ELECTROCHEMICAL CORROSION BEHAVIOR OF STEEL IN THE JUNCTURE AREA OF SEA CLAY AND SAND

Corrosion behavior of steel in the juncture area of sea clay and sand was studied. The results show that galvanic corrosion occurred between steel samples buried in sea clay and sand, and that the polarity of the galvanic cell reversed after some testing later. The cause of reversing of polarity is discussed.     

Properties and organic activation of ocean clay in the East Pacific

In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5% (volume) of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.     

APPLICATION OF CLAYS TO REMOVAL OF RED TIDE ORGANISMS Ⅰ.COAGULATION OF RED TIDE ORGANISMS WITH CLAYS

Coagulation of red tide organism cells with clays is discussed in theory and the effects of some fac-tors on it are studied.A quantitative model is presented which describes how the coagulation varies withpH in solution.According to the model,within the pH-range between pH_(zpc_a)and pH_(zpc_b),V_R is negativeand the coagulation is strong and strongest at pH=(pH_(zpc_a)+pH_(zpc_b))/2.It is also demonstrated that whenthe diameter of clay particles is close to that of cells,the collision probability is low,resulting in weakercoagulation.The model results have been corroborated by experiments and so are scientific and theoreticalbases for application.     

孔隙液体的可压缩性对非饱和孔隙介质弹塑性分析的影响

首先在多相孔隙介质的混合物理论框架内探讨了如何利用固-液两相孔隙介质模型描述介质的非饱和问题。其次,讨论了一个实用的描述孔隙液体可压缩性的方法,并建立了小变形条件下固-液两相孔隙介质的弹塑性本构方程。最后,采用俞茂宏统一强度理论,针对一个具体的结构例子,分析了孔隙液体的可压缩性对结构弹塑性分析的影响。     

南华北地区石炭—二叠系砂岩和泥岩中粘土矿物的形成与转化

区内砂岩中的粘土矿物主要是自生的高岭石、绿泥石和伊蒙混层,而泥岩中的粘土矿物是伊蒙混层和高岭石,少量绿泥石,未见蒙脱石.砂岩和泥岩中粘土矿物的转化具有相似的水介质和地温条件,都反映出在中—晚成岩期形成,而且与烃类的排出和运移密切相关.泥岩中粘土矿物转化和脱水作用为砂岩输送流体和释放溶解物质,而且泥岩中有机质的脱羟基向砂输送酸性水,促进砂岩中骨架颗粒溶解、次生孔隙的产生.     

石灰改良膨胀土力学性质的研究

膨胀(?)主要是由强亲水性粘土矿物蒙脱石和伊利石组成的,是具有膨胀性、多裂隙性和超固结性的高塑性粘性土。在铁路施工中,膨胀土不能直接作为路基填土,必需进行改良。通过室内试验的方法来讨论石灰改良膨胀土的力学性质在各种影响因素下的变化规律。     

模拟渗滤液作用下压实黏土的力学性质

垃圾填埋场中渗滤液的作用可能对压实黏土衬垫及地基土的力学性质产生一定的影响,但目前研究成果存在矛盾之处。以CaCl2溶液和苯酚溶液作为渗滤液中无机和有机污染物的代表,对添加10%钠基膨润土的压实黏土进行力学性质的试验研究。结果表明,（1）两种模拟渗滤液的作用使土的压缩性增强,抗剪强度降低。（2）苯酚对压实黏土力学性质的影响更为显著,不排水强度约为自来水和0.05molL-1CaCl2溶液的55%。（3）土样初始孔隙比相同时,溶液作用下扩散双电层变薄造成孔隙变大,可能是产生这种现象的主要原因。（4）模拟渗滤液的作用对压实黏土衬垫及地基土具有不利的影响。     

上海黏性土剪切带形成的数值模拟分析

各种工程事故表明：现有的土力学计算模型均未考虑应变局部化问题,故不能解释这些工程事故的发生,因此应变局部化和剪切带形成的研究成为国际土力学界研究热点之一。数值模拟是研究剪切带形成的一个重要内容。在数值模拟中首先进行剪切带形成条件的研究,接着考虑土质不均匀性的影响,引入弱单元和强单元,进行弱单元与强单元影响力的研究。     

CASM: a unified state parameter model for clay and sand

The purpose of this paper is to present a simple, unified critical state constitutive model for both clay and sand. The model, called CASM (Clay And Sand Model), is formulated in terms of the state parameter that is defined as the vertical distance between current state (v, p′) and the critical state line in v–ln p′ space. The paper first shows that the standard Cam-clay models (i.e. the original and modified Cam-clay models) can be reformulated in terms of the state parameter. Although the standard Cam-clay models prove to be successful in modelling normally consolidated clays, it is well known that they cannot predict many important features of the behavior of sands and overconsolidated clays. By adopting a general stress ratio-state parameter relation to describe the state boundary surface of soils, it is shown that a simple, unified constitutive model (CASM) can be developed for both clay and sand. It is also demonstrated that the standard Cam-clay yield surfaces can be either recovered or approximated as special cases of the yield locus assumed in CASM. The main feature of the proposed model is that a single set of yield and plastic potential functions has been used to model the behaviour of clay and sand under both drained and undrained loading conditions. In addition, it is shown that the behaviour of overconsolidated clays can also be satisfactorily modelled. Simplicity is a major advantage of the present state parameter model, as only two new material constants need to be introduced when compared with the standard Cam-clay models. © 1998 John Wiley & Sons, Ltd.     

Field Measurement of Suction, Water Content, and Water Permeability

This paper presents a review of techniques for field measurement of suction, water content, and water hydraulic conductivity (permeability). Main problems in the use of field tensiometers are addressed and hints on how to improve tensiometer performance are given. Advantages and limitations of instruments for indirect measurement of suction including electrical conductivity sensors, thermal conductivity sensors, dielectric permittivity sensors, filter paper, and psychrometer are discussed. Techniques for water content measurement based on dielectric methods are then presented. These include time and amplitude domain reflectometry and capacitance. Finally, a brief overview of methods for measurement of water permeability in the field is presented.