植酸改性磁铁矿吸附材料。通过傅里叶红外光谱(FTIR)、扫描电镜(SEM)和X射线光电子能谱(XPS)表征研究其表面形貌和微观结构。采用静态平衡实验考察了pH、吸附时间等因素对铅、镉吸附性能的影响,探讨了吸附动力学规律,拟合了吸附等温线。结果表明:腐植酸上的羧基、羟基被成功地接枝到了磁铁矿表面。在室温下,溶液初始pH对Pb~(2+)的吸附率几乎无影响,对Cd~(2+)的影响较大,当pH=7时,Pb~(2+)和Cd~(2+)吸附率均达到了95%。对初始质量浓度为10mg/L的Pb~(2+)、Cd~(2+)最佳吸附平衡时间为360min,吸附过程符合准二级动力学方程。吸附等温线实验得到的竞争吸附顺序为Pb~(2+)Cd~(2+),由Langmuir等温吸附模型得到Pb~(2+)、Cd~(2+)饱和吸附容量分别为39.27mg/g、28.95mg/g,显著大于磁铁矿的饱和吸附容量,表明磁铁矿经腐植酸改性后增强了对水中铅镉的吸附能力。     

集成RTK的三维激光扫描技术测量地形的方法

针对标靶扫描、全站仪辅助等因素造成扫描作业过程的复杂繁琐,提出了集成RTK的三维激光扫描技术测量地形的整体方案。采用网络RTK同轴同步测量扫描站坐标;两级拼接策略：地物点粗拼接与基于面搜索的ICP精确配准;采用测块四角或周边RTK点进行点云绝对定向;采用自主研发的点云测图平台进行地形测绘。通过几种典型地形的实验验证,该方案使得扫描作业效率提高了约5倍,与现行全野外数字测图方法比较,作业效率提高了约3倍。     

XRF岩芯扫描分析方法及其在湖泊沉积研究中的应用

XRF岩芯扫描分析方法在海洋和湖泊沉积环境变化方面的应用研究,已取得了显著的成果,但在国内尚未见到研究成果的报道。XRF岩芯扫描分析方法具有快速、无破坏性、连续测试元素和对样品制备要求不高等特点,在获取高分辨环境记录方面更具独特的优势。因此,这一分析方法具有极好的应用前景,它能提高分析的准确性和精确度,加强高分辨率湖泊沉积与环境演变的整体性研究,促进环境指标的综合运用与定量化研究。从介绍XRF岩芯扫描分析方法的原理、特点、影响因素、分析结果的校正入手,进而分析该测试方法的应用现状与远景。     

凹凸棒石与酸反应纳米尺度研究——反应机理和表面积变化

利用高分辨透射电子显微镜(HRTEM)和BET-比表面积分析(BET-SSA)技术调查了沉积型凹凸棒石与酸作用过程中形态和比表面积变化,并探讨了凹凸棒石与酸反应机理。对不同条件下凹凸棒石与酸反应产物纳米尺度观察表明,凹凸棒石的酸溶反应既表现出棒状晶体端部四面体和八面体一致溶解,也表现出柱面位置四面体和八面体不一致溶解。纳米尺度观察揭示出凹凸棒石与酸反应机制是质子从外表面扩散渗透,而不是质子从晶体孔道的渗透,反应速率主要受穿过酸溶产物硅酸层扩散速率控制。凹凸棒石的酸溶反应过程中,酸处理凹凸棒石的纳米孔结构现象与柱面位置四面体硅局部溶蚀有关。酸处理凹凸棒石比表面积增加归因于凹凸棒石中八面体不均匀、不连续溶解和局部四面体硅的溶蚀导致凹凸棒石孔道开放和直径扩大,从而使N2分子更多的进入凹凸棒石的孔道。部分八面体残留对四面体片起支撑作用,当凹凸棒石中八面体阳离子近于完全溶解时,四面体片失去支撑,结构塌陷,内孔孔道消失,比表面积再度下降。     

电子探针定量分析测定FeO和Fe2O3含量常用方法的评定

直接测氧法测定矿物中FeO和Fe2O3含量，在其众多影响因素中，经测量不确定度评定发现，超轻元素氧的影响显著。一方面受电子探针仪器因素和基体校正精度的限制，氧的电子探针定量分析值的准确度很低；另一方面氧对FeO和Fe2O3含量的不确定度灵敏系数分别为8．981、9．981，将氧的测量不确定度再扩大近10倍。可见直接测氧法测定FeO和Fe2O3含量，仅因超轻元素氧的测量不确定度传递就会使其误差范围过大，效果不是很理想。而利用Fe的Lα、Lβ谱线强度比的价态效应推测矿物中FeO和Fe2O3含量，由于Lβ/Lα强度比与Fe^2＋／Fe^3＋比值之间关系曲线的确定，需要对矿物进行大量的系统性研究，甚至是否必然存在这种对应都还缺乏理论依据，可见此法也并不可靠。相对而言，常用的电价差值法和剩余氧计算法仍为优选方案。     

Hydrostatic compression of galenobismutite (PbBi<Subscript>2</Subscript>S<Subscript>4</Subscript>): elastic properties and high-pressure crystal chemistry

A single-crystal sample of galenobismutite was subjected to hydrostatic pressures in the range of 0.0001 and 9 GPa at room temperature using the diamond-anvil cell technique. A series of X-ray diffraction intensities were collected at ten distinct pressures using a CCD equipped 4-circle diffractometer. The crystal structure was refined to R1(|F₀| > 4σ) values of approximately 0.05 at all pressures. By fitting a third-order Birch-Murnaghan equation of state to the unit-cell volumes V ₀ = 700.6(2) ų, K ₀ = 43.9(7) GPa and dK/dP = 6.9(3) could be determined for the lattice compression. Both types of cations in galenobismutite have stereochemically active lone electron pairs, which distort the cation polyhedra at room pressure. The cation eccentricities decrease at higher pressure but are still pronounced at 9 GPa. Galenobismutite is isotypic with CaFe₂O₄ (CF) but moves away from the idealised CF-type structure during compression. Instead of the two octahedral cation sites and one bi-capped trigonal-prismatic site, PbBi₂S₄ attains a new high-pressure structure characterised by one octahedral site and two mono-capped trigonal-prismatic sites. Analyses of the crystal structure at high pressure confirm the preference of Bi for the octahedral site and the smaller one of the two trigonal-prismatic sites.