砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系     

聚类分析法在浅海水团分析中的应用及黄、东海变性水团的分析

本文引入变性水团概念,用聚类分析确定黄、东海浅海海域变性水团的边界及其变化。根据给定的标准进行聚类,确定了水团的个数、边界及混合区。 由聚类方法所得结果看出,在该海区中有八个变性水团。根据温、盐相对指标,将这些水团分为九种不同的特征。也可以把这些水团划分为三种盐度类型。在温—盐点聚图上,不同变性水团的温盐点,分布于一条曲线附近,它体现出逐级变性的特点。各变性水团的变化范围都很大,这说明该海区中水团变性强烈。在暖季中的增温降盐和冷季中的降温增盐,可认为是整个黄海和东海水体变性的特征。所有季节性水团都经历一个形成与消亡的过程。 文中讨论了变性水团和海洋环境的相互关系。水团变性是热力因素和动力因素共同作用而产生的。通过变性水团的分析,作者认为,在该海区水团的变性中,热力因素起着主要作用。变性水团界线的舌状分布与流向之间的关系是很明显的,可作为分析环流的旁证。最后描述了变性水团和底层中心渔场之间的关系。     

An experimental method for determining the frequency-dependent added mass and added mass moment of inertia for a floating body in heave and pitch motions

Most of the existing relevant materials have been obtained from experiments, in which evaluating the added mass at the resonant frequency corresponding to the peak of a frequency-response curve obtained from the “forced” vibration analysis is the most popular technique. In this paper, a simple experimental method was presented where the “free” vibration responses instead of the “forced” ones were used to determine the values of m_ah and I_ap. The main part of the experimental system is composed of a floating body (model) and a spring–shaft shaker. The “free” vibration of this main part was induced by imposing on it an initial displacement (and/or an initial velocity), and from the time histories of displacements information such as the “damped” natural frequencies, damping ratios, sectional added mass coefficients (C_V and C_P) were obtained. Since the displacements of the spring–shaft shaker are “translational” and those of the floating body due to pitch motions are “angular”, a technique for the transformation between the associated parameters of the two components of the main part was presented.     

台湾海峡上升流区夏季溶解氧的特征

本文根据1983—1984年,1987—1988年台湾海峡中北部海域调查资料,着重讨论了该海域夏季溶解氧分布特征及其与上升流、生物活动的关系。该上升流区温度、盐度、溶解氧含量及其饱和度的特征值分别为24.4℃,34.3,4.49mlO_2/L和93％。溶解氧含量及其饱和度与温度呈正相关关系,与盐度呈负相关关系。     

磁通门罗盘的原理

磁通门罗盘是一种新型罗盘。此罗盘的关键部件是探头,探头主要是由高导磁的软磁材料做成的磁环和线圈组成。当在初级线圈加上交变的激励信号时,即可得到与次级线圈在地磁场中相对应的磁方位角。本文介绍其原理,并对其进行了理论分析。     

Sediment movement under unidirectional flows: an assessment of empirical threshold curves

A selection of threshold data sets from previous investigations is used to re-examine, selectively, some of the empirical curves that are most commonly used for the prediction of sediment threshold. Simple analytical formulae are derived describing single line curves for mean threshold values and envelopes for the initial movement of discrete particles and the commencement of mass sediment transport phases of the critical condition.The complexity of factors governing the prevailing conditions at threshold, together with the randomness of events, limits deterministic solutions; however, the curves provide an approach that can be used readily in practical applications. In contrast, the envelope presentation is more of a stochastic approach to the definition of threshold. It recognises that there is no definitive threshold condition under which a particular particle size can be displaced, but rather that a range of threshold values exist.The empirical threshold relationships were derived on the basis of a relatively large amount of data. However, the sources utilised have interpreted the ‘critical condition’ in various ways, implying that the formulae must be treated with caution in applications.     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

基于非等间距模型的建筑物沉降预测方法研究

该文基于实测资料进行建筑物沉降预测。在灰色模型和泊松曲线模型理论的基础上,引入对非等间距数列进行变换处理的方法,从而建立了非等间距预测模型。结合建筑物沉降监测资料进行分析比较,结果表明,两种预测方法均能较好地反映建筑物的沉降趋势。     

水平井含水率上升影响因素

利用塔里木油田塔中4油田(TZ4)底水油藏相关的地质、流体数据建立数值模型。在所建模型的基础上,应用数值模拟计算的累积产油、产水和产液量回归俞启泰水驱特征曲线,以反映水平井见水特征的参数b。以参数b为研究对象,采用正交试验的方法研究不同因素对b值的影响,筛选影响水平井见水特征的主要因素,认为原油粘度、油层厚度、非均质性及水平井水平段在油藏中的位置是影响水平井含水上升趋势的主要指标。最后建立主要因素与b值的关系式,结合俞启泰曲线b值图版,提出预测水平井见水规律的公式——图版法(F-b法)。应用F-b法对塔里木水平井含水率进行预测,并与其他相关方法及实际生产数据对比,认为F-b法可作为预测塔里木油田水平井含水率、估算可采储量的一种有效方法。     

火山沉积岩及其矿床研究中伽马测井曲线解释的误区

根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。